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| A Study on the Non-Destructive Method of Identifying Chinese Traditional Handmade Paper With Attenuated Total Reflection Fourier Transform Infrared Spectroscopy |
| LÜ Shu-xian |
Peking University Library, Beijing 100871，China
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Abstract Fiber identification is an important work in preserving ancient paper. Exploring a non-destructive fiber identification method of Chinese traditional handmade paper is significant to the research and preservation of ancient Chinese books, archives, and paper cultural relics. In this study, Attenuated Total Reflection Fourier Transform Infrared Spectroscopy (ATR-FTIR) was used to analyze 64 standard Chinese traditional handmade paper samples of 17 categories whose fiber compositions were known.First, the main components in the paper and the attribution of all the infrared peaks were confirmed by referring to the infrared peaks of cellulose and lignin, as well as the X-ray diffraction (XRD) analysis results of some paper samples. Then, the comparative analysis of the spectra with very high similarity was carried out to summarize the spectral characteristics of various kinds of paper in the four bands of 4 000~1 800, 1 800~1 500, 1 500~1 200 and 1 200~600 cm-1, respectively. At the same time, by second derivative processing, the second derivative spectrum characteristics of each kind of paper were summarized in the bands of 1 500~1 200 and 1 200~900 cm-1, respectively. Finally, through the numerical calculation results, such as the infrared cry stallinity index and the ratios of the peak heights and the peak areas, a more detailed distinction among different kinds of paper was achieved. The above method was used for a blind test of 16 unknown samples, and the results of the infrared analysis were consistent with the results of the microscopic fiber analysis, which preliminarily proved the feasibility and effectiveness of this method. All the experimental results show that the non-destructive analysis method of ATR-FTIR can be used to make fast and accurate identification of the fiber type of hemp paper, mulberry paper, Wingceltis paper, Xuan paper, Thymelaeaceae paper and bamboo paper, but this method still has some limitations for the identification of the plant materials With closer genetic relationships,such as mulberry and paper mulberry, which are also difficult to distinguish through microscopic analysis.
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Received: 2022-06-22
Accepted: 2023-12-05
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Corresponding Authors:
LÜ Shu-xian
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[1] YAN Chun-sheng, HUANG Chen, HAN Song-tao, et al（阎春生, 黄 晨, 韩松涛, 等）. Chinese Optics（中国光学）, 2020, 13（5）: 936.
[2] LUO Xi-yun, DU Yi-ping, SHEN Mei-hua, et al（罗曦芸, 杜一平, 沈美华, 等）. Spectroscopy and Spectral Analysis（光谱学与光谱分析）, 2015, 35(1): 60.
[3] Yan Yueer, Wen Chenqing, Jin Ming, et al. Chemical Research in Chinese Universities, 2019, 35(4): 586.
[4] Xia Jingjing, Zhang Jixiong, Zhao Yueting, et al. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2019(219): 8.
[5] ZHANG Xu, YAN Yue-er, YANG Guang-hui, et al（张 旭, 闫玥儿, 杨光辉, 等）. Journal of Fudan University (Natural Science)[复旦学报（自然科学版）], 2021, 60(5): 655.
[6] PEI Ji-cheng（裴继诚主编）. Lignocellulosic Chemistry（植物纤维化学）. Beijing：China Light Industry Press（北京：中国轻工业出版社）, 2020. 69.
[7] Liu Xinyou, Timar M C, Varodi A M, et al. Wood Sci. Technol., 2017, 51(2): 357.
[8] Cichosz S，Masek A. Materials, 2020, 13(20): 4573.
[9] Poletto M，Ornaghi Júnior H L，Zattera A J. Materials, 2014, 7: 6105.
[10] Lee C M，Kubicki J D，Fan B，et al. The Journal of Physical Chemistry. B, 2015, 119: 15138.
[11] LÜ Shu-xian（吕淑贤）. Sciences of Conservation and Archaeology（文物保护与考古科学）, 2023, 35(2): 26.
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