| 光谱学与光谱分析 |
|
|
|
|
|
| Solvent Effect of Europium(Ⅲ) Complex Sensitized by Charge Transfer Excited State of Functional Cation |
| FU Shi-rong, SHI Meng*, HAN Pei-gao, ZHANG Bei-bei, YAN Ke-zhu |
| Shandong Provincial Key Laboratory of Laser Polarization and Information Technology, Laser Institute, Qufu Normal University, Qufu 273165, China |
|
|
|
|
Abstract In the novel europium(Ⅲ) complex of the form [Eu(tta)4·DEASPI], the sensitization of lanthanide luminescence is via functional cation. The photophysical sensitization process of Eu(tta)4·DEASPI involves an energy transfer from charge transfer excited state of hemicyanine (aminostyrylpyridinium) cation, and the sensitization mechanism follows Förster resonance energy mechanism. The solvent effect on this new kind of europium(Ⅲ) complex was investigated in the present work. The europium(Ⅲ) complex was dissolved in a variety of solvents, i.e. acetone, DMF, ethanol and acetonitrile, and the emission intensity of europium(Ⅲ) complex in acetonitrile is much higher than in other solvents. The detailed discussion about solvent effect is provided in this paper.
|
|
Received: 2013-01-12
Accepted: 2013-04-06
|
|
|
|
Corresponding Authors:
SHI Meng
E-mail: philipyes@163.com
|
|
[1] Qan Gang, Zhong Ze, Luo Min, et al. Adv. Mater., 2009, 21(1): 111.
[2] Sun P P, Duan J P, Lih J J, et al. Adv. Funct. Mater., 2003, 13(9): 683.
[3] Montalti M, Prodi L, Zaccheroni N, et al. J. Am. Chem. Soc., 2001, 123(50): 12694.
[4] Aspinall H C. Chem. Rev., 2002, 102(6): 1807.
[5] Yam V W W, Lo X K W. Coordin. Chem. Rev., 1999, 184(1): 157.
[6] Tsukube H, Shinoda S, Tamiaki H. Coordin. Chem. Rev., 2002, 226(1-2): 227.
[7] Fu Limin, Wen Xiaofan, Ai Xicheng, et al. Angew. Chem. Int. Ed., 2005, 117(5): 757.
[8] Werts M H V, Nerambourg N, Pélégry D, et al. Photochem. Photobiol. Sci., 2005, 4: 531.
[9] Lis S, Pawlicki G. J. Lumin., 2010, 130 (5): 832.
[10] Dexter D L. J. Chem. Phys., 1953, 21(5): 836.
[11] D’Aléo A, Picot A, Baldeck P L, et al. Inorg. Chem., 2008, 47: 102.
[12] D’Aléo A, Picot A, Beeby A, et al. Inorg. Chem., 2008, 47: 10258.
[13] Lei Kewei, Liu Weisheng, Tan Minyu. Spectrochim. Acta Part A, 2007, 66(3): 590.
[14] Ansari A A, Singh N, Khan A F, et al. J. Lumin., 2007, 127(2): 446.
[15] Yang Tianlin, Qin Wenwu, Liu Weisheng. J. Anal. Chem., 2005, 60(4): 325.
[16] Crosby G A, Demas J N. J. Phys. Chem., 1971, 75(8): 991.
[17] Shavaleev N M, Pope S J A, Bell Z R, et al. Dalton Trans., 2003, (5): 808.
[18] Peacock R D. Struct. Bond. Berlin, 1975, 22: 83.
[19] Binnemans K, Herck K V, Grller-Walrand C. Chem. Phys. Lett., 1997, 266(3-4): 297.
[20] Shi Meng, Pan Mei, Su Fufang, et al. J. Lumin., 2012, (132): 398.
[21] Tang Qun, Liu Shu-xia, Liang Da-dong, et al. J. Sol. Stat. Chem., 2012, 190: 85. |
| [1] |
XIE Huan-ran, CUI Hao, YAN Dong, LI Hui, LIANG Zuo-qin*, WANG Xiao-mei, YE Chang-qing. Synthesis and Piezofluorochromic Properties of a 2-Substituted
Triphenylamine-Anthracene Derivative[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1776-1780. |
| [2] |
FANG Zi-qiu1,2, CHEN Guo-qing1,2*, WU Ya-min1,2. Studyon the Spectral Properties of Riboflavin in Different Polar Solvents[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2020, 40(04): 1132-1136. |
| [3] |
ZHANG Chun-yan1,2, LUO Jian-xin2*, OU Li-juan2, LIU Yong2, HU Bo-nian2, YU Gui-peng1*, PAN Chun-yue1*. Luminescence Properties of Carbazole-Substituted Alq3 Derivative: a Potential Multifunctional Fluorescent Sensing Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1290-1297. |
| [4] |
ZHOU Xin, LUO Li-lin, LI Xia*. Fluorescence Sensing Based on the Europium (Ⅲ) Complex with p-Aminobenzoic Acid and 1,10-Phenanthroline[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(09): 2813-2816. |
| [5] |
XIAO Xue1，ZHAO Nan-jing1*，YU Shao-hui2，MA Ming-jun1，YANG Rui-fang1，YIN Gao-fang1，DUAN Jing-bo1， FANG Li1，ZHANG Yu-jun1，LIU Wen-qing1. Effect of Methanol-Water Mixture on Three-Dimensional Fluorescence Spectra of Carbaryl[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(06): 1775-1778. |
| [6] |
LI Jia-jia, LI Rui, MA Xue, FAN Ting-ting, LIN Yi-qing, SONG Yu-ting, HAN Jing-qi, LI Xia* . Fluorescence Properties and the Detection of Benzaldehyde of Lanthanide Complex with 2-Sufoterephthalalic Acid [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2016, 36(02): 345-348. |
| [7] |
LI Shuai-peng1,2, LIN Xiao-long2, ZHANG Feng-qin2, JIANG Yong-heng1,2*, SUN Yu3, LI Si-yuan3, ZHU Dong-you3, LIU Meng-hui3. Study of Fermi Resonance Characteristic of CS2 in THF [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(04): 894-897. |
| [8] |
SONG Guang-qing1, 2, XI Hong-bo1, ZHOU Yue-xi1*, LI Jie2, ZHAO Jing-tian3, CUI Jun-hua3 . A Method for Determination of Trace Naphthalene and Phenanthrene in Water Using Constant-Wavelength Synchronous Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32(07): 1838-1841. |
| [9] |
SUN Qin-jun, XU Zheng*, ZHAO Su-ling, ZHANG Fu-jun, GAO Li-yan . Luminescence Characteristics of PVK Doped with Eu-Complex Eu(UVA)3Phen [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2011, 31(10): 2676-2679. |
| [10] |
LIU Sheng-gui1，2, LIN Cheng-you1, WANG Hui-hui1, HE Pei1, GONG Meng-lian1 . Synthesis and Luminiescence of Eu(Ⅲ) Complex Based on 4,4,4- Trifluoro-1-(4’-m-Terphenyl)-1,3-Butanedione and 1,10-Phenanthroline[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(03): 612-615. |
| [11] |
ZHANG Liu-yang1, 2, LI Zuo-wei1*, LU Guo-hui1, GAO Shu-qin1, JIANG Yong-heng1 . Solvent Effects on Raman Spectroscopy of 1,1,3,3-Tetramethylurea in Organic Solvents [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(05): 1296-1299. |
| [12] |
ZHANG Liu-yang1,4,WANG Zhi-gang2,WANG Yue-meng3,LI Zuo-wei1*,LU Guo-hui1,JIANG Yong-heng1, GAO Shu-qin1. Investigation of Effect of Solvents on CO Fermi Resonance with Solvent Variation Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(02): 570-573. |
| [13] |
WANG Lian-meng1,ZHAO Yong-liang1,2*,ZHANG Mei1,GAO De-qing3. Synthesis, Characterization and Photoluminescence Properties of (EuxRE1-x)(β-NTA)3Phen Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(08): 1883-1886. |
| [14] |
YE Yan-chun1,2,TAN Hui-min1,ZHANG Jun-liang2,GUO Yan-wen2. Study on the Ultraviolet Spectra of Diacetone Acrylamide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(06): 1356-1358. |
| [15] |
YANG Wu,GAO Qi-kuan,LU Xiao-lin,WU Jin-xiu. Study on the Interactions of Eu(Ⅲ) Complex of O-(Thioxanthone-[2]-yl)-Oxyacetic Acid with DNA[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2008, 28(02): 366-369. |
|
|
|
|
