新型L-氨基酸尾式卟啉及其锌(Ⅱ)配合物的合成与光谱性质

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Abstract Three new L-amino acid tailed porphyrins and their zinc(Ⅱ) complexes were synthesized by L-amino acid and 5-[o-(bromoethoxyl)phenyl]-10,15,20-triphenyl prophyrin. FAB-MS, UV-Vis, IR, elemental analysis and chemical analysis were used to determine the structures of these porphyrins and their zinc complexes. The FTIR spectra (4 000-400 cm^-1) of L-amino acid tailed porphyrin and its zinc(Ⅱ) complexes were measured and investigated. The major bands have been empirically assigned in comparison with L- amino acid tailed porphyrin and its zinc(Ⅱ) complexes.

Key words：L-amino acid tailed porphyrin;Zinc(Ⅱ) complex;Synthesis;Spectral property

Received: 2002-12-09 Accepted: 2003-05-26

ZTFLH:	O614.24
	O657.33

Corresponding Authors: LUO Guo-tian

Cite this article:

LUO Guo-tian,TENG Li-li,LAI Xiao-qi, et al. Synthesis and Spectral Properties of L-Amino Acid Tailed Porphyrin and Their Zinc(Ⅱ) Complexes [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(02): 173-176.

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http://www.gpxygpfx.com/EN/Y2004/V24/I02/173

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