|
|
|
|
|
|
| Spectrometric Investigation of Structure Hydroxyl in Traditional Ceramics |
| YAN Ling-tong, LI Li, SUN He-yang, XU Qing, FENG Song-lin* |
Institute of High Energy Physics, Chinese Academy of Sciences, Beijing 100049, China
|
|
|
|
|
Abstract Fired clay products can absorb water molecules and be re-hydroxylated, and the amount of structural hydroxyl groups generated has a certain relationship with the storage time. Based on the theory of rehydroxylation in fired-clay, thermogravimetric analysis can be used to study the dating of pottery products. Infrared and Raman spectroscopy techniques can also be used to analyze the structural hydroxyl information in mineral materials, so people hope to explore the use of spectral non-destructive analysis for dating traditional ceramics instead of the thermogravimetric method. In order to verify the feasibility, we collected a variety of typical raw materials and traceable ancient ceramic potshards in this paper and analyzed their internal structural hydroxyl groups by infrared and Raman spectroscopy. The obvious peaks of aluminum hydroxyl in orthoclase, porcelain clay and kaolinite can be observed in the range of 3 600~3 700 cm-1 both in infrared and Raman spectra. When analyzing traditional ceramic samples, there is no peak of the structural hydroxyl group in this range in the infrared spectrum. When the wavelength of the excitation light of the Raman spectroscopy is 532 nm, two obvious peaks can be observed in the range of 3 600~4 000 cm-1 in the spectra of many samples. When the wavelength was changed, there was no peak in the corresponding rang. Especially when the excitation light wavelength is 514 nm, two peaks can be observed at 4 288 and 4 512 cm-1. The peaks observed when the excitation light wavelengths are 532 and 514 nm can correspond to about 659 and 669 nm in the wavelength mode of Raman spectra. The results showed that when the excitation light wavelength is 532 nm, the two peaks observed in the range of 3 600~4 000 cm-1 in the Raman spectrum should not be characteristic signal of structural hydroxyl groups in minerals, but rather sharp fluorescence peak. Under current technical conditions, infrared and Raman spectroscopy is difficult to be applied for rehydroxylation dating of Chinese traditional high-temperature ceramic products.
|
|
Received: 2021-03-17
Accepted: 2021-06-04
|
|
|
|
Corresponding Authors:
FENG Song-lin
E-mail: fengsl@ihep.ac.cn
|
|
[1] Heller L, Farmer V C, MaCkenzie R C, et al. Clay Minerals, 1962, 5(28): 56.
[2] Hamilton A, Hall C. Journal of American Ceramic Society, 2012, 95(9): 2673.
[3] Wilson M A, Hoff W D, Hall C, et al. Physical Review Letters, 2003, 90(12): 125503.
[4] Hall C, Hamilton A, Wilson M A. Journal of Archaeological Science, 2013, 40: 305.
[5] Wilson M A, Clelland S, Carter M A, et al. Archaeometry, 2014, 56(4): 689.
[6] Hall C, Wilson M A, Hoffw D. Journal of American Ceramic Society, 2011, 94(11): 3651.
[7] Wilson M A, Hamilton A, Ince C, et al. Proceedings of the Royal Society, 2012, 468: 3476.
[8] Bowen P K, Ranck H J, Scarlett T J, et al. Journal of American Ceramic Society, 2011, 94(8): 2585.
[9] Clegg F, Breen C, Carter M A, et al. Journal of AmericanCeramic Society, 2012, 95(1): 416.
[10] ZHU Ji-hao, FENG Song-lin, CHU Feng-you, et al（朱继浩，冯松林，初凤友，等）. Spectroscopy and Spectral Analysis（光谱学与光谱分析）, 2010, 30(11): 3143.
[11] Kiefert L, Karamplas S. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2011, 81(1): 119.
[12] Rice P M. Pottery Analysis. Chicago: The University of Chicago Press, 2015.
[13] Frost R L, Kloprogge J T. Journal of Raman Spectroscopy, 2000, 31: 415.
|
| [1] |
LI Jie, ZHOU Qu*, JIA Lu-fen, CUI Xiao-sen. Comparative Study on Detection Methods of Furfural in Transformer Oil Based on IR and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 125-133. |
| [2] |
CHENG Jia-wei1, 2，LIU Xin-xing1, 2*，ZHANG Juan1, 2. Application of Infrared Spectroscopy in Exploration of Mineral Deposits: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 15-21. |
| [3] |
WANG Fang-yuan1, 2, HAN Sen1, 2, YE Song1, 2, YIN Shan1, 2, LI Shu1, 2, WANG Xin-qiang1, 2*. A DFT Method to Study the Structure and Raman Spectra of Lignin
Monomer and Dimer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 76-81. |
| [4] |
GAO Feng1, 2, XING Ya-ge3, 4, LUO Hua-ping1, 2, ZHANG Yuan-hua3, 4, GUO Ling3, 4*. Nondestructive Identification of Apricot Varieties Based on Visible/Near Infrared Spectroscopy and Chemometrics Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 44-51. |
| [5] |
XING Hai-bo1, ZHENG Bo-wen1, LI Xin-yue1, HUANG Bo-tao2, XIANG Xiao2, HU Xiao-jun1*. Colorimetric and SERS Dual-Channel Sensing Detection of Pyrene in
Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 95-102. |
| [6] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
| [7] |
WANG Xin-qiang1, 3, CHU Pei-zhu1, 3, XIONG Wei2, 4, YE Song1, 3, GAN Yong-ying1, 3, ZHANG Wen-tao1, 3, LI Shu1, 3, WANG Fang-yuan1, 3*. Study on Monomer Simulation of Cellulose Raman Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 164-168. |
| [8] |
LIU Jia, ZHENG Ya-long, WANG Cheng-bo, YIN Zuo-wei*, PAN Shao-kui. Spectra Characterization of Diaspore-Sapphire From Hotan, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 176-180. |
| [9] |
XIA Ming-ming1, 2, LIU Jia3, WU Meng1, 2, FAN Jian-bo1, 2, LIU Xiao-li1, 2, CHEN Ling1, 2, MA Xin-ling1, 2, LI Zhong-pei1, 2, LIU Ming1, 2*. Three Dimensional Fluorescence Characteristics of Soluble Organic Matter From Different Straw Decomposition Products Treated With Calcium Containing Additives[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 118-124. |
| [10] |
BAO Hao1, 2，ZHANG Yan1, 2*. Research on Spectral Feature Band Selection Model Based on Improved Harris Hawk Optimization Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 148-157. |
| [11] |
GU Yi-lu1, 2，PEI Jing-cheng1, 2*，ZHANG Yu-hui1, 2，YIN Xi-yan1, 2，YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
| [12] |
GUO Ya-fei1, CAO Qiang1, YE Lei-lei1, ZHANG Cheng-yuan1, KOU Ren-bo1, WANG Jun-mei1, GUO Mei1, 2*. Double Index Sequence Analysis of FTIR and Anti-Inflammatory Spectrum Effect Relationship of Rheum Tanguticum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 188-196. |
| [13] |
HAN Xue1, 2, LIU Hai1, 2, LIU Jia-wei3, WU Ming-kai1, 2*. Rapid Identification of Inorganic Elements in Understory Soils in
Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
| [14] |
WANG Lan-hua1, 2, CHEN Yi-lin1*, FU Xue-hai1, JIAN Kuo3, YANG Tian-yu1, 2, ZHANG Bo1, 4, HONG Yong1, WANG Wen-feng1. Comparative Study on Maceral Composition and Raman Spectroscopy of Jet From Fushun City, Liaoning Province and Jimsar County, Xinjiang Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 292-300. |
| [15] |
YANG Cheng-en1, 2, LI Meng3, LU Qiu-yu2, WANG Jin-ling4, LI Yu-ting2*, SU Ling1*. Fast Prediction of Flavone and Polysaccharide Contents in
Aronia Melanocarpa by FTIR and ELM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 62-68. |
|
|
|
|
