| 光谱学与光谱分析 |
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| Study on the Reaction between Cobalt Tetrasulphonated Phthalocyanine and Sodium Sulfide |
| LIU Wei，YE Tao，GUO Rong |
| Chemistry and Chemical Engineering College, Yangzhou University，Yangzhou 225002，China |
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Abstract A new method which uses multi-wave number and double-parameter to analyse the UV-Vis. spectra is proposed to determine the composition and stabilization constants of coordination compounds. With this method, the reaction of cobalt tetrasulphonated phthalcyanine[CoTsPc] and sodium sulfide[Na2S] was studied. The result shows that pH of the medium has great effect on the reaction. A five coordinated compound Co(Ⅱ)TsPc(HS) was formed at pH=7.0. The equilibrium constants and thermodynamics are reported for the reaction under that condition. At higher pH, a redox-reaction took place and a five coordinated compound with the oxidation number Ⅰ for cobalt [SCo(Ⅰ)TsPc] was found.
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Received: 2002-09-23
Accepted: 2003-01-16
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Corresponding Authors:
LIU Wei
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| Cite this article: |
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LIU Wei,YE Tao,GUO Rong. Study on the Reaction between Cobalt Tetrasulphonated Phthalocyanine and Sodium Sulfide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(06): 762-767.
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http://www.gpxygpfx.com/EN/Y2004/V24/I06/762 |
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