光谱学与光谱分析 |
|
|
|
|
|
Fluorescence Property of a Chemical Probe for Naked-Eye and Detection of Fe3+ |
SONG Yu-min, MA Xin-xian, YANG Wu |
College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China |
|
|
Abstract A higher selective and sensitive probe for the detection of Fe(Ⅲ) in aqueous media was made using 2,4-Diisocyanatotoluene (TDI) as a bridge to couple Fe3O4 nanoparticles(NPs) and Rhodamine-6G hydrazide. The characterization of composite materials with Infrared spectra(IR), Thermal Gravimetric analysis(TGA) and Transmission Emission Microscopy(TEM) points to the graft of Rhodamine-6G hydrazide onto the surface of the Fe3O4. The obvious color change of the probe solution from light grey to pink upon the addition of Fe3+ demonstrated the probe could be used for “naked-eye” detection of Fe3+ in water at pH 7. The presence of 1 equivalent (10μmol·L-1 μm) of each of these metal ions, including Mn2+, Ni2+, Y2+, Eu3+, Ce3+, La3+, Pr3+, Cd2+, Cr3+, Sm3+, Fe2+, Cu2+and Zn2+ ions, did not demonstrate any obvious fluorescence change of the probe water solution, which confirmed the probe was a probe with remarkable selectivity for Fe3+. And the fluorescence images of HeLa cells in physiological solutions after incubation with Fe3+ and then further incubated with the probe leading to a strong intracellular fluorescence, which suggested the probe could penetrate the HeLa cell membrane and could respond to Fe3+ in intracellular within living cells.
|
Received: 2012-06-25
Accepted: 2012-08-20
|
|
Corresponding Authors:
SONG Yu-min
E-mail: songym@nwnu.edu.cn
|
|
[1] Brugnara C. Clin. Chem., 2003, 49, 1573. [2] Zhang X B, Cheng G, Zhang W J, et al. Talanta, 2007, 71:171. [3] Ghaedi M, Shokrollahi A, Mehrnoosh R, et al. Cent. Eur. J. Chem., 2008, 6:488. [4] Bae S, Tae J. Tetrahedron Lett., 2007, 48:5389. [5] Xiang Y, Tong A J. Org. Lett., 2006, 8:1549. [6] Bricks J L, Kovalchuk A, Trieflinger C, et al. J. Am. Chem. Soc., 2005, 127:13522. [7] Mitra A, Ramanujam B, Rao C P. Tetrahedron Lett., 2009, 50:776. [8] Ghosh S, Chakrabarty R, Mukherjee P S. Inorg. Chem., 2009, 48:549. [9] Zhang X, ShiraishiY, Hirai T. Tetrahedron Lett., 2007, 48:5455. [10] Dong L, Wu C, Zeng X, et al. Sens. Actuators, B, 2010, B145:433. [11] Sumner J P, Kopelman R. Analyst, 2005, 130:528. [12] Tumambac G E, Rosencrance C M, Wolf C. Tetrahedron, 2004, 60:11293. [13] Beutler E, Felitti V, Gelbart T,et al. Drug Metab. Dispos., 2001, 29:495. [14] Cairo G, Pietrangelo A. Biochem. J,2000, 352:241. [15] Amendola V, Fabbrizzi L, Forti F, et al. Coord. Chem. Rev.,2006, 250:273. [16] Wang B D, HaiJ, Liu Z C, et al. Angew. Chem. Int. Ed., 2010, 49:1. [17] Yang X F, Guo X Q, Zhao Y B. Talanta,2002, 57:883. [18] Wu D Y P, Huang W Z, Lin H H,et al. Inorganic Chemistry, 2008, 47:7190. [19] Nag M, Basak P, Manorama S V. Mater. Res. Bull.,2007, 42:1691. [20] Huang J H, Xu Y F, Qian X H. J. Org. Chem.,2009, 74:2167. [21] Xiang Y, Tong A. Org. Lett., 2006, 8:1549. [22] Watson S, Beydoun D,Scott J, et al. J. Nanoparticle Res., 2004, 6:193. |
[1] |
YI Min-na1, 2, 3, CAO Hui-min1, 2, 3*, LI Shuang-na-si1, 2, 3, ZHANG Zhu-shan-ying1, 2, 3, ZHU Chun-nan1, 2, 3. A Novel Dual Emission Carbon Point Ratio Fluorescent Probe for Rapid Detection of Lead Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3788-3793. |
[2] |
QI Guo-min1, TONG Shi-qian1, LIN Xu-cong1, 2*. Specific Identification of Microcystin-LR by Aptamer-Functionalized Magnetic Nanoprobe With Laser-Induced Fluorescence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3813-3819. |
[3] |
HE Yan-ping, WANG Xin, LI Hao-yang, LI Dong, CHEN Jin-quan, XU Jian-hua*. Room Temperature Synthesis of Polychromatic Tunable Luminescent Carbon Dots and Its Application in Sensitive Detection of Hemoglobin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3365-3371. |
[4] |
LENG Jun-qiang, LAN Xin-yu, JIANG Wen-shuo, XIAO Jia-yue, LIU Tian-xin, LIU Zhen-bo*. Molecular Fluorescent Probe for Detection of Metal Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2002-2011. |
[5] |
QIAN Duo, SU Wen-en, LIU Zhi-yuan, GAO Xiao-yu, YI Yu-xin, HU Cong-cong, LIU Bin, YANG Sheng-yuan*. Soy Protein Gold Nanocluster as an “Off-On” Fluorescent Probe for the Detection of Bacillus Anthracis Biomarkers DPA[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(06): 1815-1820. |
[6] |
LI Xuan1, CHEN Quan-li1, 2*, ZHENG Xiao-hua2. Spectral Characteristics of Light Yellow Feldspar From Guyang, Inner Mongolia[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1622-1627. |
[7] |
ZHOU Ao1, 2, YUE Zheng-bo1, 2, LIU A-zuan1, 2, GAO Yi-jun3, WANG Shao-ping3, CHUAI Xin3, DENG Rui1, WANG Jin1, 2*. Spectral Analysis of Extracellular Polymers During Iron Dissimilar
Reduction by Salt-Tolerant Shewanella Aquimarina[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1320-1328. |
[8] |
ZHENG Li-zhen1, 2, CHENG Cong2, MA Wen-hua2, WANG Zhuo-rui2, HU Dao-dao2*. Online Detection of Water Forms and Moisture Volatilization Behavior in Earthen Relics Based on FE Fluorescence Probe[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 383-388. |
[9] |
LÜ Chun-qiu1, SI Lu-lu1, PAN Zhao-jin2, LIANG Yang-lin1, LIAO Xiu-fen2, CHEN Cong-jin2*. Fast and Ratiometric Detection of Dimethoate Via the Dual- Emission Center Nitrogen-Doped Carbon Quantum Dots[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(02): 468-474. |
[10] |
ZHAI Yan-ke1, PAN Yi-xing1, XIANG Hao1, XU Li1*, ZHU Ze-ce2, LEI Mi1. Coordination Interaction of DSAZn With Quercetin and High Sensitivity Detection of Quercetin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(01): 122-128. |
[11] |
SONG Jiang-tao, YUAN Yue-hua, ZHU Yong-jun, WANG Yu-zhen, TIAN Mao-zhong*, FENG Feng*. Research Progress of Near-Infrared Fluorescent Probes for Hydrogen Sulfide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3321-3329. |
[12] |
WANG Li, GAO Shi-fang, MENG Lu-ping, SHANG Liang, SHI Meng*, LIU Guang-qiang. Au-Nanorod Patterned Optical Fiber SERS Probes Fabricated by Laser-Induction[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(11): 3454-3460. |
[13] |
XU Yi-fei, LIU Lu, SHI Shi-kao*, WANG Yue, PAN Yu-jing, MA Xing-wei. Spectroscopic Properties of Carbon Quantum Dots Prepared From Persimmon Leaves and Fluorescent Probe to Fe3+ Ions[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(08): 2418-2422. |
[14] |
WAN Xiao-ming1, 2, ZENG Wei-bin1, 2, LEI Mei1, 2, CHEN Tong-bin1, 2. Micro-Distribution of Elements and Speciation of Arsenic in the Sporangium of Pteris Vittata[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(02): 478-482. |
[15] |
YU Qing1, CHEN Xiao-li2, ZHANG Qi-long1,3*, LIU Hua3, YANG Xian-jiong3, XU Hong3, HUANG Ya-li3*, FENG Xing4*, REDSHAW Carl5. A Highly Selective Colorimetric Naked-Eye Probe for Hypochlorite Detection in Water[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 322-332. |
|
|
|
|