光谱学与光谱分析 |
|
|
|
|
|
Research Progress of Raman Spectroscopy on Dyestuff Identification of Ancient Relics and Artifacts |
HE Qiu-ju1, 2, WANG Li-qin1* |
1. College of Cultural Heritage,Key Laboratory of Culture Heritage Research and Conservation (Northwest University),Ministry of Education,Xi’an 710069,China 2. Centre for the Conservation and Restoration of Cultural Heritage,Capital Museum,Beijing 100045,China |
|
|
Abstract As the birthplace of Silk Road, China has a long dyeing history. The valuable information about the production time,the source of dyeing material,dyeing process and preservation status were existed in organic dyestuff deriving from cultural relics and artifacts. However,because of the low contents,complex compositions and easily degraded of dyestuff,it is always a challenging task to identify the dyestuff in relics analyzing field. As a finger-print spectrum,Raman spectroscopy owns unique superiorities in dyestuff identification. Thus,the principle,characteristic,limitation,progress and development direction of micro-Raman spectroscopy (MRS/μ-Raman),near infrared reflection and Fourier transform Raman spectroscopy (NIR-FT-Raman), surface-enhanced Raman spectroscopy (SERS) and resonance raman spectroscopy (RRS) have been introduced in this paper. Furthermore, the features of Raman spectra of gardenia,curcumin and other natural dyestuffs were classified by MRS technology, and then the fluorescence phenomena of purpurin excitated with different wavelength laser was compared and analyzed. At last, gray green silver colloidal particles were made as the base,then the colorant of madder was identified combining with thin layer chromatography (TLC) separation technology and SERS,the result showed that the surface enhancement effect of silver colloidal particles could significantly reduce fluorescence background of the Raman spectra. It is pointed out that Raman spectroscopy is a rapid and convenient molecular structure qualitative methodology,which has broad application prospect in dyestuff analysis of cultural relics and artifacts. We propose that the combination of multi-Raman spectroscopy, separation technology and long distance transmission technology are the development trends of Raman spectroscopy.
|
Received: 2015-01-03
Accepted: 2015-04-25
|
|
Corresponding Authors:
WANG Li-qin
E-mail: wangliqin@nwn.edu.cn
|
|
[1] Degano I,Ribechini E,Modugno F,et al. Applied Spectroscopy Reviews,2009,44(5): 363. [2] Liu Jian,Guo Danhua,Zhou Yang,et al. Journal of Archaeological Science,2011,38: 1763. [3] Gulmini M,Idone A,Diana E,et al. Dyes and Pigments,2013,98: 136. [4] Vandenabeele P,Moens L,Edwards H,et al. Journal of Raman Spectroscopy,2000,31: 509. [5] Bell I M,Clark R J H,Gibbs P J,et al. Spectrochimica Acta A,1997,53: 2159. [6] Burgio L,Clark R J H. Spectrochimica Acta A,2001,57: 1491. [7] Chen Kui,Marco Leona,Tuan VoDinh. Sensor Review,2007,27(2): 109. [8] Efremov E V,Ariese F,Gooijer C. Analytica Chimica Acta, 2008, 606: 119. [9] Smith G G D,Clark R J H. Journal of Archaeological Science,2004,31: 1137. [10] Lenain B P. Analusis,2000,28: 11. [11] Clark R J H,Gibbs P J. Journal of Archaeological Science,1998,25: 621. [12] Burgio L,Clark R J H. Journal of Raman Spectroscopy,2000,31: 395. [13] Whitney A,Duyne R,Casadio F. Journal of Raman Spectroscopy,2006,37: 993. [14] Leona M,Stenger J,Ferloni E. Journal of Raman Spectroscopy,2006,37: 981. [15] Asher S A,Munro C H,Chi Z. Laser Focus World,1997: 99. [16] Harvey S D,Peters T J,Wright B W,et al. Applied Spectroscopy,2003 (57): 580. [17] Paris C,Coupry C. Journal of Raman Spectroscopy,2005,36: 77. [18] Schulte F,Brzezinka K,Lutzenberger K,et al. Journal of Raman Spectroscopy,2008,39: 1455. [19] Andreev G N,Schulz H,Fuchs R,et al. Journal of Analytical Chemistry,2001,371: 1009. [20] Daher C,Drieu L,Bellot-Gurlet L,et al. Journal of Raman Spectroscopy,2014,45: 1207. [21] Fleischmann M,Hendra P J,Mcquillan A J. Chemical Physics Letters,1974,26(2): 163. [22] Caamares M V,Garcia-Ramos J V,Domingo C,e al. Journal of Raman Spectroscopy,2008,39: 1309. [23] Whitney A V,Duyne R,Casadio F J. Journal of Raman Spectroscopy,2006,37: 993. [24] Chen Kui,Vo-Dinh Kim-Chi,Yan Fei,et al. Analytica Chimica Acta,2006,569: 234. [25] Chen Kui,Leona M,Vo-Dinh Kim-Chi,et al. Journal of Raman Spectroscopy,2006,37: 520. [26] Leona M,Lombardi J R. Journal of Raman Spectroscopy,2007,38: 853. [27] Doherty B,Brunetti B G,Sgamellotti A,et al. Journal of Raman Spectroscopy,2011,42: 1932. [28] Caamares M V,Garcia-Ramos J V,Domingo C,et al. Journal of Raman Spectroscopy,2004,35: 921. [29] Robert B. Photosynthesis Research,2009,101: 147. [30] Shadi I T,Chowdhry B Z,Snowden M J,et al. Journal of Raman Spectroscopy,2004,35: 800. [31] Rosi F,Clementi C,Paolantoni M,et al. Journal of Raman Spectroscopy,2013,44: 1451. [32] Clementi C, Miliani C, Romani A,et al. Spectrochim. Acta Part A,2006,64: 906. [33] Bell S,Bourguignon E,Grady A,et al. Spectroscopy Europe,2002,14(6): 17. [34] Bell S,Edwards H,Chalmers J,et al. Royal Society for Chemistry, Cambridge,2005,292. [35] Zaffino C,Bruni S,Guglielmi V. Journal of Raman Spectroscopy,2014,45: 211. [36] GONG Yan,LU Yong-kai,LIN Su-jun,et al(龚 ,卢永凯,林素君,等). Chemistry(化学通报),2010,(8): 689. [37] Chen Jing,Abell J,Huang Yaowen. Lab on a Chip,2012,12: 3096. [38] Caamares M V,Reagan D A,Lombardi J R,et al. Journal of Raman Spectroscopy,2014,45: 1147. [39] XU Wei-qing,XU Shu-ping,HU Bing,et al(徐蔚青,徐抒平,胡 冰,等). Chemical Journal of Chinese Universities(高等学校化学学报),2004,25(1) : 144. [40] Stokes D L,VoDinh T. Sensors and Actuators B: Chemical,2000,69 (1): 28. |
[1] |
WANG Gan-lin1, LIU Qian1, LI Ding-ming1, YANG Su-liang1*, TIAN Guo-xin1, 2*. Quantitative Analysis of NO-3,SO2-4,ClO-4 With Water as Internal Standard by Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1855-1861. |
[2] |
HUANG Bin, DU Gong-zhi, HOU Hua-yi*, HUANG Wen-juan, CHEN Xiang-bai*. Raman Spectroscopy Study of Reduced Nicotinamide Adenine Dinucleotide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1679-1683. |
[3] |
ZHU Xiang1, 2*, YUAN Chao-sheng1, CHENG Xue-rui1, LI Tao1, ZHOU Song1, ZHANG Xin1, DONG Xing-bang1, LIANG Yong-fu2, WANG Zheng2. Study on Performances of Transmitting Pressure and Measuring Pressure of [C4mim][BF4] by Using Spectroscopic Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1674-1678. |
[4] |
WANG Ming-xuan, WANG Qiao-yun*, PIAN Fei-fei, SHAN Peng, LI Zhi-gang, MA Zhen-he. Quantitative Analysis of Diabetic Blood Raman Spectroscopy Based on XGBoost[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1721-1727. |
[5] |
YOU Gui-mei1, ZHANG Wen-jie1, CAO Zhen-wei2, HAN Xiang-na1*, GUO Hong1. Analysis of Pigments of Colored Paintings From Early Qing-Dynasty Fengxian Dian in the Forbidden City[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1874-1880. |
[6] |
LI Qing1, 2, XU Li1, 2, PENG Shan-gui1, 2, LUO Xiao1, 2, ZHANG Rong-qin1, 2, YAN Zhu-yun3, WEN Yong-sheng1, 2*. Research on Identification of Danshen Origin Based on Micro-Focused
Raman Spectroscopy Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1774-1780. |
[7] |
WANG Zhong, WAN Dong-dong, SHAN Chuang, LI Yue-e, ZHOU Qing-guo*. A Denoising Method Based on Back Propagation Neural Network for
Raman Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1553-1560. |
[8] |
FU Qiu-yue1, FANG Xiang-lin1, ZHAO Yi2, QIU Xun1, WANG Peng1, LI Shao-xin1*. Research Progress of Pathogenic Bacteria and Their Drug Resistance
Detection Based on Surface Enhanced Raman Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1339-1345. |
[9] |
YAN Ling-tong, LI Li, SUN He-yang, XU Qing, FENG Song-lin*. Spectrometric Investigation of Structure Hydroxyl in Traditional Ceramics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1361-1365. |
[10] |
ZHAO Yong1, HE Men-yuan1, WANG Bo-lin2, ZHAO Rong2, MENG Zong1*. Classification of Mycoplasma Pneumoniae Strains Based on
One-Dimensional Convolutional Neural Network and
Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1439-1444. |
[11] |
LI Meng-meng1, TENG Ya-jun2, TAN Hong-lin1, ZU En-dong1*. Study on Freshwater Cultured White Pearls From Anhui Province Based on Chromaticity and Raman Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1504-1507. |
[12] |
DAI Ruo-chen1, TANG Huan2*, TANG Bin1*, ZHAO Ming-fu1, DAI Li-yong1, ZHAO Ya3, LONG Zou-rong1, ZHONG Nian-bing1. Study on Detection Method of Foxing on Paper Artifacts Based on
Hyperspectral Imaging Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1567-1571. |
[13] |
LI De-hui1, WU Tai-xia1*, WANG Shu-dong2*, LI Zhe-hua1, TIAN Yi-wei1, FEI Xiao-long1, LIU Yang1, LEI Yong3, LI Guang-hua3. Hyperspectral Indices for Identification of Red Pigments Used in Cultural Relic[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1588-1594. |
[14] |
JIAO Ruo-nan, LIU Kun*, KONG Fan-yi, WANG Ting, HAN Xue, LI Yong-jiang, SUN Chang-sen. Research on Coherent Anti-Stokes Raman Spectroscopy Detection of
Microplastics in Seawater and Sand[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1022-1027. |
[15] |
ZHANG Li-sheng. Photocatalytic Properties Based on Graphene Substrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1058-1063. |
|
|
|
|