光谱学与光谱分析 |
|
|
|
|
|
Synthesis and Luminescence Properties of Ternary Complexes of Europium with Aromatic Carboxylic Acid and Acrylonitrile |
GUO Dong-cai1, 2, YI Li-ming1, SHU Wan-gen2, ZHANG Zhen-zhen1, ZENG Zhao-rong1, ZHANG Xi-qian1 |
1. School of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China 2. School of Chemistry and Chemical Engineering, Central Southern University, Changsha 410083, China |
|
|
Abstract Five ternary complexes were synthesized from europium with aromatic carboxylic acid(p-methylbenzoic acid, methoxybenzoic acid, m-chlorobenzoic acid and benzoic acid, p-hydroxylbenzoic acid) and acrylonitrile, and characterized by means of elemental analysis, thermal analysis, FTIR spectra and UV spectra. The fluorescence spectra show that five ternary complexes have good luminescence properties, and the sequence of the ability of the aromatic carboxylic acids to transfer light energy to europium ion is as follows: p-methylbenzoic acid>benzoic acid>m-chlorobenzoic acid>p-hydroxylbenzoic acid>methoxybenzoic acid. Meanwhile, the ternary europium complexes containing a reactive ligand acrylonitrile will possibly have a potential application to the fabrication of bonding-type europium polymer luminescent materials.
|
Received: 2005-08-26
Accepted: 2005-11-20
|
|
Corresponding Authors:
GUO Dong-cai
|
|
Cite this article: |
GUO Dong-cai,YI Li-ming,SHU Wan-gen, et al. Synthesis and Luminescence Properties of Ternary Complexes of Europium with Aromatic Carboxylic Acid and Acrylonitrile[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(11): 2003-2006.
|
|
|
|
URL: |
https://www.gpxygpfx.com/EN/Y2006/V26/I11/2003 |
[1] Chen Ye, Sun Xiaojun, Cai Weimin, et al. Materials Chemistry and Physics, 2003, 80: 371. [2] Wang Jun, Wang Haishui, Liu Fengyi, et al. Synthetic Metals, 2003, 139: 163. [3] Zhao Ying, Sun Bo, Xu Yizhuang, et al. Journal of Molecular Structure, 2001, 560: 115. [4] WANG Xi-gui, WU Hong-ying, YAO Guang-qing, et al(王喜贵, 吴红英, 姚光庆, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析),2004,24(6):708. [5] LI Yong-xiu,LIU Ting,MIN Yu-lin, et al(李永绣, 刘 婷, 闵宇霖,等). Chinese Journal of Luminescence(发光学报),2003,24(2): 152. [6] GAO Xin,DENG Zhen-bo,TAO Dong-liang,et al(高 新, 邓振波, 陶栋梁, 等). Journal of the Chinese Rare Earth Society(中国稀土学报),2001,19(6):536. [7] SI Hang(司 航主编). Organic Chemical Materials(有机化工原料·第3版). Beijing: Chemical Industry Press(北京:化学工业出版社), 1999. 101. [8] Nakanshi Koji, Solomon P H. Infrared Absorption Spectroscopic Analysis(红外光谱分析100例). Translated by WANG Xu-ming(王绪明译). Beijing: Science Press(北京:科学出版社), 1984. 18. [9] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds(无机和配位化合物的红外拉曼光谱). Translated by HUANG De-ru,WANG Ren-qing(黄德如, 汪仁庆, 译). Beijing: Chemical Industry Press(北京:化学工业出版社), 1986. 237. [10] CHEN Jing-hong,LI Chuan-ru(陈镜泓, 李传儒, 著). Thermal Analysis and Its Application(热分析及其应用). Beijing: Science Press(北京:科学出版社), 1985. 16. [11] Berg L A. In Differential Thermal Analysis, Edited by Mackenzie R C. Vol. 1, Chap. 11. London: Academic Press, 1970. 343.
|
[1] |
GU Yi-lu1, 2,PEI Jing-cheng1, 2*,ZHANG Yu-hui1, 2,YIN Xi-yan1, 2,YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
[2] |
ZHOU Bei-bei1, LI Heng-kai1*, LONG Bei-ping2. Variation Analysis of Spectral Characteristics of Reclaimed Vegetation in an Ionic Rare Earth Mining Area[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3946-3954. |
[3] |
LAI Niu, HUANG Qi-qiang, ZHANG Qin-yang, ZHANG Bo-wen, WANG Juan, YANG Jie, WANG Chong, YANG Yu, WANG Rong-fei*. Introduction to Perovskite Quantum Dots and Metal-Organic Frameworks and the Development of Composites[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3321-3329. |
[4] |
DING Han. Background-Free Development of Latent Fingerprints on Fluorescent
Substrates[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3427-3435. |
[5] |
QIN Li-mei, Andy Hsitien Shen*. Photoluminescence Spectral Characteristics of Jet From Fushun, Liaoning Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3180-3185. |
[6] |
ZHANG Hao-yu1, FU Biao1*, WANG Jiao1, MA Xiao-ling2, LUO Guang-qian1, YAO Hong1. Determination of Trace Rare Earth Elements in Coal Ash by Inductively Coupled Plasma Tandem Mass Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2074-2081. |
[7] |
ZHU Hong-wei1, CHENG You-fa1, CHEN Shu-xiang2*, FAN Chun-li1, LI Ting1, LIU Hai-bin1, ZHAO Xiao-xue1SHAN Guang-qi1, LI Jian-jun1. Spectroscopic Characteristics of a Natural Diamond Suspected of Synthetic Diamond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1690-1696. |
[8] |
YAN Xue-jun1, ZHOU Yang2, HU Dan-jing1, YU Dan-yan1, YU Si-yi1, YAN Jun1*. Application of UV-VIS Diffuse Reflectance Spectrum, Raman and
Photoluminescence Spectrum Technology in Nondestructive
Testing of Yellow Pearl[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1703-1710. |
[9] |
CHEN Di, SONG Chen, SONG Shan-shan, ZHANG Zhi-jie*, ZHANG Hai-yan. The Dating of 9 Batches of Authentic Os Draconis and the Correlation
Between the Age Range and the Ingredients[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1900-1904. |
[10] |
HAN Zhao-xia1, 2, 3*, YANG Zhi-jin1, ZHANG Zhi-hong1, DING Shu-hui1, ZHANG Da-wei1, 2, 3, HONG Rui-jin1, 2, 3, TAO Chun-xian1, 2, 3, LIN Hui1, 2, 3, YU De-chao1, 2, 3. Preparation of Full-Color Carbon Quantum Dots and Their Application in WLED[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1358-1366. |
[11] |
CI Cheng-gang*, ZANG Jie-chao, LI Ming-fei*. DFT Study on Spectra of Mn-Carbonyl Molecular Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1434-1441. |
[12] |
LI Zhao, WANG Ya-nan, XU Yi-pu, CAO Jing, WANG Yong-feng, WU Kun-yao, DENG Lu. Synthesis and Photoluminescence of Blue-Emitting Phosphor
YVO4∶Tm3+ for White Light Emitting Diodes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 623-628. |
[13] |
ZHAI Yan-ke1, PAN Yi-xing1, XIANG Hao1, XU Li1*, ZHU Ze-ce2, LEI Mi1. Coordination Interaction of DSAZn With Quercetin and High Sensitivity Detection of Quercetin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 122-128. |
[14] |
HE Yan1, SU Yue1, YANG Ming-xing1, 2*. Study on Spectroscopy and Locality Characteristics of the Nephrites in Yutian, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3851-3857. |
[15] |
ZHAO Guo-qiang1, QIU Meng-lin1*, ZHANG Jin-fu1, WANG Ting-shun1, WANG Guang-fu1, 2*. Peak Splitting Method of Ion-Beam-Induced-Luminescence Spectrum Based on Voigt Function Fitting[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3512-3518. |
|
|
|
|