|
|
|
|
|
|
Identification of Adulterated Olive Oil by Two-Dimensional Raman Correlation Spectroscopy With Cooming as a Perturbation Factor |
YU Ying-tao1, WANG Ji-feng1, SUN Yu-ye1, LI Fu-juan2, WAN Chao3 |
1. College of Environmental Science & Engineering, Dalian Maritime University, Dalian 116026, China
2. North China Sea Environmental Monitoring Center, State Oceanic Administration, Qingdao 266033, China
3. Inspection and Quarantine Technology Center, Dalian Customs District P. R. China, Dalian 116001, China |
|
|
Abstract The doping of inferior or low-priced oils into the edible oil infringes consumers’ rights and harms public health. Therefore, the anti-counterfeiting identification of edible oils is of great significance. When the content of counterfeit components in the adulterated oil decreases, the similarity between the genuine oil and the adulterated oil becomes higher so that the identification of low-doping oil is generally difficult. In this paper, synchronous two-dimensional Raman correlation spectroscopy with cooling as a perturbation factor was used for the identification of the pure and the low-doping (5%, 10%, 20%) olive oils. Soybean oil with high similarity to the olive oil was selected as a counterfeit component. In the range of 15 to 0 centigrade degree, the Raman spectra of the pure and the adulterated olive oils were similar and changed slightly when the temperature decreased. The characteristic peaks appeared at 2 850,2 874,2 906,2 933,2 958,3 005 cm-1. The characteristic peak at 2 850 cm-1 corresponding to the symmetric stretching vibration of methylene (CH2) was the strongest peak. When the temperature dropped below 0 centigrade degree, the Raman spectra of the pure and the adulterated olive oils changed significantly along with the decrease of temperature. In the range of -5 to -20 centigrade degree, the characteristic peaks appeared around 2 848, 2 883, 2 933, 2 956, 3 005 cm-1. The peak at 2 848 cm-1 was attributed to the redshift of the peak (2 850 cm-1) of the symmetric stretching vibration of CH2, and its relative peak strength decreased with the dropping of temperature; meanwhile, the peak at 2 883 cm-1 corresponding to the asymmetrical stretching vibration of CH2 gradually increased and became the strongest peak. Synchronous two-dimensional Raman correlation spectra showed that the strength of the auto peak around 2 925 cm-1 and that of the negative cross peak at (2 925, 2 883 cm-1) remarkably decreased with the increase of doping ratio, and the two-dimensional spectral difference among the pure and the low-doping (5%, 10%, 20%) olive oils was significant. Hierarchical clustering analysis based on the synchronous two-dimensional Raman correlation spectra showed that the blind samples of the pure and the low-doping olive oils were all accurately identified. Synchronous two-dimensional Raman correlation spectroscopy with cooling as a perturbation factor is efficient to distinguish the low-doping oils from the genuine olive oil and can be also helpful for the identification of other kinds of oils.
|
Received: 2019-10-25
Accepted: 2020-02-12
|
|
|
[1] Menezes D B, Reyer A, Musso M. Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 2018, 190: 433.
[2] Suzuki Y, Furuya H. Journal of Peptide Science, 2018, 24(4-5):e3079.
[3] Osiecka N, Galewski Z, Juszynska-Galazka E, et al. Journal of Molecular Liquids, 2016, 224: 677.
[4] Qiu C, Arzhantsev S. Analytical Biochemistry, 2018, 555: 26.
[5] Xiao Q, Sui H, Yu Q, et al. Propellants Explosives Pyrotechnics, 2019, 44(11): 1375.
[6] Yan R, Chen J B, Sun S Q, et al. Journal of Molecular Structure, 2016, 1124: 110.
[7] Chen J B, Wang Y, Rong L X, et al. Journal of Molecular Structure, 2018, 1163: 327.
[8] Chen J B, Wang Y, Liu A X, et al. Journal of Molecular Structure, 2018, 1155: 681.
[9] XU Bei-lei, SUN Su-qin, ZHANG Gui-jun, et al(徐蓓蕾, 孙素琴, 张贵君, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2018, 38(3): 800.
[10] Zhang Z Y, Sha M, Wang H Y. Journal of Raman Spectroscopy, 2017, 48 (8): 1111.
[11] Philippidis A, Poulakis E, Papadaki A, et al. Analytical Letters, 2016, 50(7): 1182.
[12] Li Y P, Fang T, Zhu S Q, et al. Spectrochimica Acta Part A-Molecular and Biomolecular Spectroscopy, 2018, 189: 37. |
[1] |
LI Jie, ZHOU Qu*, JIA Lu-fen, CUI Xiao-sen. Comparative Study on Detection Methods of Furfural in Transformer Oil Based on IR and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 125-133. |
[2] |
WANG Fang-yuan1, 2, HAN Sen1, 2, YE Song1, 2, YIN Shan1, 2, LI Shu1, 2, WANG Xin-qiang1, 2*. A DFT Method to Study the Structure and Raman Spectra of Lignin
Monomer and Dimer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 76-81. |
[3] |
XING Hai-bo1, ZHENG Bo-wen1, LI Xin-yue1, HUANG Bo-tao2, XIANG Xiao2, HU Xiao-jun1*. Colorimetric and SERS Dual-Channel Sensing Detection of Pyrene in
Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 95-102. |
[4] |
WANG Xin-qiang1, 3, CHU Pei-zhu1, 3, XIONG Wei2, 4, YE Song1, 3, GAN Yong-ying1, 3, ZHANG Wen-tao1, 3, LI Shu1, 3, WANG Fang-yuan1, 3*. Study on Monomer Simulation of Cellulose Raman Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 164-168. |
[5] |
GUO Ya-fei1, CAO Qiang1, YE Lei-lei1, ZHANG Cheng-yuan1, KOU Ren-bo1, WANG Jun-mei1, GUO Mei1, 2*. Double Index Sequence Analysis of FTIR and Anti-Inflammatory Spectrum Effect Relationship of Rheum Tanguticum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 188-196. |
[6] |
WANG Lan-hua1, 2, CHEN Yi-lin1*, FU Xue-hai1, JIAN Kuo3, YANG Tian-yu1, 2, ZHANG Bo1, 4, HONG Yong1, WANG Wen-feng1. Comparative Study on Maceral Composition and Raman Spectroscopy of Jet From Fushun City, Liaoning Province and Jimsar County, Xinjiang Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 292-300. |
[7] |
LI Wei1, TAN Feng2*, ZHANG Wei1, GAO Lu-si3, LI Jin-shan4. Application of Improved Random Frog Algorithm in Fast Identification of Soybean Varieties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3763-3769. |
[8] |
WANG Zhi-qiang1, CHENG Yan-xin1, ZHANG Rui-ting1, MA Lin1, GAO Peng1, LIN Ke1, 2*. Rapid Detection and Analysis of Chinese Liquor Quality by Raman
Spectroscopy Combined With Fluorescence Background[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3770-3774. |
[9] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
[10] |
LIU Hao-dong1, 2, JIANG Xi-quan1, 2, NIU Hao1, 2, LIU Yu-bo1, LI Hui2, LIU Yuan2, Wei Zhang2, LI Lu-yan1, CHEN Ting1,ZHAO Yan-jie1*,NI Jia-sheng2*. Quantitative Analysis of Ethanol Based on Laser Raman Spectroscopy Normalization Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3820-3825. |
[11] |
LU Wen-jing, FANG Ya-ping, LIN Tai-feng, WANG Hui-qin, ZHENG Da-wei, ZHANG Ping*. Rapid Identification of the Raman Phenotypes of Breast Cancer Cell
Derived Exosomes and the Relationship With Maternal Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3840-3846. |
[12] |
LI Qi-chen1, 2, LI Min-zan1, 2*, YANG Wei2, 3, SUN Hong2, 3, ZHANG Yao1, 3. Quantitative Analysis of Water-Soluble Phosphorous Based on Raman
Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3871-3876. |
[13] |
GUO He-yuanxi1, LI Li-jun1*, FENG Jun1, 2*, LIN Xin1, LI Rui1. A SERS-Aptsensor for Detection of Chloramphenicol Based on DNA Hybridization Indicator and Silver Nanorod Array Chip[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3445-3451. |
[14] |
ZHU Hua-dong1, 2, 3, ZHANG Si-qi1, 2, 3, TANG Chun-jie1, 2, 3. Research and Application of On-Line Analysis of CO2 and H2S in Natural Gas Feed Gas by Laser Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3551-3558. |
[15] |
XU Rong1, AO Dong-mei2*, LI Man-tian1, 2, LIU Sai1, GUO Kun1, HU Ying2, YANG Chun-mei2, XU Chang-qing1. Study on Traditional Chinese Medicine of Lonicera L. Based on Infrared Spectroscopy and Cluster Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3518-3523. |
|
|
|
|