| 光谱学与光谱分析 |
|
|
|
|
|
| Fractionation and Spectroscopic Property of Dissolved Organic Matters in Soils |
| ZHOU Jiang-min1, 2, DAI Jing-yu1*, PAN Gen-xing1 |
1. College of Resources and Environmental Sciences, Nanjing Agricultural University, Nanjing 210095，China
2. College of Resources and Environmental Sciences, Sichuan Agricultural University, Ya′an 625014，China |
|
|
|
|
Abstract Based on a modified Leenheer DOM fractionation scheme, fractionation of DOM from paddy soils was conducted by using XAD-8 resin into hydrophobic bases (HOB), hydrophobic acids (HOA), acid-insoluble matter (AIM), hydrophobic neutrals (HON) and hydrophillic matter (HIM), and their structural characteristics were studied by means of elemental composition, FTIR and 1H-NMR spectroscopy. The fractionation scheme used here provided a preferable separation of the fractions in terms of hydrophobicity and a high recovery. Of the DOC extracted from the soils, the HOB was the least fraction, accounting for 0.73%-3.83%, and the HIM fraction was the largest, accounting for 36%-42%. The HON fraction represented 7%-15%. The relative content of the HOA plus AIM was about 50%. Separated by this technique, the large-chain alkylate and the major portion of the N components mainly characterized HON, while the HOA fraction contained a large amount of carboxyl groups but less amount of aromatic groups with a higher quantity of carbohydrates compared to that of FA. AIM fraction was dominated by high branched(n value) polyphenols and humus bound carbohydrates. HIM was characterized by considerable amount of carboxyl and carbohydrates.
|
|
Received: 2003-04-26
Accepted: 2003-08-16
|
|
|
|
Corresponding Authors:
DAI Jing-yu
|
|
| Cite this article: |
|
ZHOU Jiang-min,DAI Jing-yu,PAN Gen-xing. Fractionation and Spectroscopic Property of Dissolved Organic Matters in Soils [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(09): 1060-1065.
|
|
|
|
| URL: |
|
http://www.gpxygpfx.com/EN/Y2004/V24/I09/1060 |
[1] Kalbitz K, Solinger S et al. Soil Science, 2000, 165(4): 277.
[2] Riffaldi R, Levi-Minzi R et al. Agriculture, Ecosystems and Environment, 1998, (69): 113.
[3] TAO Shu et al(陶 澍等). Chinese Journal of Soil Science(土壤通报), 2000, 31(4): 174.
[4] Kuwatsuka S, Tsutsuki K, Kumada K. Soil Sci. Plant Nutr., 1978, 24: 337.
[5] Leenheer J A. Environmental Science Technology, 1981，15：578.
[6] David M B, Vance G F, Rissing J M et al. Journal of Environmental Quality, 1989, 18: 212.
[7] Cook B D, Allan D L. Soil Biol. Biochem., 1992, 24(6): 595.
[8] Qualls R G, Haines B L. Soil Sci. Soc. Am. J., 1991, 55: 1112.
[9] Zech W, Guggenberger, Schulter H R. Sci. Total Environ., 1994, 152: 49.
[10] Nambu K, Yonebayashi K. Soil Sci. Plant Nutr., 1999, 45(1): 65.
[11] Tuija M, Pirkko K. Environment International, 1998, 24(5/6): 521.
[12] Huizhong Ma, Herbert E A, Yujun Yin. Wat. Res., 2001, 35(4): 985.
[13] Christensen J B, Dorthe L. Jensen et al. Wat. Res., 1998, 32(1): 125.
[14] Wilson M A, Collin P J, Tate K R. Journal of Soil Science, 1983, 34: 297.
[15] DOU Sen, HUA Shi-ying(窦 森，华士英). Acta Pedologica Sinica(土壤学报), 1997, 34(3): 225.
[16] Chefetz B, Hadar Y, Chen Y. Acta hydrochim. Hydrobiol., 1998, 26(3): 172.
[17] Cheetz B, Hatcher P G et al. Soil Sci. Soc. Am. J., 1998, 62: 326.
[18] Morrison R T, Boyd R N. Organic Chemistry, Part 17, Massachusetts, USA: Allyn and Bacon Inc: Neston, 1983.
[19] Kaiser K, Zech W. Science of Soils, 1997, 2: 71.
[20] GU Zhi-mang, WANG Xiao-rong et al(顾志忙, 王晓蓉等). Chinese Journal of Analytical Chemistry(分析化学), 2000, 28(3): 314.
[21] Grossl P R, Inskeep W P. Soil Sci. Soc. Am. J., 1996, 60: 158.
|
| [1] |
MA Fang1, HUANG An-min2, ZHANG Qiu-hui1*. Discrimination of Four Black Heartwoods Using FTIR Spectroscopy and
Clustering Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1915-1921. |
| [2] |
CHENG Can1, HEI Da-qian2*, JIA Wen-bao1, SHAN Qing1, LING Yong-sheng1, ZHAO Dong1. Study on Metallic Samples Determination Based on Prompt Gamma
Neutron Activation Analysis Technique[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1928-1933. |
| [3] |
ZHANG Dian-kai1, LI Yan-hong1*, ZI Chang-yu1, ZHANG Yuan-qin1, YANG Rong1, TIAN Guo-cai2, ZHAO Wen-bo1. Molecular Structure and Molecular Simulation of Eshan Lignite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(04): 1293-1298. |
| [4] |
WANG Fang-fang1, ZHANG Xiao-dong1, 2*, PING Xiao-duo1, ZHANG Shuo1, LIU Xiao1, 2. Effect of Acidification Pretreatment on the Composition and Structure of Soluble Organic Matter in Coking Coal[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 896-903. |
| [5] |
HU Chao-shuai1, XU Yun-liang1, CHU Hong-yu1, CHENG Jun-xia1, GAO Li-juan1, ZHU Ya-ming1, 2*, ZHAO Xue-fei1, 2*. FTIR Analysis of the Correlation Between the Pyrolysis Characteristics and Molecular Structure of Ultrasonic Extraction Derived From Mid-Temperature Pitch[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 889-895. |
| [6] |
LI Xue-ping1, 2, 3, ZENG Qiang1, 2, 3*. Development and Progress of Spectral Analysis in Coal Structure Research[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 350-357. |
| [7] |
YANG Jiong1, 2, QIU Zhi-li1, 4*, SUN Bo3, GU Xian-zi5, ZHANG Yue-feng1, GAO Ming-kui3, BAI Dong-zhou1, CHEN Ming-jia1. Nondestructive Testing and Origin Traceability of Serpentine Jade From Dawenkou Culture Based on p-FTIR and p-XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 446-453. |
| [8] |
HE Xiong-fei1, 2, HUANG Wei3, TANG Gang3, ZHANG Hao3*. Mechanism Investigation of Cement-Based Permeable Crystalline Waterproof Material Based on Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3909-3914. |
| [9] |
ZHOU Jing1,2, ZHANG Qing-qing1,2, JIANG Jin-guo2, NIE Qian2, BAI Zhong-chen1, 2*. Study on the Rapid Identification of Flavonoids in Chestnut Rose (Rosa Roxburghii Tratt) by FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3045-3050. |
| [10] |
Samy M. El-Megharbel*，Moamen S. Refat. In First Time: Synthesis and Spectroscopic Interpretations of Manganese(Ⅱ), Nickel(Ⅱ) and Mercury(Ⅱ) Clidinium Bromide Drug Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3316-3320. |
| [11] |
Samy M. El-Megharbel*, Moamen S. Refat. Preparations and Spectroscopic Studies on the Three New Strontium(Ⅱ), Barium(Ⅱ), and Lead(Ⅱ) Carbocysteine Complexes[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(09): 2975-2979. |
| [12] |
YU Chun-mei, ZHANG Nan, TENG Hai-peng. Investigation of Different Structures of Coals Through FTIR and Raman Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2050-2056. |
| [13] |
QU Li-guo1,2,3, LIU Jian-guo1, XU Liang1*, XU Han-yang1, JIN Ling1, DENG Ya-song1,2, SHEN Xian-chun1, SHU Sheng-quan1,2. Vehicle Exhaust Detection Method Based on Portable FTIR[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1751-1757. |
| [14] |
Samar O. Aljazzar. Spectroscopic Investigations for the Six New Synthesized Complexes of Fluoroquinolones and Quinolones Drugs With Nickel(Ⅱ) Metal Ion: Infrared and Electronic Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1976-1981. |
| [15] |
Lamia A. Albedair. Synthesis, Structural, Spectroscopic Characterization and Biological Properties of the Zn(Ⅱ), Cu(Ⅱ), Ni(Ⅱ), Co(Ⅱ), and Mn(Ⅱ) Complexes With the Widely Used Herbicide 2,4-Dichlorophenoxyacetic Acid[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1982-1987. |
|
|
|
|
