| 光谱学与光谱分析 |
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| Raman Spectra Study on the GeS2-Ga2S3-KCl System Glasses |
| TAO Hai-zheng, ZHAO Xiu-jian*, JING Cheng-bin, TONG Wei |
| Wuhan University of Technology, Wuhan 430070, China |
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Abstract Raman spectra of GeS2-Ga2S3-KCl pseudo-ternary system glasses at room temperature in the air were probed systematically in the region of 150-500 cm-1. Based on the results of Raman spectra and preparing procedure in pseudo-binary systems GeS2-KCl and Ga2S3-KCl, the sole interaction of Ga2S3 and KCl was identified and new units GaS3/2Cl were produced in GeS2-Ga2S3-KCl glasses. That K+ ions in the form of Cl as the nearest coordination were homogeneously dispersed in the polymeric network was confirmed by the Raman spectra evolution of samples on the serials Ⅰ and Ⅲ. Raman spectral evolution of three composition serials can be successfully interpreted using a localized model considering the effect of K+ ions on the structural units GaS3/2Cl and Ga2S4Cl2.
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Received: 2003-12-16
Accepted: 2004-04-28
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Corresponding Authors:
ZHAO Xiu-jian
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| Cite this article: |
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TAO Hai-zheng,ZHAO Xiu-jian,JING Cheng-bin, et al. Raman Spectra Study on the GeS2-Ga2S3-KCl System Glasses [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(01): 44-47.
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https://www.gpxygpfx.com/EN/Y2005/V25/I01/44 |
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