光谱学与光谱分析 |
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Highly Sensitive Spectrofluorimetric Determination of Trace Amounts of Chromium(Ⅵ) with Mono[6-o-(4-Aminobenzoic Acid)]-β-Cyclodextrin |
ZHANG Li, SHE Shi-ke, GAO Feng, ZHOU Yun-you, ZHU Chang-qing,WANG Lun* |
College of Chemistry and Materials Science, Anhui Normal University, Wuhu 241000, China |
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Abstract A novel fluorescence probe, mono[6-o-(4-aminobenzoic acid)]-β-cyclodextrin(ACD), was synthesized, and a new sensitive fluorescence identification reaction was studied based on the reaction of Cr2O2-7 with compound ACD in NaAc-HAc buffer medium at pH 4.90.Under optimal conditions the determination limit was 1.26 μg· L-1.The linear range was 5.20-1 040 μg· L-1.This method has been applied to the determination of trace amounts of chromium (Ⅵ)in electroplating liquor, electroplating waste water with satisfactory results.
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Received: 2003-12-23
Accepted: 2004-05-20
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Corresponding Authors:
WANG Lun
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Cite this article: |
ZHANG Li,SHE Shi-ke,GAO Feng, et al. Highly Sensitive Spectrofluorimetric Determination of Trace Amounts of Chromium(Ⅵ) with Mono[6-o-(4-Aminobenzoic Acid)]-β-Cyclodextrin [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(07): 1103-1105.
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URL: |
https://www.gpxygpfx.com/EN/Y2005/V25/I07/1103 |
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