| 光谱学与光谱分析 |
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| Study on Measuring Host-Guest Ratio of Inclusion Compound of β-CD-Permethrin by IR |
| SHAO Qiong-fang1, DONG Ming2*, XIE Xiao-hong1, ZENG Lan-ping1, LENG Lei-bao1 |
1. Department of Chemistry, Jiangxi Science and Technology Teachers College, Nanchang 330013，China
2. College of Life Science, Jiangxi Normal University, Nanchang 330027，China |
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Abstract Permethrin is one of the agrochemicals used in tea gardens currently with the characteristic of being easily decomposed in light. Permethrin with β-cyclodextrin(CD) made into Inclusion Compound (IC) can increase its stability and reduce dosage to remain on the tea. Host/guest ratio is one of the important parameters of IC. The IC of permethrin with β-CD was prepared by means of liquid phase method and characterized by using IR. The result of the IR proves that the characteristic absorption peaks of the host and guest are not changed by forming their IC. The host/guest ratio of the IC measured by IR is 1∶1. Potassium sulfocyanate(KSCN) was chosen as an inside mark material, because it has only one strong absorption peak at 2 100 cm-1 and the peak was chosen as a quantitative peak of KSCN. The peak at 580 cm-1 is the characteristic absorption of the wreath vibration of β-CD and was chosen as a quantitative peak of β-CD. KSCN and β-CD were mixed with a certain quantity ratio and the mixture was analyzed by IR. The work curve of IR was established. A kind of new experimental method of measuring host/guest ratio of the IC was provided.
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Received: 2003-12-16
Accepted: 2004-03-28
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Corresponding Authors:
DONG Ming
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| Cite this article: |
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SHAO Qiong-fang,DONG Ming,XIE Xiao-hong, et al. Study on Measuring Host-Guest Ratio of Inclusion Compound of β-CD-Permethrin by IR [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(06): 698-700.
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| URL: |
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http://www.gpxygpfx.com/EN/Y2004/V24/I06/698 |
[1] JIANG Guo-min(蒋国民). The Handbook of Insecticide Formulations and Its Technologies for Household and Public Health Uses(卫生杀虫剂剂型技术手册). Beijing: Chemistry Industry Publishing House(北京： 化学工业出版社)，2000. 386.
[2] WU Xue-fen，BAI Yan，ZHANG Guang-zhao(武雪芬，白 雁，张广照). J. of China Pharmacy(中国药学杂志)，2001，8： 548.
[3] TONG Lin-hui(童林荟). Cyclodextrin Chemistry—Foundation and Application(环糊精化学——基础与应用). Beijing: Science Press(北京： 科学出版社)，2001. 215.
[4] QIAN Jun-hong ，XU Wen-lin(钱俊红，许文林). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2003, 23(4): 692.
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