|
|
|
|
|
|
Pressure and Temperature Dependence of Raman Spectroscopy of Solid Ionic Crystal β-K0.294Ga1.969O3 |
ZHANG Feng1, LIU Shan1, PU Mei-fang1, TANG Qi-qi1, WU Bin-bin1, LI Lin2, HU Qi-wei3, XIA Yuan-hua3, FANG Lei-ming3, LEI Li1* |
1. Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065, China
2. State Key Laboratory of Geological Processes and Resources, China University of Geosciences, Beijing 100083, China
3. Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900, China |
|
|
Abstract β-gallate type compounds are promising solid-state ionic conductor, which has important application value in the field of energy storage. These compounds exhibit complex lattice dynamics due to the conducting layer tends to have an excess of alkali metal ions, which makes it difficult to further understand its conductive mechanism. Both pressure and temperature can affect the structure of materials by changing the spacing between atoms, and it has great application value in studying the dynamic process of materials, especially the diffusion process of ions. So far, the temperature dependence of vibrational properties has received less attention, and the high-pressure behavior of β-gallate type compounds has not been reported. Due to the unique advantage of laser Raman scattering technique in studying the lattice dynamics of matter, especially the pressure and temperature-dependent Raman spectroscopy, it is an effective experimental method for studying the lattice dynamics of the β-gallate type compounds. In this work, a novel β-gallate type K0.294Ga1.969O3 (KGO) crystal was successfully synthesized by using large-volume-press technology. The crystal was characterized by a scanning electron microscope, energy spectrum. The crystal structure of KGO is analyzed by single-crystal X-ray diffraction and compared with the crystal structure of β-Ga2O3. The lattice dynamics of disordered alkali metal ions in the KGO conducting layer was studied by pressure and temperature dependent Raman spectroscopy. We found that the β-gallate type KGO crystal structure formed by alternatively stacked-layer spinel-blocks and the loose conducting plane remains stable at the pressure up to 23.3 GPa. The significant difference in the pressure coefficients between high and low-frequency Raman modes are derived from different types of vibration. It is evidenced that the presence of thermally activated processes K+ ions in KGO at approximately 300 ℃, it’s embodied in the intensity of low-frequency Raman mode related to alkali metal K+ motion increases rapidly, while that of high-frequency vibration mode related to Ga-O polyhedron increases slowly. And the mobile K+ ions undergo disorder diffusion process along the conduction plane. Our results will contribute to a deeper understanding of the conductive mechanism of β-gallate type compounds, and it is also very important to achieve accurate compositional control and doping of β-gallate type compounds.
|
Received: 2020-02-28
Accepted: 2020-07-12
|
|
Corresponding Authors:
LEI Li
E-mail: lei@scu.edu.cn
|
|
[1] Zhao C L, Liu L, Qi X G, et al. Advanced Energy Materials, 2018, 8: 1703012.
[2] Butee S P, Kambale K R, Firodiya M. Processing and Application of Ceramics, 2016, 10: 67.
[3] Ikawa H, Tsurumi T, Ishimori M, et al. Journal of Solid State Chemistry, 1985, 60: 51.
[4] Lu X C, Xia G G, Lemmon J P, et al. Journal of Power Sources, 2010, 195: 2431.
[5] Kuo C K,Nicholson P S. Solid State Ionics, 1999, 118: 251.
[6] Bao Y H, Kuo C K, Nicholson P S. Solid State Ionics, 2000, 130: 293.
[7] Burns G, Chandrashekhar G V, Dacol F H, et al. Physical Review B, 1980, 22: 1073.
[8] Hu Q W, Lei L, Jiang X D, et al. Solid State Sciences, 2014, 37: 103.
[9] Zhang L L, Cheng Y, Lei L, et al. Crystal Growth & Design, 2018, 18: 1843.
[10] Lei L,Zhang L L. Matter and Radiation at Extremes, 2018, 3: 95.
[11] Mao H K, Bell P M, Shaner J W, et al. Journal of Applied Physics, 1978, 49: 3276.
[12] Dohy D, Lucazeau G, Revcolevschi A. Journal of Solid State Chemistry, 1982, 45: 180.
[13] Dohy D, Lucazeau G,Bougeard D. Solid State Ionics, 1983, 11: 1.
[14] Arashi H, Naito H,Kaimai A. Journal of Materials Science, 1993, 28: 5725. |
[1] |
LI Jie, ZHOU Qu*, JIA Lu-fen, CUI Xiao-sen. Comparative Study on Detection Methods of Furfural in Transformer Oil Based on IR and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 125-133. |
[2] |
WANG Fang-yuan1, 2, HAN Sen1, 2, YE Song1, 2, YIN Shan1, 2, LI Shu1, 2, WANG Xin-qiang1, 2*. A DFT Method to Study the Structure and Raman Spectra of Lignin
Monomer and Dimer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 76-81. |
[3] |
XING Hai-bo1, ZHENG Bo-wen1, LI Xin-yue1, HUANG Bo-tao2, XIANG Xiao2, HU Xiao-jun1*. Colorimetric and SERS Dual-Channel Sensing Detection of Pyrene in
Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 95-102. |
[4] |
WANG Xin-qiang1, 3, CHU Pei-zhu1, 3, XIONG Wei2, 4, YE Song1, 3, GAN Yong-ying1, 3, ZHANG Wen-tao1, 3, LI Shu1, 3, WANG Fang-yuan1, 3*. Study on Monomer Simulation of Cellulose Raman Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 164-168. |
[5] |
WANG Lan-hua1, 2, CHEN Yi-lin1*, FU Xue-hai1, JIAN Kuo3, YANG Tian-yu1, 2, ZHANG Bo1, 4, HONG Yong1, WANG Wen-feng1. Comparative Study on Maceral Composition and Raman Spectroscopy of Jet From Fushun City, Liaoning Province and Jimsar County, Xinjiang Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 292-300. |
[6] |
LI Wei1, TAN Feng2*, ZHANG Wei1, GAO Lu-si3, LI Jin-shan4. Application of Improved Random Frog Algorithm in Fast Identification of Soybean Varieties[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3763-3769. |
[7] |
WANG Zhi-qiang1, CHENG Yan-xin1, ZHANG Rui-ting1, MA Lin1, GAO Peng1, LIN Ke1, 2*. Rapid Detection and Analysis of Chinese Liquor Quality by Raman
Spectroscopy Combined With Fluorescence Background[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3770-3774. |
[8] |
LIU Hao-dong1, 2, JIANG Xi-quan1, 2, NIU Hao1, 2, LIU Yu-bo1, LI Hui2, LIU Yuan2, Wei Zhang2, LI Lu-yan1, CHEN Ting1,ZHAO Yan-jie1*,NI Jia-sheng2*. Quantitative Analysis of Ethanol Based on Laser Raman Spectroscopy Normalization Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3820-3825. |
[9] |
LU Wen-jing, FANG Ya-ping, LIN Tai-feng, WANG Hui-qin, ZHENG Da-wei, ZHANG Ping*. Rapid Identification of the Raman Phenotypes of Breast Cancer Cell
Derived Exosomes and the Relationship With Maternal Cells[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3840-3846. |
[10] |
LI Qi-chen1, 2, LI Min-zan1, 2*, YANG Wei2, 3, SUN Hong2, 3, ZHANG Yao1, 3. Quantitative Analysis of Water-Soluble Phosphorous Based on Raman
Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3871-3876. |
[11] |
GUO He-yuanxi1, LI Li-jun1*, FENG Jun1, 2*, LIN Xin1, LI Rui1. A SERS-Aptsensor for Detection of Chloramphenicol Based on DNA Hybridization Indicator and Silver Nanorod Array Chip[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3445-3451. |
[12] |
ZHU Hua-dong1, 2, 3, ZHANG Si-qi1, 2, 3, TANG Chun-jie1, 2, 3. Research and Application of On-Line Analysis of CO2 and H2S in Natural Gas Feed Gas by Laser Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3551-3558. |
[13] |
LIU Jia-ru1, SHEN Gui-yun2, HE Jian-bin2, GUO Hong1*. Research on Materials and Technology of Pingyuan Princess Tomb of Liao Dynasty[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3469-3474. |
[14] |
LI Wen-wen1, 2, LONG Chang-jiang1, 2, 4*, LI Shan-jun1, 2, 3, 4, CHEN Hong1, 2, 4. Detection of Mixed Pesticide Residues of Prochloraz and Imazalil in
Citrus Epidermis by Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3052-3058. |
[15] |
ZHAO Ling-yi1, 2, YANG Xi3, WEI Yi4, YANG Rui-qin1, 2*, ZHAO Qian4, ZHANG Hong-wen4, CAI Wei-ping4. SERS Detection and Efficient Identification of Heroin and Its Metabolites Based on Au/SiO2 Composite Nanosphere Array[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3150-3157. |
|
|
|
|