|
|
|
|
|
|
| Spectra Characterization of the Uvarovite in Anorthitic Jade |
| LIU Jia1, YANG Ming-xing1, 2*, DI Jing-ru1, 2, HE Chong2 |
1. Gemmological Institue, China University of Geosciences, Wuhan 430074, China
2. Gem Testing Center, China University of Geosciences, Wuhan 430074, China |
|
|
|
|
Abstract The green minerals in Anorthitic Jade were considered to be uvarovite, which is a very rare member in natural garnet group. Uvarovite is very rare in natural conditions, the color is emerald green, uvarovite of high quality can be compared with Jade and Emerald. Predecessors have done some researches on the other end members of the garnets. However, little researches have been done on the uvarovite, no reports have been obtained about the spectrum characteristics of the uvarovite in Anorthitic Jade. The composition of this garnet was Uvt49.66Grs36.04Adr13.58Prp0.67Sps0.06 by using the JXA-8230 Electron Probe. Using the Bruker R200L Raman spectrometer, the Raman shifts we got of the sample were 1 000，890，879，830，618，589，530，508，399，370，270，240 and 176 cm-1，respectively, which have been influenced by the interaction of different trivalent cations Cr3+, Al3+ and Fe3+; Measurement of the infrared vibration frequency was performed using the Bruker V80 infrared spectrometer, acquiring the results of 1 019, 951, 908, 844, 826, 721, 669, 608, 538, 496, 462, 430 and 413 cm-1，respectively, the regular vibration excursion occurs due to the influence of the unit cell volume and the mass fraction of the trivalent cations; With the Jasco MSV-5200, the Micro-UV-Vis-NIR spectra shows that absorption peaks caused by electron transition of Cr3+were at 439, 613, 453 and 685 nm absorption were acromion, while a acromion absorption peaks caused by electron transition of Fe3+ was at 371 nm, the colored ion of the uvarovite is mainly Cr3+. The detailed spectrum study of the uvarovite in Anorthitic Jade provides rich spectral data for the identification of the garnet, and distinguishing from the similar traditional Dushan jade.
|
|
Received: 2017-07-02
Accepted: 2017-11-12
|
|
|
|
Corresponding Authors:
YANG Ming-xing
E-mail: 240419372@qq.com
|
|
[1] LIU Jia, YANG Ming-xing, DI Jing-ru, et al(刘 佳，杨明星，狄敬如，等). Journal of Gems & Gemmology(宝石和宝石学杂志)，2018，20(1)：26.
[2] Valenzano L, Pascale F, Ferrero M, et al. International Journal of Quantum Chemistry, 2010, 110(2): 416.
[3] Pascale F, Catti M, Damin A, et al. J. Phys. Chem. B, 2005, 109(39): 18522.
[4] Dovesi R, Valenzano L, Pascale F, et al. J. Raman Spectrosc.，2009, 40(4): 416.
[5] Parthasarathy G, Balaram V, Srinivasan R. Journal of Asian Earth Sciences, 1999, 17(3): 345.
[6] Yoshiko Suwa, Shigeharu Naka. American Mineralogist, 1975, 60: 1125.
[7] Petre Makreski, Tomce R, Gligor J. Journal of Raman Spectroscopy, 2011, 42(1): 72.
[8] HE Xue-mei, Lü Lin-su(何雪梅, 吕麟素). Journal of Gems & Grmmology(宝石和宝石学杂质), 2003, 5(3): 10.
[9] PENG Wen-shi, LIU Gao-kui(彭文世, 刘高魁). Infrared Spectrum Atlas of Minerals(矿物红外光谱图集). Beijing: Science Press(北京: 科学出版社), 1982.
[10] Moroz T, Ragozin A, Salikhov D, et al. Spectrochimica Acta Part, 2009, 73(3): 436.
[11] Zicovich Wilson C M, Torres F J, Pascale F, et al. Journal of Computational Chemistry, 2008, 29(13): 2268.
[12] Navas A S, Reddy B J, Nieto F. Spectrochimica Acta Part A, 2004, 60(10): 2261.
[13] Andrut M, Wildner M. Physics & Chemistry of Minerals, 2002, 29(9): 595.
[14] Manning P G. The Canadian Mineralogist, 1969, 9(5): 723.
[15] Lakshman S V J, Reddy B J. Physica, 1974, 71(1): 197.
[16] CHEN Feng, LIN Chuan-yi, ZHANG Hui-fen, et al(陈 丰, 林传易, 张蕙芬, 等). An Introduction to Mineral Physics(矿物物理学概论). Beijing: Science Press(北京: 科学出版社)，1995. 61.
[17] Novak G A, Gibbs G V. American Mineralogist, 1971, 56: 791.
[18] Huckenholz H G，Knittel D. Contributions to Mineralogy and Petrology, 1975, 49(3): 211. |
| [1] |
LI Jie, ZHOU Qu*, JIA Lu-fen, CUI Xiao-sen. Comparative Study on Detection Methods of Furfural in Transformer Oil Based on IR and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 125-133. |
| [2] |
CHENG Jia-wei1, 2，LIU Xin-xing1, 2*，ZHANG Juan1, 2. Application of Infrared Spectroscopy in Exploration of Mineral Deposits: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 15-21. |
| [3] |
YANG Cheng-en1, 2, LI Meng3, LU Qiu-yu2, WANG Jin-ling4, LI Yu-ting2*, SU Ling1*. Fast Prediction of Flavone and Polysaccharide Contents in
Aronia Melanocarpa by FTIR and ELM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 62-68. |
| [4] |
WANG Fang-yuan1, 2, HAN Sen1, 2, YE Song1, 2, YIN Shan1, 2, LI Shu1, 2, WANG Xin-qiang1, 2*. A DFT Method to Study the Structure and Raman Spectra of Lignin
Monomer and Dimer[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 76-81. |
| [5] |
GAO Feng1, 2, XING Ya-ge3, 4, LUO Hua-ping1, 2, ZHANG Yuan-hua3, 4, GUO Ling3, 4*. Nondestructive Identification of Apricot Varieties Based on Visible/Near Infrared Spectroscopy and Chemometrics Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 44-51. |
| [6] |
XING Hai-bo1, ZHENG Bo-wen1, LI Xin-yue1, HUANG Bo-tao2, XIANG Xiao2, HU Xiao-jun1*. Colorimetric and SERS Dual-Channel Sensing Detection of Pyrene in
Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 95-102. |
| [7] |
WANG Xin-qiang1, 3, CHU Pei-zhu1, 3, XIONG Wei2, 4, YE Song1, 3, GAN Yong-ying1, 3, ZHANG Wen-tao1, 3, LI Shu1, 3, WANG Fang-yuan1, 3*. Study on Monomer Simulation of Cellulose Raman Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 164-168. |
| [8] |
LIU Jia, ZHENG Ya-long, WANG Cheng-bo, YIN Zuo-wei*, PAN Shao-kui. Spectra Characterization of Diaspore-Sapphire From Hotan, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 176-180. |
| [9] |
BAO Hao1, 2，ZHANG Yan1, 2*. Research on Spectral Feature Band Selection Model Based on Improved Harris Hawk Optimization Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 148-157. |
| [10] |
GUO Ya-fei1, CAO Qiang1, YE Lei-lei1, ZHANG Cheng-yuan1, KOU Ren-bo1, WANG Jun-mei1, GUO Mei1, 2*. Double Index Sequence Analysis of FTIR and Anti-Inflammatory Spectrum Effect Relationship of Rheum Tanguticum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 188-196. |
| [11] |
WANG Lan-hua1, 2, CHEN Yi-lin1*, FU Xue-hai1, JIAN Kuo3, YANG Tian-yu1, 2, ZHANG Bo1, 4, HONG Yong1, WANG Wen-feng1. Comparative Study on Maceral Composition and Raman Spectroscopy of Jet From Fushun City, Liaoning Province and Jimsar County, Xinjiang Province[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 292-300. |
| [12] |
BAI Xue-bing1, 2, SONG Chang-ze1, ZHANG Qian-wei1, DAI Bin-xiu1, JIN Guo-jie1, 2, LIU Wen-zheng1, TAO Yong-sheng1, 2*. Rapid and Nndestructive Dagnosis Mthod for Posphate Dficiency in “Cabernet Sauvignon” Gape Laves by Vis/NIR Sectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3719-3725. |
| [13] |
WANG Qi-biao1, HE Yu-kai1, LUO Yu-shi1, WANG Shu-jun1, XIE Bo2, DENG Chao2*, LIU Yong3, TUO Xian-guo3. Study on Analysis Method of Distiller's Grains Acidity Based on
Convolutional Neural Network and Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3726-3731. |
| [14] |
DANG Rui, GAO Zi-ang, ZHANG Tong, WANG Jia-xing. Lighting Damage Model of Silk Cultural Relics in Museum Collections Based on Infrared Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3930-3936. |
| [15] |
LI Qi-chen1, 2, LI Min-zan1, 2*, YANG Wei2, 3, SUN Hong2, 3, ZHANG Yao1, 3. Quantitative Analysis of Water-Soluble Phosphorous Based on Raman
Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3871-3876. |
|
|
|
|
