光谱学与光谱分析 |
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Synthesis, Crystal Structure and Spectral Properties Study of a 3D Netlike Coordination Polymer [Zn(HBIDC)·H2O]n |
DONG Yu-wei, FAN Rui-qing*, WANG Ping, WANG Li-yuan, YANG Yu-lin* |
Department of Chemistry, Harbin Institute of Technology, Harbin 150001, China |
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Abstract The 3D netlike coordination polymer of ZnⅡ with benzimidazole-5,6-dicarboxylic acid (H3BIDC), [Zn(HBIDC)·H2O]n was synthesized by the hydrothermal method through self-assembling. The crystal structure of complex 1 was characterized by single-crystal X-ray diffraction, elemental analysis and IR spectra, and we also studied the fluorescence properties of complex 1 in DMSO and in the solid state with UV-Vis absorption spectra, fluorescence spectra and fluorescence lifetime. Complex 1 has blue luminescence in solutions of DMSO with emission band at 481 nm; and has blue luminescence in the solid state at room temperature with a strong emission band at 493 nm, and these all can be attributed to the π*→π transition based on the benzimidazole-5,6-dicarboxy acid. The experimental results indicate that complex 1 displays higher fluorescence quantum efficiency and can be used as a potential blue luminescence material.
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Received: 2012-06-04
Accepted: 2012-08-12
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Corresponding Authors:
FAN Rui-qing, YANG Yu-lin
E-mail: fanruiqing@hit.edu.cn;ylyang@hit.edu.cn
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