| 光谱学与光谱分析 |
|
|
|
|
|
| Raman Spectroscopic Analysis of Dissolution and Phase Transformation of Chloropinnoite in the Boric Acid Aqueous Solution |
| LI Xiao-ping1, GAO Shi-yang2, LIU Zhi-hong2, HU Man-cheng2, XIA Shu-ping2* |
1. School of Tourism and Environment Science, Shaanxi Normal University, Xi'an 710062, China
2. School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an 710062, China |
|
|
|
|
Abstract Raman spectroscopy of dissolution and transformation of chloropinnoite in 4.5%(w.t.%) boric acid aqueous solution at 30 ℃ has been recorded. The Raman spectra of kinetics process have been obtained. The phase transformation product is kurnakovite(2MgO·3B2O3·15H2O). The main polyborate anions and their interaction in aqueous solution have been proposed according to the Raman spectrum. Some assignments were tentatively given and the relations between the existing forms of polyborate anions and the crystallizing solid phases have been gained. Ａ mechanisms of dissolution and crystallization reactions and the formation condition of kurnakovite in Qinghai-Tibet plateau were proposed and discussed.
|
|
Received: 2003-12-06
Accepted: 2004-04-16
|
|
|
|
Corresponding Authors:
XIA Shu-ping
|
|
| Cite this article: |
|
LI Xiao-ping,GAO Shi-yang,LIU Zhi-hong, et al. Raman Spectroscopic Analysis of Dissolution and Phase Transformation of Chloropinnoite in the Boric Acid Aqueous Solution [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(01): 48-50.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2005/V25/I01/48 |
[1] Li Jun, Xia Shuping, Gao Shiyang. Spectrochimica Acta Part A, 1995, 51(4): 519.
[2] Jia Yongzhong, Gao Shiyang, Xia Shuping, Li Jun. Spectrochimica Acta Part A, 2000, 56: 1291.
[3] JIA Yong-zhong, GAO Shi-yang, XIA Shu-ping et al(贾永忠，高世扬，夏树屏等). Chemical Journal of Chinese Universities(高等学校化学学报), 2000, 22(1): 99.
[4] Ishihara Koji, Nagasawa Akira, Umemoto Kimiko et al. Inorg. Chem., 1994, 33: 3811.
[5] LIU Zhi-hong, GAO Shi-yang, XIA Shu-ping(刘志宏，高世扬，夏树屏). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(2): 291.
[6] Qinghai Institute of Salt Lakes, Chinese Academy of Sciences(中国科学院青海盐湖研究所). Analysis Methods of Salts and Brine(卤水和盐的分析方法). 2nd ed. Beijing: Science Press(北京: 科学出版社), 1988. 39.
|
| [1] |
WU Run-min1, XIE Fei1, SONG Xu-dong1*, BAI Yong-hui1, WANG Jiao-fei1, SU Wei-guang1, YU Guang-suo1, 2. The Mechanism of Hydrocarbon Flame Soot Formation in Spectral
Diagnosis: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 1-8. |
| [2] |
PENG Jiao-yu1, 2*, YANG Ke-li1, 2, BIAN Shao-ju1, 3, 4, CUI Rui-zhi1, 3, DONG Ya-ping1, 2, LI Wu1, 3. Quantitative Analysis of Monoborates (H3BO3 and B(OH)-4) in Aqueous Solution by Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2456-2462. |
| [3] |
TIAN Yuan, ZHAO Xin, LIN Hai, LI De-sheng*. Irradiation Parameters of Dy3+ Doped Fluoride Borate Glass Phosphors under Laser Excitation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1665-1669. |
| [4] |
DONG Jia-lin1, HONG Ming-jian1, 3*, ZHENG Xiang-quan2, 3, XU Yi2, 3. Discrimination of Human, Dog and Rabbit Blood Using Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 459-466. |
| [5] |
ZHANG Bao-yong1,2，ZHOU Hong-ji1,2，WU Qiang1,2，GAO Xia3. Raman Spectra Characteristics of Gas Hydrate Growth with Different Driving Forces[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2768-2773. |
| [6] |
WU Cheng-ling1, GUO Jun-hong1, 2, YAO Heng-bin1, PAN Ling-nan1, WANG Fei1, WU Wen-qi1, JI Tong1, HU Fang-ren1, 2*. Study on the Photoluminescence Properties of ZnO Single Crystal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(06): 1700-1702. |
| [7] |
XU Dong-mei1, PAN Kun1, LIU Xu-wei1, WANG Xue-jin1*, WANG Wen-zhong2, LIANG Chun-jun3, WANG Zhi2 . Raman and Visible-Near Infrared Spectra of Cu(InGa)Se2 Films [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(10): 3197-3201. |
| [8] |
WANG Guo-xiang1, WANG Hai-yan2, WANG Hu1, ZHANG Zheng-yong2, LIU Jun1 . Study on the Recognition of Liquor Age of Gujing Based on Raman Spectra and Support Vector Regression[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(03): 729-735. |
| [9] |
YANG Peng1, 2, ZHAO Xin1, WANG Zhi-qiang2, LIN Hai1, 2* . Ce3+/Tb3+ Doped Alkaline-Earth Borate Glasses Employed in Enhanced Solar Cells [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(12): 3291-3295. |
| [10] |
ZHANG Bao-yong1, 2, YU Yue1, 2*, WU Qiang1, 2, GAO Xia3 . Quantitative Analysis of the Hydration Process of Mine Gas Mixture Based on Raman Spectroscopy [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(07): 1912-1916. |
| [11] |
LIU Zhi-liang1, JIAO Qing2*, QIU Jian-bei2 . Effect of Eu Ions on the Ag Nanoparticles Precipitation and Their Optical Properties in Borate Glasses [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(08): 2065-2069. |
| [12] |
LI Tao, TANG Yan-lin*, LING Zhi-gang, LONG Zheng-wen . Study on the Frontier Orbital and Raman Spectra of Aflatoxin B1 and Isomer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(08): 2122-2125. |
| [13] |
LI Jing1, MAO Shi-de1*, ZHENG Hai-fei2,3 . Raman Spectroscopic Quantitative Study of NaCl-CaCl2-H2O System at High Temperatures and Pressures[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(07): 1747-1753. |
| [14] |
WU Dun, SUN Ruo-yu, LIU Gui-jian*, YUAN Zi-jiao. The Spectrum Studies of Structure Characteristics in Magma Contact Metamorphic Coal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(10): 2861-2864. |
| [15] |
TAO Dong-yan, LIU Chao*, YIN Chun-hai, ZENG Yi-ping . Raman Spectra Analysis of GaN∶Er Films Prepared by Ion Implantation [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(03): 699-703. |
|
|
|
|
