| 光谱学与光谱分析 |
|
|
|
|
|
| Raman Spectra of Aragonite and Calcite at High Temperature and High Pressure |
| FU Pei-ge, ZHENG Hai-fei* |
| Key Laboratory of Orogenic Belts and Crustal Evolution, Ministry of Education, Peking University, Beijing 100871, China |
|
|
|
|
Abstract Raman spectra of aragonite and calcite were studied in the temperature range of 18～388 ℃ and pressure range of 79～2 014 MPa, and 19～351 ℃ and 96～1 823 MPa, respectively in the diamond anvil cell. The relationships among the Raman shifts of aragonite and calcite, the system pressure and temperature were obtained. The Raman shifts of aragonite and calcite become higher with the pressure increasing, and become lower with the temperature increasing except the Raman shift of 704 cm-1 of aragonite. The absolute values of νi/T of aragonite and calcite for the lattice modes are greater than those for the internal modes of the CO3 groups, and the values of νi/T and νi/P of aragonite and calcite are various. The Raman shifts of the internal CO3 modes are related to the C—O bond length and the C—O bond is more compressible and less expansible in calcite than in aragonite, besides, they may be also related to the dynamical effects of the CO3 groups accompanying the aragonite-calcite transition.
|
|
Received: 2012-10-21
Accepted: 2013-01-30
|
|
|
|
Corresponding Authors:
ZHENG Hai-fei
E-mail: hfzheng@pku.edu.cn
|
|
[1] Liu L G, Chen C C, Lin C C, et al. Physics and Chemistry of Minerals, 2005, 32: 97.
[2] Chen C C, Lin C C, Liu L G, et al. American Mineralogist, 2001, 86: 1525.
[3] Liu L G, Mernagh T P. American Mineralogist, 1990, 75: 801.
[4] Mirwald P W. Contributions to Mineralogy and Petrology, 1976, 59: 33.
[5] Suito K, Namba J, Horikawa T. American Mineralogist, 2001, 86: 997.
[6] Perdikouri C, Kasioptas A, Putnis C V, et al. Mineralogical Magazine, 2008, 72(1): 111.
[7] Perdikouri C, Kasioptas A, Geisler T, et al. Geochimica et Cosmochimica Acta, 2011, 75: 6211.
[8] Gong Q J, Deng J, Wang Q F, et al. Acta Geologica Sinica, 2008, 82(5): 994.
[9] Gillet P, Biellmann C, Reynard B, et al. Physics and Chemistry of Minerals, 1993, 20: 1.
[10] ZHOU Yi-ming (周义明). Acta Petrologica Sinica (岩石学报), 2003, 19(2): 213.
[11] Schmidt C, Ziemann M A. American Mineralogist, 2000, 85: 1725.
[12] Kraft S, Knittle E, Williams Q. Journal of Geophysical Research-Solid Earth, 1991, 96: 17997. |
| [1] |
WANG Gan-lin1, LIU Qian1, LI Ding-ming1, YANG Su-liang1*, TIAN Guo-xin1, 2*. Quantitative Analysis of NO-3，SO2-4，ClO-4 With Water as Internal Standard by Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1855-1861. |
| [2] |
HUANG Bin, DU Gong-zhi, HOU Hua-yi*, HUANG Wen-juan, CHEN Xiang-bai*. Raman Spectroscopy Study of Reduced Nicotinamide Adenine Dinucleotide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1679-1683. |
| [3] |
ZHU Xiang1, 2*, YUAN Chao-sheng1, CHENG Xue-rui1, LI Tao1, ZHOU Song1, ZHANG Xin1, DONG Xing-bang1, LIANG Yong-fu2, WANG Zheng2. Study on Performances of Transmitting Pressure and Measuring Pressure of [C4mim][BF4] by Using Spectroscopic Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1674-1678. |
| [4] |
WANG Ming-xuan, WANG Qiao-yun*, PIAN Fei-fei, SHAN Peng, LI Zhi-gang, MA Zhen-he. Quantitative Analysis of Diabetic Blood Raman Spectroscopy Based on XGBoost[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1721-1727. |
| [5] |
YOU Gui-mei1, ZHANG Wen-jie1, CAO Zhen-wei2, HAN Xiang-na1*, GUO Hong1. Analysis of Pigments of Colored Paintings From Early Qing-Dynasty Fengxian Dian in the Forbidden City[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1874-1880. |
| [6] |
LI Qing1, 2, XU Li1, 2, PENG Shan-gui1, 2, LUO Xiao1, 2, ZHANG Rong-qin1, 2, YAN Zhu-yun3, WEN Yong-sheng1, 2*. Research on Identification of Danshen Origin Based on Micro-Focused
Raman Spectroscopy Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1774-1780. |
| [7] |
WANG Zhong, WAN Dong-dong, SHAN Chuang, LI Yue-e, ZHOU Qing-guo*. A Denoising Method Based on Back Propagation Neural Network for
Raman Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1553-1560. |
| [8] |
FU Qiu-yue1, FANG Xiang-lin1, ZHAO Yi2, QIU Xun1, WANG Peng1, LI Shao-xin1*. Research Progress of Pathogenic Bacteria and Their Drug Resistance
Detection Based on Surface Enhanced Raman Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1339-1345. |
| [9] |
YAN Ling-tong, LI Li, SUN He-yang, XU Qing, FENG Song-lin*. Spectrometric Investigation of Structure Hydroxyl in Traditional Ceramics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1361-1365. |
| [10] |
ZHAO Yong1, HE Men-yuan1, WANG Bo-lin2, ZHAO Rong2, MENG Zong1*. Classification of Mycoplasma Pneumoniae Strains Based on
One-Dimensional Convolutional Neural Network and
Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1439-1444. |
| [11] |
LI Meng-meng1, TENG Ya-jun2, TAN Hong-lin1, ZU En-dong1*. Study on Freshwater Cultured White Pearls From Anhui Province Based on Chromaticity and Raman Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1504-1507. |
| [12] |
JIAO Ruo-nan, LIU Kun*, KONG Fan-yi, WANG Ting, HAN Xue, LI Yong-jiang, SUN Chang-sen. Research on Coherent Anti-Stokes Raman Spectroscopy Detection of
Microplastics in Seawater and Sand[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1022-1027. |
| [13] |
ZHANG Li-sheng. Photocatalytic Properties Based on Graphene Substrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1058-1063. |
| [14] |
LÜ Yang, PEI Jing-cheng*, GAO Ya-ting, CHEN Bo-yu. Chemical Constituents and Spectra Characterization of Gem-Grade
Triplite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1204-1208. |
| [15] |
REN Yong-tian, HU Yi, CHEN Jun, CHEN Jun*. Study on Compressed Sensing Method for Raman Spectroscopic Analysis of Isotope Hydrogen Gas[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 776-782. |
|
|
|
|
