光谱学与光谱分析 |
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Synthesis and Characterization of La(Ⅲ) Binuclear Complex with 2-Hydroxy-1-Naphthaldehyde-β-Alanine and Its Interaction with DNA |
LI Ying-ying, FAN Yu-hua*, BI Cai-feng, ZHANG Dong-mei, ZOU Yan-na,XIAO Yan |
College of Chemistry and Chemical Engineering,Ocean University of China, Qingdao 266003, China |
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Abstract The binuclear complex of Schiff base C14H12NO3K(KHL) derived from 2-hydroxy-1-naphthaldehyde and β-alanine with lanthanide nitrate was synthesized and characterized by elemental analysis, IR, UV, TG-DTA, and molar conductance analysis. The composition of the complex was [La2(L)2(NO3)2]·2C2H5OH. The interaction of the complex and DNA was studied by fluorescence spectrum. The result indicates that the La(Ⅲ) complex could cause a sharp decrease in the fluorescence intensity of EB-DNA system, and the complex could partly sustain the place of EB.
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Received: 2005-09-28
Accepted: 2005-12-28
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Corresponding Authors:
FAN Yu-hua
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Cite this article: |
LI Ying-ying,FAN Yu-hua,BI Cai-feng, et al. Synthesis and Characterization of La(Ⅲ) Binuclear Complex with 2-Hydroxy-1-Naphthaldehyde-β-Alanine and Its Interaction with DNA[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(12): 2268-2271.
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https://www.gpxygpfx.com/EN/Y2006/V26/I12/2268 |
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