| 光谱学与光谱分析 |
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| Preparation and Characterization of Kaolinite-Potassium Dihydrogen Phosphate Intercalation Composite |
| TANG Wu-fei, GU Xiao-yu*, ZHANG Sheng, YUAN Hong-fu, JIANG Yu, ZHAO Jing-ran |
| Key Laboratory of Carbon Fiber and Functional Polymers, Beijing University of Chemistry Technology, Ministry of Education, Beijing 100029, China |
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Abstract Thepotassium dihydrogenphospiate (KDP) intercalated kaolinite (K-KDP) was prepared by a three-step reaction. Firstly, polar dimethyl sulphoxide (DMSO) was introduced into the layers of kaolinite by ultrasonic method and the product K-DMSO was obtained as precursor; secondly DMSO was replaced by potassium acetate (KAc) and the product K-KAc was gotten as intermediate; finally KAc was replaced by KDP. The intercalation ratio of the final product K-KDP reached 81.3%. The structure of products at differentreaction process was characterized by Fourier-transformed infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscope (SEM) in detail. FTIR results showed the existence of PO in the final product but moved from 1 300 to 1 201 cm-1. XRD results documented that the interlayer spacing of kaolinite was enlarged during the whole intercalation reaction. SEM indicated that the agglomeration of kaolinite was destroyed and the particle size distribution became more uniform.
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Received: 2013-12-31
Accepted: 2014-03-28
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Corresponding Authors:
GU Xiao-yu
E-mail: guxy@mail.buct.edu.cn
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[1] PAN Jin-sheng，QUAN Jian-min，TIAN Min-bo(潘金生，全健民，田民波). Materials Science and Foundations(材料科学与基础). Beijing: Tsinghua University Press(清华大学出版社)，2003. 116.
[2] ZHANG Jing-yu，BAI Zhi-min，ZHAO Dong(张婧宇，白志民，赵 栋). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2013，33(3): 704.
[3] SUN Jie，CHEN Xi-lei，SUN Dao-xing(孙 杰，陈希磊，孙道兴). Chemical Engineering and Equipment(化学工程与装备)，2012，(3): 15.
[4] Huang Guobo，Gao Jianrong，Li Yujing，et al. Polymer Degradation and Stability，2010，95(2): 245.
[5] Kadir Apaydin，Abdelghani Laachachi，Vincent Ball，et al. Polymer Degradation and Stability，2013，98(2): 627.
[6] Liang Yongsheng，Yu Jianying，Feng Zhangang，et al. Construction and Building Materials，2013，48: 1114.
[7] Emerson H de Faria，Gustavo P Ricci，Katia J Ciuffi，et al. Catalysis Today，2012，187(1): 135.
[8] FENG Li，LIN Zhe，GUO Jin(冯 莉，林 喆，郭 进). Journal of the Chinese Ceramic Society(硅酸盐学报)，2007，35(5): 653.
[9] ZHANG Jing-yang，YE Ling，ZHANG Xin(张敬阳，叶 玲，张 昕). Journal of Huaqiao University(华侨大学学报)，2011, 32(3): 288.
[10] Deng Youjun，G Norman White，Joe B Dixon. Journal of Colloid and Interface Science, 2003，257: 208.
[11] WU Da-qing，WANG Lin-jiang(吴大清，王林江). Journal of Mineralogy and Petrology(矿物岩石)，2003, 23(4): 25.
[12] FENG Li，SONG Shuo-jiang，MA Xia(冯 莉，宋说讲，马 霞). New Chemistry Materials(化工新型材料)，2007, 35(9): 5.
[13] XIA Hua，ZHANG Sheng-hui，YANG Wei(夏 华，张生辉，杨 微). Journal of the Chinese Ceramic Society(硅酸盐学报)，2004，32(5): 631.
[14] Li Yanfeng，Zhang Bo，Pan Xiaobing. Composites Science and Technology，2008，68: 1954.
[15] Liu Xishan，Gu Xiaoyu，Zhang Sheng. Journal of Applied Polymer Science, 2013，130(5): 3645.
[16] Galle Fontaine，Serge Bourbigot，Sophie Duquesne. Polymer Degradation and Stability，2008，93: 68.
[17] Kiliaris P，Papaspyrides C D. Progress in Polymer Science，2012，35: 902. |
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