光谱学与光谱分析 |
|
|
|
|
|
Study on Preparation and Optical Spectroscopy of Nickle Phthalocyanine-Doped Sol-Gel Materials |
ZHAN Hong-bing1,2, CHEN Wen-zhe1, LI Guang-hui1, WANG Min-quan2 |
1. College of Materials Science and Engineering, Fuzhou University, Fuzhou 350002,China 2. Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027,China |
|
|
Abstract We report here the preparation of nickle tetrasulfo-phthalocyanine (NiTSPc)-doped silica xerogel matrix obtained by sol-gel technique. The evolution of silica matrix′s texture and the rate during the sol-gel process, as well as silica xerogel′s pore structure were studied. Dimerization behavior of NiTSPc molecules was characterized by electronic absorption spectra,and changes in the absorption spectra were correlated with various stages of the sol-gel process. The results show that in the composites NiTSPc concurs in the forms of monomer and dimer,and dimerization is stronger during the latter stages. The reason is given from the change in the micro-environment in which NiTSPc existed during the sol-gel process.
|
Received: 2002-09-07
Accepted: 2003-01-26
|
|
Corresponding Authors:
ZHAN Hong-bing
|
|
Cite this article: |
ZHAN Hong-bing,CHEN Wen-zhe,LI Guang-hui, et al. Study on Preparation and Optical Spectroscopy of Nickle Phthalocyanine-Doped Sol-Gel Materials [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(05): 561-564.
|
|
|
|
URL: |
http://www.gpxygpfx.com/EN/Y2004/V24/I05/561 |
[1] Leznoff C C, Lever A B P. Phthalocyanine Properties and Applications. NewYork: VCH Publishers, Inc.,1989. 397. [2] Shirk J S, Lindle J R. J. Nonlin. Opt. Phys., 1989,1: 699. [3] Sastre A, Diaz-Garcia M A. J. Phys. Chem., 1997,101: 977. [4] QIAN Guo-dong(钱国栋). Study on Preparation Optical Sectroscopy of Inorganic-based Hybrid Nanocomposite Materials for Luminescence Application(无机基有机纳米复合发光材料制备与光谱学基础研究): [Ph.D.degree thesis(学位论文)].Hangzhou(杭州): Zhejiang University(浙江大学), 1996. [5] Fuqua P D, Dunn B, Zink Ji. J. Sol-Gel Sci. and Tech., 1998, 11: 241. [6] Haiping Xia, Masayaki Nogami. J. Materials Science, 1999,34: 3053. [7] YAN Ji-min, ZHANG Qi-yuan(严继民,张启元). Absorption and Condensation: The Surface and Pores of Solid(吸附与凝聚: 固体的表面和孔). Beijing: Science Press(北京: 科学出版社), 1979. 67. [8] HUANG Jin-ling, PENG Yi-ru, CHEN Nai-sheng(黄金陵,彭亦如,陈耐生). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001,21(1): 1.
|
[1] |
LI Shu-jie1, LIU Jie1, DENG Zi-ang1, OU Quan-hong1, SHI You-ming2, LIU Gang1*. Study of Germinated Rice Seeds by FTIR Spectroscopy Combined With Curve Fitting[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1832-1840. |
[2] |
ZHANG Yan-ru1, 2, SHAO Peng-shuai1*. Study on the Effects of Planting Years of Vegetable Greenhouse on the
Cucumber Qualties Using Mid-IR Spectroscopoy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1816-1821. |
[3] |
SHI Wen-qiang1, XU Xiu-ying1*, ZHANG Wei1, ZHANG Ping2, SUN Hai-tian1, 3, HU Jun1. Prediction Model of Soil Moisture Content in Northern Cold Region Based on Near-Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1704-1710. |
[4] |
WANG Xue-pei1, 2, ZHANG Lu-wei1, 2, BAI Xue-bing3, MO Xian-bin1, ZHANG Xiao-shuan1, 2*. Infrared Spectral Characterization of Ultraviolet Ozone Treatment on Substrate Surface for Flexible Electronics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1867-1873. |
[5] |
WANG Yue1, 3, 4, CHEN Nan1, 2, 3, 4, WANG Bo-yu1, 5, LIU Tao1, 3, 4*, XIA Yang1, 2, 3, 4*. Fourier Transform Near-Infrared Spectral System Based on Laser-Driven Plasma Light Source[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1666-1673. |
[6] |
FENG Rui-jie1, CHEN Zheng-guang1, 2*, YI Shu-juan3. Identification of Corn Varieties Based on Bayesian Optimization SVM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1698-1703. |
[7] |
YU Zhi-rong, HONG Ming-jian*. Near-Infrared Spectral Quantitative Analysis Network Based on Grouped Fully Connection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1735-1740. |
[8] |
XIE Yu-yu1, 2, 3, HOU Xue-ling1, CHEN Zhi-hui2, AISA Haji Akber1, 3*. Density Functional Theory Studies on Structure and Spectra of Salidroside Molecule[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1786-1791. |
[9] |
MENG Fan-jia1, LUO Shi1, WU Yue-feng1, SUN Hong1, LIU Fei2, LI Min-zan1*, HUANG Wei3, LI Mu3. Characteristic Extraction Method and Discriminant Model of Ear Rot of Maize Seed Base on NIR Spectra[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1716-1720. |
[10] |
PENG Yan-fang1, WANG Jun1, WU Zhi-sheng2*, LIU Xiao-na3, QIAO Yan-jiang2*. NIR Band Assignment of Tanshinone ⅡA and Cryptotanshinone by
2D-COS Technology and Model Application Tanshinone Extract[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1781-1785. |
[11] |
TIAN Xue1, CHE Qian1, YAN Wei-min1, OU Quan-hong1, SHI You-ming2, LIU Gang1*. Discrimination of Millet Varieties and Producing Areas Based on Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1841-1847. |
[12] |
HU Bin1, 2, FU Hao1, WANG Wen-bin1, ZHANG Bing1, 2, TANG Fan3*, MA Shan-wei1, 2, LU Qiang1, 2*. Research on Deep Sorting Approach Based on Infrared Spectroscopy for High-Value Utilization of Municipal Solid Waste[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1353-1360. |
[13] |
YAN Ling-tong, LI Li, SUN He-yang, XU Qing, FENG Song-lin*. Spectrometric Investigation of Structure Hydroxyl in Traditional Ceramics[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1361-1365. |
[14] |
WANG Li-qi1, YAO Jing1, WANG Rui-ying1, CHEN Ying-shu1, LUO Shu-nian2, WANG Wei-ning2, ZHANG Yan-rong1*. Research on Detection of Soybean Meal Quality by NIR Based on
PLS-GRNN[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1433-1438. |
[15] |
WANG Yan-ru, TANG Hai-jun*, ZHANG Yao. Study on Infrared Spectral Detection of Fuel Contamination in Mobil Jet Oil II Lubricating Oil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1541-1546. |
|
|
|
|