| 光谱学与光谱分析 |
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| Effect of Temperature on the Structure of CaO-MgO-Al2O3-SiO2 Nanocrystalline Glass-Ceramics Studied by Raman Spectroscopy |
| LI Bao-wei1, OUYANG Shun-li1*, ZHANG Xue-feng1, JIA Xiao-lin1,2, DENG Lei-bo1, LIU Fang1 |
1. Key Laboratory of Integrated Exploitation of Bayan Obo Multi-Metal Resources, Inner Mongolia University of Science and Technology, Baotou 014010, China
2. College of Materials Science & Engineering，Zhengzhou University，Zhengzhou 450052, China |
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Abstract In the present paper, nanocrystalline glass-ceramic of CaO-MgO-Al2O3-SiO2 system was produced by melting method. The CaO-MgO-Al2O3-SiO2 nanocrystalline glass-ceramic was measured by Raman spectroscopy in the temperature range from -190 to 310 ℃ in order to study the effect of temperature on the structure of this system nanocrystalline glass-ceramics. The results showed that different non-bridge oxygen bond silicon-oxygen tetrahedron structural unit changes are not consistent with rising temperature. Further analyses indicated that: the SiO4 tetrahedron with 2 non-bridged oxygen (Q2), the SiO4 tetrahedron with 3 non-bridged oxygen (Q1), which are situated at the edge of the 3-D SiO4 tetrahedrons network, and the SiO4 tetrahedron with 4 non-bridged oxygen (Q0), which is situated outside the 3-D network all suffered a significant influence by the temperature change, which has been expressed as: shifts towards the high wave-number, increased bond force constants, and shortened bond lengths. This paper studied the influence of temperature on CMAS system nanocrystalline glass-ceramics using variable temperature Raman technology. It provides experiment basis to the research on external environment influence on CMAS system nanocrystalline glass-ceramics materials in terms of structure and performance. In addition, the research provides experimental basis for controlling the expansion coefficient of nanocrystalline glass-ceramic of CaO-MgO-Al2O3-SiO2 system.
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Received: 2013-09-01
Accepted: 2014-01-09
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Corresponding Authors:
OUYANG Shun-li
E-mail: ouyangshunli@imust.cn
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