| 光谱学与光谱分析 |
|
|
|
|
|
| Study on the Eu-containing Coordination Polymer Ⅰ.Structural Characterization of Eu(Ⅲ)-thienyltrifluroacetone-poly (Styrene-acrylic acid) |
| XIAO Li-ren, GAO Feng, TANG Jie-yuan, ZHANG Wen-gong* |
| Institute of Polymer Science, Fujian Normal University, Fuzhou 350007, China |
|
|
|
|
Abstract Three samples (a), (b) and (c) of luminescent Eu-containing copolymer (NaEu(Ⅲ)-TTA-PSAA) were synthesized through the reaction of copolymer of acrylic acid and styrene (Mw＝3 000) with metalorganic complex (NaEu(TTA)4) obtained from Eu and thienyltrifluroacetone. These samples of coordination polymers were characterized by FTIR, UV and XPS, and their composition and structures were determined. The results of electrical conductivity methods and elemental analysis indicated that there were different compositions and structures of these coordination polymers in different pH. The results of elemental analysis also showed that the content of Eu3+ in sample (a), (b) and (c) was 11.89%，12.55% and 13.41%, respectively.
|
|
Received: 2002-11-18
Accepted: 2003-02-18
|
|
|
|
Corresponding Authors:
ZHANG Wen-gong
|
|
| Cite this article: |
|
XIAO Li-ren,GAO Feng,TANG Jie-yuan, et al. Study on the Eu-containing Coordination Polymer Ⅰ.Structural Characterization of Eu(Ⅲ)-thienyltrifluroacetone-poly (Styrene-acrylic acid) [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(06): 756-761.
|
|
|
|
| URL: |
|
http://www.gpxygpfx.com/EN/Y2004/V24/I06/756 |
[1] Turner S, Kahn O, Rabardel O. J. Am. Chem. Soc., 1996, 116: 6428.
[2] Edwards A, Claude C, Sokolik I et al. J. Appl. Phys., 1997, 82(4): 1841.
[3] Buno-Core G E, Li H, Marcinika B Coond. Chem. Rev., 1990, 99: 55.
[4] Wang L H, Wang W, Zhang W G et al. Chem. Mater, 2000, 12: 2212.
[5] Wollf N E, Ressley R. J. Appl. Phys. Lett., 1963, 2: 152.
[6] Okamoto Y, Kido J. Mat. Res. Soc. Symp. Proc., 1992, 277: 65.
[7] Okamoto Y, Ueba Y, Dzhanibekov N F et al. Marcromolecules, 1981, 14: 17.
[8] TANG Jie-yuan, ZHANG Wen-gong(唐洁渊，章文贡). Chinese J. of Acta Polymerca Sinica(高分子学报)，2001，(4)： 480.
[9] CHENG Chuan-xuan(程传煊). Physical Chemistry of Surface(表面物理化学). Beijing(北京)： Science Technology Document Press(科学技术文献出版社)，1995. 667.
|
| [1] |
LIN Shun-hui，ZHANG Li-hui, LIU Yong-quan, WANG Xiao-kun, LIN Chun-lei, YU Yun-peng*. Thermal Annealing Effect on Photoluminescence of Y2O3∶Eu3+ Thin Films Prepared by Magnetron Sputtering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(11): 3336-3340. |
| [2] |
WANG Yu1, LUO Lan1, 2*, GUO Rui1, SUN Chuan-yao1, GAO Ming-yuan1. Cation Substitution-Dependent Phase Transition and Color-Tunable Emission in (Ca1-xBax)2SiO4∶Eu Phosphor Series[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(06): 1895-1901. |
| [3] |
SUN Chuan-yao1, LUO Lan1, 2*, WANG Yu1, GUO Rui1, ZHANG Yuan-bo1. Photoluminscence Spectra and Ternary CIE Colour Image of (Mg1-x-yBaxSry)1.95SiO4∶0.05Eu Phosphor Series[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(01): 98-106. |
| [4] |
SUN Tian-lei1, YAN Jing-hui1*, GENG Ai-fang1*, ZHANG Hong2, ZOU Ming-qiang3, 4. Design and Synthesis of Rare Earth Organic-Inorganic Hybrid Material Based on Polyoxometalate and 1,4,5,8-Naphthalenediimide Derivatives[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2019, 39(06): 1915-1921. |
| [5] |
ZHOU Xin, LUO Li-lin, LI Xia*. Fluorescence Sensing Based on the Europium (Ⅲ) Complex with p-Aminobenzoic Acid and 1,10-Phenanthroline[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2813-2816. |
| [6] |
LI Jia-jia, LI Rui, MA Xue, FAN Ting-ting, LIN Yi-qing, SONG Yu-ting, HAN Jing-qi, LI Xia* . Fluorescence Properties and the Detection of Benzaldehyde of Lanthanide Complex with 2-Sufoterephthalalic Acid [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(02): 345-348. |
| [7] |
QIU Li-xia1, WAN Fang1, ZHU Bin-bin1, SUN Yan-qiong1,2*, YOU Yi1*, CHEN Yi-ping1 . Synthesis, Structure and Spectroscopy Study of a 1D Copper Coordination Polymer Based on a Carboxybenzyl Viologen Ligand and SCN-Anion[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(05): 1340-1344. |
| [8] |
ZHANG Yang-yang1, ZHONG Hua2, CHEN Bao-jiu2, XIA Ying1, LIN Hai1* . Differentiated Fluorescence Centers in Europium Acetylacetonate Hydrate Doped Poly Methyl Methacrylate [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(06): 1482-1485. |
| [9] |
FU Shi-rong, SHI Meng*, HAN Pei-gao, ZHANG Bei-bei, YAN Ke-zhu. Solvent Effect of Europium(Ⅲ) Complex Sensitized by Charge Transfer Excited State of Functional Cation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(09): 2502-2505. |
| [10] |
LIU Jun1,2, LIU Shao-xuan2, GAO Yun-long2,3, FAN Xiao-kun2,4, GUAN Yan2, WENG Shi-fu2, YANG Zhan-lan2, XU Yi-zhuang2*, WU Jin-guang2. On the Interaction between PVP and Europium Benzenesulfonate [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(06): 1487-1490. |
| [11] |
DONG Yu-wei, FAN Rui-qing*, WANG Ping, WANG Li-yuan, YANG Yu-lin* . Synthesis, Crystal Structure and Spectral Properties Study of a 3D Netlike Coordination Polymer [Zn(HBIDC)·H2O]n [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(02): 481-485. |
| [12] |
YANG Zhao-ning, LI Jun, QIU Jian-bei, YANG Zheng-wen*, SONG Zhi-guo, WANG Rong-fei, YU Xue, YANG Yong, ZHOU Da-cheng . Synthesis and Photoluminescence Properties of Eu3+, Bi3+ Codoped BaZrO3 Phosphors[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(01): 19-22. |
| [13] |
XU Cun-jin1, SHI Yan-qin2 . Synthesis and Luminescence Properties of a Reactive Ternary Europium Complex Containing 1,10-Phenanthroline [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2013, 33(01): 116-119. |
| [14] |
SUN Qin-jun, XU Zheng*, ZHAO Su-ling, ZHANG Fu-jun, GAO Li-yan . Luminescence Characteristics of PVK Doped with Eu-Complex Eu(UVA)3Phen [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(10): 2676-2679. |
| [15] |
CHENG Guo, WEI Chang-ping*, REN Xiao-ming, WANG He, WEI Wen-tao. Synthesis, Characterization and Luminescence Properties of Novel β-Diketone and Eu(Ⅲ) Ternary Complex[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(09): 2346-2349. |
|
|
|
|
