|
|
|
|
|
|
| The Dating of 9 Batches of Authentic Os Draconis and the Correlation
Between the Age Range and the Ingredients |
| CHEN Di, SONG Chen, SONG Shan-shan, ZHANG Zhi-jie*, ZHANG Hai-yan |
Institute of Chinese Materia Medica，China Academy of Chinese Medical Sciences，Beijing 100700，China
|
|
|
|
|
Abstract In this paper, the carbon-14 dating was used, and 9 batches of Os Draconis samples correspond to the fossil age range: 3 batches of samples are between 18000 and 37000 years, and 6 batches of samples are 43500 years before. XRD and EPMA were used to determine the phase composition and elemental morphology of 9 batches of authentic Os Draconis. The main component of the Os Draconis was calcium hydroxyphosphate and some samples were hydroxyphosphate Symbiosis of calcium and calcium carbonate; the micro-phase is mainly hydroxyapatite, while calcium carbonate is mostly in the form of calcite-type calcium carbonate, and a small part is in the form of dolomite. The ARF, ICP-AES, ICP-MS, and AES were used to determine the element content of the samples. The results showed that the Ga/P ratio in the Os Draconis was greater than 2. The trace elements of the 9 batches of Os Draconis had approximately the same Distribution pattern: Sc, V, Cr, Co, Ni, Cu are all depleted relative to the original mantle, Ba, Sr, As are abnormally enriched, and element U is highly enriched; the distribution of rare earth elements in 9 batches of Os Draconis is also It has roughly the same distribution pattern, showing LREE enrichment type, with Ce negative anomaly, Eu partial positive anomaly, partial negative anomaly, LREE positive anomaly; 6 batches of Os Draconis before 43500 years, the total amount of rare earth elements is significantly higher The three batches of samples between 18000 and 37000 years are presumed to be related to their burial diagenetic environment on the one hand, and to the older the age, the higher the concentration of some elements.
|
|
Received: 2021-04-19
Accepted: 2023-05-10
|
|
|
|
Corresponding Authors:
ZHANG Zhi-jie
E-mail: zzjtcm@126.com; blbian@icmm.ac.cn
|
|
[1] Chinese Pharmacopoeia Commission(国家药典委员会). Pharmacopoeia of the People’s Republic of China(中华人民共和国药典). Part 1(一部). Beijing: China Medical Science Press(北京: 中国医药科技出版社), 1977. 1512.
[2] DU Yuan-sheng, TONG Jin-nan(杜远生，童金南). Introduction to Palaeontology and Historical Geology(古生物地史学概论). Wuhan: (武汉: 中国地质大学出版社), 1998. 4.
[3] LIU Jian-hua, CHEN Xin-hua, DING Yu-ting(刘建华，陈新华，丁玉庭). Food Science(食品科学), 2017, 38(13): 20.
[4] DENG Jian-guo, LIU Dong-liang, YE Yong, et al(邓建国，刘东亮，叶 勇，等). Journal of Nanjing University(Natural Sciences)[南京大学学报（自然科学版）], 2015, 37(1): 138.
[5] YANG Xiao-feng, WU Hai-zhen, YANG Xiao-yong, et al(杨晓峰，吴海珍，杨晓勇, 等). Chinese Rare Earths(稀土), 2000, 21(5): 23.
[6] YANG Lian-ju, HU Shi-lin, LI Xian-duan(杨连菊，胡世林，李先端). China Journal of Chinese Materia Medica(中国中药杂志), 1991, 16(9): 522.
[7] Mcdonough W F, Sun S S. Chemical Geology, 1995, 120(3-4): 223.
[8] KUANG Hong-wei, XU Ke-min, LIU Yong-qing, et al(旷红伟，许克民，柳永清，等). Geological Review(地质论评), 2013, 59(6): 1001.
[9] ZHANG Hui, LUO Ming-biao, XU Zhi-liang, et al(张 慧，罗明标，徐志良，等）. Hydrometallurgy of China（湿法冶金）, 2019, 38(5): 416.
[10] WANG Jiang-ke(王将克). Biogeochemistry(生物地球化学). Guangzhou: Guangdong Science & Technology Press (广州：广东科技出版社), 1999. 271.
[11] Sverjensky Dimitri A. Earth and Planetary Science Letters, 1984, 67(1): 70.
[12] MacRae N D, Nesbitt H W, Kronberg B I. Earth and Planetary Science Letters, 1992, 109(3-4): 585.
[13] WANG Zhong-gang, YU Xue-yuan, ZHAO Zhen-hua(王中刚，于学远，赵振华). Rare Earth Element Geochmistry(稀土元素地球化学). Beijing: Science Press(北京: 科学出版社), 1989. 90, 318.
[14] YANG Qun, WANG Yi-lin, YUAN Po, et al (杨 群，王怡林，袁 波, 等). Journal of Optoelectronics·Laser(光电子·激光), 2004, 15(11): 1365.
[15] YI Hai-sheng, LIN Jin-hui, ZHAO Xi-xi, et al(伊海生，林金辉，赵西西，等). Acta Sedimentologica Sinica(沉积学报), 2008，(1): 1.
[16] Sun S S, McDonough W F. Geological Society, London, Special Publications, 1989, 42(1): 313.
|
| [1] |
CAO Qin-yuan1, SHI Miao2, 3, 4*, MA Shi-yu2. Spectral Characteristics and Analysis of Main and Trace Elements of Scheelite From Xuebaoding[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(06): 1689-1696. |
| [2] |
HAN Xiang-na1, DAI Li-yang1, JIANG Shun-xing2, WANG Xiao-lin2, 3*. Study on the Weathering of a Dinosaur Fossil From Hami, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(04): 1106-1111. |
| [3] |
GU Yi-lu1, 2，PEI Jing-cheng1, 2*，ZHANG Yu-hui1, 2，YIN Xi-yan1, 2，YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
| [4] |
HE Yan1, TAO Ran1, YANG Ming-xing1, 2*. The Spectral and Technology Studies of Faience Beads Unearthed in Hubei Province During Warring States Period[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3700-3709. |
| [5] |
WANG Wei-en. Analysis of Trace Elements in Ophiocordyceps Sinensis From
Different Habitats[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3247-3251. |
| [6] |
WANG Yan1, HUANG Yi1, 2*, YANG Fan1, 2*, WU Zhong-wei2, 3, GUAN Yao4, XUE Fei1. The Origin and Geochemical Characteristics of the Hydrothermal Sediments From the 49.2°E—50.5°E Hydrothermal Fields of the Southwest Indian Ocean Ultra-Slow Spreading Ridge[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2868-2875. |
| [7] |
CHEN Chao-yang1, 2, LIU Cui-hong1, 2, LI Zhi-bin3, Andy Hsitien Shen1, 2*. Alexandrite Effect Origin of Gem Grade Diaspore[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2557-2562. |
| [8] |
ZHANG Hao-yu1, FU Biao1*, WANG Jiao1, MA Xiao-ling2, LUO Guang-qian1, YAO Hong1. Determination of Trace Rare Earth Elements in Coal Ash by Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2074-2081. |
| [9] |
HE Yan1, SU Yue1, YANG Ming-xing1, 2*. Study on Spectroscopy and Locality Characteristics of the Nephrites in Yutian, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3851-3857. |
| [10] |
JUMAHONG Yilizhati1, 2, TAN Xi-juan1, 2*, LIANG Ting1, 2, ZHOU Yi1, 2. Determination of Heavy Metals and Rare Earth Elements in Bottom Ash of Waste Incineration by ICP-MS With High-Pressure Closed
Digestion Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(10): 3168-3173. |
| [11] |
ZHU Zhao-zhou1*, YANG Xin-xin1, LI Jun1, HE Hui-jun2, ZHANG Zi-jing1, YAN Wen-rui1. Determination of Rare Earth Elements in High-Salt Water by ICP-MS
After Pre-Concentration Using a Chelating Resin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1862-1866. |
| [12] |
CHEN Chao-yang1，HUANG Wei-zhi1，SHAO Tian1，LI Zhi-bin2，Andy Hsitien Shen1*. Characteristics of Visible Spectrum of Apatite With Alexandrite Effect[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(05): 1483-1486. |
| [13] |
XU Jin-li1, 2, HU Meng-ying1, 2, ZHANG Peng-peng1, 2, XING Xia1, 2, BAI Jin-feng1, 2, ZHANG Qin1, 2*. Application of High Pressure Pelletised Sample and LIBS in the Determination of Rare Earth Elements in Soil Samples[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(12): 3806-3811. |
| [14] |
WANG Yi-ya1, GAO Xin-hua2, WANG Yi-min1*, DENG Sai-wen1, LI Song1. Review on the Literature of X-Ray Fluorescence Analysis of Rare Earth Elements in Geological Materials[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3341-3352. |
| [15] |
LIU Yan-de, GAO Xue, JIANG Xiao-gang, GAO Hai-gen, LIN Xiao-dong, ZHANG Yu, ZHENG Yi-lei. Detection of Anthracnose in Camellia Oleifera Based on Laser-Induced Breakdown Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(09): 2815-2820. |
|
|
|
|
