光谱学与光谱分析 |
|
|
|
|
|
Upconversion Luminescence Properties of ZBLAN∶Nd3+, Tm3+, Yb3+ |
YANG Zhi-ping,DU Hai-yan, SUN Jia-yue*,WANG Wei |
School of Chemistry and Environmental Engineering,Beijing Technology and Business University,Beijing 100037, China |
|
|
Abstract The ZBLAN∶Nd3+, Tm3+, Yb3+ upconversion materials were prepared by high-temperature solid method. The concentrations of Tm3+ and Yb3+ were 0.01% and 0.3% respectively. The concentration of Nd3+ changed in the range from 0.1% to 2%. The absorption spectrum of ZBLAN∶Nd3+, Tm3+, Yb3+ in all samples from 300 to 1 000 nm was measured at room temperature. The upconversion emission was observed when excited by 798 nm infrared light. The material samples emitted relatively strong multi-band (the red, blue and green color) visible light. Based on the experiment, the multi-band visible spectral lines were analyzed, and the energy level transition mechanism was given. The blue light results from the transition of 1G4→3H6 of Tm3+, the green light is from the transition of 2H7/2→4I9/2 of Nd3+, and the red light originates from the transition of 2H11/2→4I9/2 of Nd3+. The results show that the upconversion mechanism includes excited state absorption, energy transfer, cross relaxation and so on. The energy transfer processes between Nd3+, Tm3+ and Yb3+ ions both forward and backward prove to be the origin of upconversion emissions. The effect of rare earth doping concentration on the energy upconversion efficiency was analyzed, according to the different upconversion light emitting intensity from samples with different Tm3+ mol concentrations. The upconversion luminescence increased with the Nd3+ concentration and got its peak at 1.5%.
|
Received: 2008-03-28
Accepted: 2008-07-02
|
|
Corresponding Authors:
SUN Jia-yue
E-mail: sunjy@btbu.edu.cn
|
|
[1] Poulain M, Lucas J. Brun P. Mater. Res. Bull., 1975, 10(4): 243. [2] Quimby R S, Drexhage M G, Suscavage M J. Electron. Lett., 1987, 23(1): 32. [3] Chen Y, Auzel F. J. Non-Crys. Sol., 1995, 184: 278. [4] CHEN Bao-jiu, WANG Hai-yu, QIN Wei-ping, et al(陈宝玖,王海宇,秦伟平,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2000, 20(3): 257. [5] FANG Ai-ping, DAI Zhen-wen, YANG Hai-gui, et al(方爱平,戴振文,杨海贵,等). Chinese Journal of Luminescence(发光学报), 2004, 25(5): 487. [6] KANG Dong-guo, CHEN Xiao-bo, LI Song, et al(康洞国,陈晓波,李 菘,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2007, 27(1): 1. [7] Zhao Suling, Hou Yanbing, Sun Li, et al. Journal of Alloys and Compounds, 2000, 311(1): 57. [8] YUAN Fang-cheng(袁放成). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(1): 157. [9] FENG Yan, CHEN Xiao-bo, SONG Feng, et al(冯 衍,陈晓波,宋 峰,等). Acta Optica Sinica(光学学报), 1999, 19(4): 552. [10] CHEN Xiao-bo, Sawanobori N, SONG Zeng-fu(陈晓波,Sawanobori N,宋增福). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001, 21(6): 752. [11] ZHANG Jun-jie, ZHANG Long, et al(张军杰,张 龙,等). Chinese Journal of Materials Research(材料研究学报), 2000, 14(4): 388. [12] Piramidowicz R, Witonski P, Klimczak M, et al. Optical Materials, 2006, 28(1-2): 152. [13] Piramidowicz R, Klimczak M, Malinowski M. Proc. of SPIE, 2005, 5958: 59582T-1. [14] Kowalska M, Klocek G, Piramidowicz R, et al. Journal of Alloys and Compounds, 2004, 380(1-2): 156. [15] Lilia Coronato Courrol, Izilda Marcia Ranieri, Luís Vicente Gomes et al. Journal of Applied Physics, 2005, 98: 113504.
|
[1] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
[2] |
GU Yi-lu1, 2,PEI Jing-cheng1, 2*,ZHANG Yu-hui1, 2,YIN Xi-yan1, 2,YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
[3] |
HAN Xue1, 2, LIU Hai1, 2, LIU Jia-wei3, WU Ming-kai1, 2*. Rapid Identification of Inorganic Elements in Understory Soils in
Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
[4] |
WANG Hong-jian1, YU Hai-ye1, GAO Shan-yun1, LI Jin-quan1, LIU Guo-hong1, YU Yue1, LI Xiao-kai1, ZHANG Lei1, ZHANG Xin1, LU Ri-feng2, SUI Yuan-yuan1*. A Model for Predicting Early Spot Disease of Maize Based on Fluorescence Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3710-3718. |
[5] |
CHENG Hui-zhu1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, MA Qian1, 2, ZHAO Yan-chun1, 2. Genetic Algorithm Optimized BP Neural Network for Quantitative
Analysis of Soil Heavy Metals in XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3742-3746. |
[6] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2,WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
[7] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
[8] |
LI Xiao-li1, WANG Yi-min2*, DENG Sai-wen2, WANG Yi-ya2, LI Song2, BAI Jin-feng1. Application of X-Ray Fluorescence Spectrometry in Geological and
Mineral Analysis for 60 Years[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 2989-2998. |
[9] |
XUE Fang-jia, YU Jie*, YIN Hang, XIA Qi-yu, SHI Jie-gen, HOU Di-bo, HUANG Ping-jie, ZHANG Guang-xin. A Time Series Double Threshold Method for Pollution Events Detection in Drinking Water Using Three-Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3081-3088. |
[10] |
MA Qian1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, CHENG Hui-zhu1, 2, ZHAO Yan-chun1, 2. Research on Classification of Heavy Metal Pb in Honeysuckle Based on XRF and Transfer Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2729-2733. |
[11] |
JIA Yu-ge1, YANG Ming-xing1, 2*, YOU Bo-ya1, YU Ke-ye1. Gemological and Spectroscopic Identification Characteristics of Frozen Jelly-Filled Turquoise and Its Raw Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2974-2982. |
[12] |
YANG Xin1, 2, XIA Min1, 2, YE Yin1, 2*, WANG Jing1, 2. Spatiotemporal Distribution Characteristics of Dissolved Organic Matter Spectrum in the Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2983-2988. |
[13] |
CHEN Wen-jing, XU Nuo, JIAO Zhao-hang, YOU Jia-hua, WANG He, QI Dong-li, FENG Yu*. Study on the Diagnosis of Breast Cancer by Fluorescence Spectrometry Based on Machine Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2407-2412. |
[14] |
ZHU Yan-ping1, CUI Chuan-jin1*, CHENG Peng-fei1, 2, PAN Jin-yan1, SU Hao1, 2, ZHANG Yi1. Measurement of Oil Pollutants by Three-Dimensional Fluorescence
Spectroscopy Combined With BP Neural Network and SWATLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2467-2475. |
[15] |
LIU Xian-yu1, YANG Jiu-chang1, 2, TU Cai1, XU Ya-fen1, XU Chang3, CHEN Quan-li2*. Study on Spectral Characteristics of Scheelite From Xuebaoding, Pingwu County, Sichuan Province, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2550-2556. |
|
|
|
|