| 光谱学与光谱分析 |
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| Ethanol Electrooxidation on Carbon Supported PtSn Catalyst: In Situ TRFTIR Study |
| WANG Qi1,SUN Gong-quan1*,JIANG Lu-hua1,ZHU Ming-yuan1,WANG Guo-xiong1,XIN Qin1,SUN Shi-gang2, CHEN Qing-song2,JIANG Yan-xia2,CHEN Sheng-pei2 |
1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
2. State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, Xiamen University, Xiamen 361005, China |
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Abstract Carbon supported PtSn catalyst (PtSn/C) was prepared by a modified polyol method and characterized by means of XRD. It was showed that the metal particle size was 2.2 nm and the unit cell parameter increased compared with Pt/C. In situ time-resolved Fourier transform infrared spectroscopy (TRFTIRS) was used to study the electrooxidation of ethanol on PtSn/C catalyst. COL was the main poison species adsorbed on the active sites to inhibit the further reaction of ethanol electrooxidation. Acetaldehyde and acetic acid were found to be the products of ethanol electrooxidation as competing reactions with ethanol dissociation when the potential was up to 0.3 V, which reduced the poisoning effect. The selectivity of acetic acid among the products was improved with the increase in the potential and reaction time. CO2,which appeared at 0.4 V, was the final product and yielded from the oxidation of COL. The catalytic mechanism of PtSn/C towards ethanol electrooxidation was analyzed based on the results.
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Received: 2006-08-28
Accepted: 2006-11-28
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Corresponding Authors:
SUN Gong-quan
E-mail: gqsun@dicp.ac.cn
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