| 光谱学与光谱分析 | 
									
										
		  							 | 
          							
		  									  								 
		  									  							|
		  									  								 
		  									  							 | 
        						 
      						 
      					 | 
  					 
  					
    					 | 
   					 
   										
    					| Study on the Micro-FTIR and Raman Spectra of the Alluvial Diamonds from Yangtze Craton and Their Geological Significances  | 
  					 
  					  										
						| ZENG Xiang-qing1, ZHENG Yun-long1, YANG Zhi-jun1,2*, AI Qun1, HU Piao-ye1  | 
					 
															
						1. Department of Geoscience, Sun Yat-Sen University, Guangzhou 510275, China 2. Guangdong Provincial Key Laboratory of Mineral Resource Exploration & Geological Processes, Guangzhou 510275, China | 
					 
										
						 | 
					 
				 
				
				
					
						
							
								
									
										
											
                        					 
												
													
													    | 
													    	
														 | 
													 
																										
													
														
															
													
													    | 
													     		                            						                            																	    Abstract  The FTIR and Raman spectra of 10 diamonds from Yuanshui, Hunan province show that the alluvial diamonds from this area are mostly IaAB type, with a significant character that the A-center is enriched relatively; the nitrogen concentration in the diamonds is between 38.20 and 840.67 μg·g-1, which has a tremendous distinction in different crystal. The residence time of the diamonds in the mantle are between 0.043 and 3.315 Ga, which is also has a great difference in different diamond grains. The remotest residence time (3.315 Ga) of one diamond is older than the most aged rock (3.285 Ga) in Xiang-E-Qian-Gui contiguous zone. A remarkable environment change had took place during the process of diamonds formation. The formation depth of dodecahedral diamonds is deeper than that of the octahedral ones. 
																										     | 
														 
														
														
															| 
											   							Received: 2013-01-29    
						    						    							Accepted: 2013-04-19    
						    						    						    																				    
															 | 
														 
														 														
															| 
																
															 | 
														 
																																									    														
															| 
																Corresponding Authors:
																YANG Zhi-jun   
																																 E-mail: yangzhj@mail.sysu.edu.cn
															    													     		
													     	 | 
														 
																																												 
															 | 
											
														 
														
													 
													
												 
												
												
													
														  
															 [1] RAO Jia-rong(饶家荣). Hunan Geology(湖南地质), 1999, 18(1): 21.  [2] SHI Ni-cheng, LU Qi, LI Guo-wu, et al(施倪承, 陆 琦, 李国武, 等). Earth Science Frontiers(地学前缘), 2011, 18(6): 341.  [3] WANG Dao-jing, HUANG Huai-yong(王道经, 黄怀勇). China Geology(中国地质), 1998, 253(6): 46.  [4] YANG Zhi-jun, PENG Ming-sheng, XIE Xian-de, et al(杨志军, 彭明生, 谢先德, 等). Rock and Mineral Analysis(岩矿测试), 2002, 21(3): 161.  [5] CHEN Mei-hua, DI Jing-ru(陈美华, 狄敬如). Geological Science and Technology Information(地质科技情报), 1999, 18(2): 97.  [6] Field J E. The Properties of Natural and Synthetic Diamond. London: Academic Press, 1992. 36, 81.  [7] Davies G. Nature, 1981, 290: 40.  [8] Taylor W R, Jaques A L, Ridd M. Am Mineral.,1990, 75:1290.  [9] YIN Zuo-wei, LU Feng-xiang, CHEN Mei-hua, et al(尹作为, 路凤香, 陈美华,等). Earth Science Frontiers(地学前缘), 2005, 12(4): 614.  [10] YANG Zhi-jun, LI Hong-zhong, LIN Feng, et al(杨志军, 李红中, 林 峰, 等). Superhard Material Engineering(超硬材料工程). 2007, 19(2): 1.  [11] Shiryaev A A, Frost D J, Langenhorst F. Diamond and Related Materials, 2007, 16, 503.  [12] HE Xue-mei(何雪梅). Geology and Prospecting(地质与勘探),2000, 36(4): 45.  [13] Chrenko R M, Tuft R E, Strong H M. Nature,1977, 270:141.  [14] Orlov Y L. The Mincralogy of the Diamond. John Wiley & Sons, Inc., New York, N Y, CISA, 1977. 24.  [15] YANG Zhi-jun, LIANG Rong, ZENG Xiang-qing, et al(杨志军, 梁 榕, 曾祥清, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2012, 32(6), 1512.  [16] CHENG Guang-xi(程光熙). Raman-Brillouin Scattering(拉曼布里渊散射). Beijing:Science Press(北京:科学出版社), 2001. 320.  [17] Taylor W R, Jaques A L, Ridd M. Am. Mineral., 1990, 75: 1290.  [18] CHI Ji-shang, LU Feng-xiang(池际尚, 路凤香). The Characteristic of the Kimberlite in North China Platform and Paleozoic Lithosphere(华北地台金伯利岩及古生代岩石圈地幔特征). Beijing:Science Press(北京: 科学出版社), 1996. 17-18, 138.  [19] MA Wen-yuan(马文远). Hunan Geology(湖南地质),1997, 16(4): 213.  [20] Deines P,Hams J W, Gurney J J. Geochim. et Cosrnochim. Acta, 1993, 57:2781.  [21] Harte B, Harris J W. Mineralogical Magazine,1994, 58A:384.  | 
														 
														
													 
												 
												
													
														
															
																
																																																																																						
																				
																					| [1] | 
																					WANG Gan-lin1, LIU Qian1, LI Ding-ming1, YANG Su-liang1*, TIAN Guo-xin1, 2*. Quantitative Analysis of NO-3,SO2-4,ClO-4 With Water as Internal Standard by Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1855-1861. | 
																				 
																			
																																																																																																									
																				
																					| [2] | 
																					HUANG Bin, DU Gong-zhi, HOU Hua-yi*, HUANG Wen-juan, CHEN Xiang-bai*. Raman Spectroscopy Study of Reduced Nicotinamide Adenine Dinucleotide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1679-1683. | 
																				 
																			
																																																																																																									
																				
																					| [3] | 
																					ZHU Xiang1, 2*, YUAN Chao-sheng1, CHENG Xue-rui1, LI Tao1, ZHOU Song1, ZHANG Xin1, DONG Xing-bang1, LIANG Yong-fu2, WANG Zheng2. Study on Performances of Transmitting Pressure and Measuring Pressure of [C4mim][BF4] by Using Spectroscopic Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1674-1678. | 
																				 
																			
																																																																																																									
																				
																					| [4] | 
																					WANG Ming-xuan, WANG Qiao-yun*, PIAN Fei-fei, SHAN Peng, LI Zhi-gang, MA Zhen-he. Quantitative Analysis of Diabetic Blood Raman Spectroscopy Based on XGBoost[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1721-1727. | 
																				 
																			
																																																																																																									
																				
																					| [5] | 
																					YOU Gui-mei1, ZHANG Wen-jie1, CAO Zhen-wei2, HAN Xiang-na1*, GUO Hong1. Analysis of Pigments of Colored Paintings From Early Qing-Dynasty Fengxian Dian in the Forbidden City[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1874-1880. | 
																				 
																			
																																																																																																									
																				
																					| [6] | 
																					LI Qing1, 2, XU Li1, 2, PENG Shan-gui1, 2, LUO Xiao1, 2, ZHANG Rong-qin1, 2, YAN Zhu-yun3, WEN Yong-sheng1, 2*. Research on Identification of Danshen Origin Based on Micro-Focused 
Raman Spectroscopy Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1774-1780. | 
																				 
																			
																																																																																																									
																				
																					| [7] | 
																					WANG Zhong, WAN Dong-dong, SHAN Chuang, LI Yue-e, ZHOU Qing-guo*. A Denoising Method Based on Back Propagation Neural Network for 
Raman Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1553-1560. | 
																				 
																			
																																																																																																									
																				
																					| [8] | 
																					FU Qiu-yue1, FANG Xiang-lin1, ZHAO Yi2, QIU Xun1, WANG Peng1, LI Shao-xin1*. Research Progress of Pathogenic Bacteria and Their Drug Resistance 
Detection Based on Surface Enhanced Raman Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1339-1345. | 
																				 
																			
																																																																																																									
																				
																					| [9] | 
																					YAN Ling-tong, LI Li, SUN He-yang, XU Qing, FENG Song-lin*. Spectrometric Investigation of Structure Hydroxyl in Traditional Ceramics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1361-1365. | 
																				 
																			
																																																																																																									
																				
																					| [10] | 
																					JI Rong-hua1, 2, ZHAO Ying-ying2, LI Min-zan2, ZHENG Li-hua2*. Research on Prediction Model of Soil Nitrogen Content Based on 
Encoder-CNN[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1372-1377. | 
																				 
																			
																																																																																																									
																				
																					| [11] | 
																					ZHAO Yong1, HE Men-yuan1, WANG Bo-lin2, ZHAO Rong2, MENG Zong1*. Classification of Mycoplasma Pneumoniae Strains Based on 
One-Dimensional Convolutional Neural Network and 
Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1439-1444. | 
																				 
																			
																																																																																																									
																				
																					| [12] | 
																					LI Meng-meng1, TENG Ya-jun2, TAN Hong-lin1, ZU En-dong1*. Study on Freshwater Cultured White Pearls From Anhui Province Based on Chromaticity and Raman Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1504-1507. | 
																				 
																			
																																																																																																									
																				
																					| [13] | 
																					JIAO Ruo-nan,  LIU Kun*,  KONG Fan-yi,  WANG Ting,  HAN Xue,  LI Yong-jiang,  SUN Chang-sen. Research on Coherent Anti-Stokes Raman Spectroscopy Detection of 
Microplastics in Seawater and Sand[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1022-1027. | 
																				 
																			
																																																																																																									
																				
																					| [14] | 
																					ZHANG Li-sheng. Photocatalytic Properties Based on Graphene Substrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1058-1063. | 
																				 
																			
																																																																																																									
																				
																					| [15] | 
																					LÜ Yang, PEI Jing-cheng*, GAO Ya-ting, CHEN Bo-yu. Chemical Constituents and Spectra Characterization of Gem-Grade 
Triplite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1204-1208. | 
																				 
																			
																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																																								 
														 | 
													 
												 
											 
											
											 
											
											 
										 
									 | 
								 
							 
						 | 
					 
				 
			
		 |