| 光谱学与光谱分析 |
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| Broad Excitation Band Alkaline-Earth Silicate Luminescent Materials Activated by Rare Earth and Its Applications |
| XIA Wei1,2,LEI Ming-kai1,LUO Xi-xian2,3,XIAO Zhi-guo2* |
1. School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024, China
2. Dalian Luminglight Sciences and Technology Co., Ltd, Dalian 116025, China
3. Optoelectronic Technology Institute, Dalian Maritime University, Dalian 116026, China |
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Abstract Series of novel broad excitation band phosphors M2MgSi2O7∶Eu, Dy(M=Ca, Sr) were prepared by a high temperature solid-state reaction method. The crystal structure of compound was characterized. And the effects of part substitution of alkaline-earth on crystal structure, photoluminescence spectra and luminescence properties were also investigated. It is found that the excitation band of silicate luminescent materials extend to visible region and they exhibit yellow, green and blue long afterglow luminescence after excited by ultraviolet or visible light. Ca2MgSi2O7∶Eu, Dy luminescent materials can be excited effectively under the 450-480 nm range and exhibit a strong emission at 536 nm, nicely combining with blue light emitted by InGaN chips to produce white light. This promises the silicate luminescent materials a potential yellow phosphor for white LED.
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Received: 2006-08-28
Accepted: 2006-12-26
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Corresponding Authors:
XIAO Zhi-guo
E-mail: dalianxiawei@126.com
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[1] LUO Xi-xian, CAO Wang-he, XIAO Zhi-guo. J. Alloys & Comp，2006，416(1-2): 250.
[2] XIAO Zhi-guo, LUO Xi-xian(肖志国，罗昔贤). Long Afterglow Luminescence Materials and the Related Applications(蓄光型发光材料及其制品). Beijing: Chemical Industry Press(北京：化学工业出版社)，2005. 309.
[3] LUO Xi-xian, ZHENG Xiao-quan, DUAN Jin-xia, et al(罗昔贤，郑孝全，段锦霞, 等). J. Chin. Ceram. Soc.(硅酸盐学报)，2003，31(11): 1058.
[4] Barry L. J. Electrochem. Soc., 1968, 115(7): 733.
[5] Barry L. J. Electrochem. Soc., 1970, 117(3): 381.
[6] XIAO Zhi-guo，XIAO Zhi-qiang(肖志国, 肖志强). China Patent(中国发明专利): ZL98105078. 6.
[7] XIAO Zhi-guo, LUO Xi-xian, XIA Wei, et al(肖志国，罗昔贤，夏 威，等). Chin. J. Rare Earth Soc.(中国稀土学报),2001，19(6): 561.
[8] Sabbagh Alvani A A，Moztarzadeh F，Sarabi A A. J. Lumin.,2005，115: 147.
[9] GENG Xiu-juan, CHEN Yong-jie, QIU Guan-ming, et al. J. Rare Earths,2005，23(3): 292.
[10] QI Ze-ming, SHI Chao-shu, LIU Miao, et al. Phys. Stat. Sol. (A),2004,201(14): 3109.
[11] ZHANG G B, QI Z M, ZHOU H J, et al. J. Electron Spectroscopy and Related Phenomena,2005, 144-147: 861.
[12] WANG Xiao-xin, LIN Yuan-hua, ZHANG Zhong-tai(王晓欣, 林元华, 张中太). J. Chin. Ceram. Soc.(硅酸盐学报),2002，30(2): 216.
[13] LUO Xi-xian, DUAN Jin-xia, LIN Guang-xu, et al(罗昔贤，段锦霞，林广旭, 等). Chin. J. Lumin.(发光学报),2003，24(2): 165.
[14] WU Ying，SHI Chun-shan(吴 郢，石春山). Chinese Rare Earth(稀土)，1994，15(5): 41.
[15] Douglas B E，McDaniel D H，Alexander J J. Concepts and Models of Inorganic Chemistry. New York: John Wiley and Sons Inc.，1994. 216.
[16] LIU Shao-xia, HE Da-wei, CHENG Zheng-wei, et al(刘少霞，何大伟，成正维，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2005，25(5): 665.
[17] Haranath D, Shanker Virendra, Chander Harish, et al. Materials Chemistry and Physics,2002, 78(1): 6.
[18] LUO Xi-xian, XIAO Zhi-guo, XIA Wei, et al. J. Rare Earths,2004,22(suppl.): 149.
[19] McKeever S W. Translated by CAI Gan-gang, WU Fang, WANG Suo-ting(蔡干钢，吴 方，王所亭, 译). Thermoluminescence of Solid(固体热释光). Beijing: Atomic Energy Press(北京：原子能出版社), 1993. 96.
[20] ZHANG Tian-zhi, SU Qiang(张天之，苏 锵). Chin. J. Lumin.(发光学报), 1999,20(2): 170.
[21] Qiu J, Minra K, Inouye H，et al. Appl. Phys. Lett., 1998, 73: 1763. |
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