光谱学与光谱分析 |
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Study on the Genuineness and Producing Area of Panax Notoginseng Based on Infrared Spectroscopy Combined with Discriminant Analysis |
LIU Fei1, WANG Yuan-zhong2, YANG Chun-yan1, JIN Hang2* |
1. Department of Physics, Yuxi Normal University, Yuxi 653100, China 2. Institute of Medicinal Plants, Yunnan Academy of Agricultural Sciences, Kunming 650200, China |
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Abstract The genuineness and producing area of Panax notoginseng were studied based on infrared spectroscopy combined with discriminant analysis. The infrared spectra of 136 taproots of P. notoginseng from 13 planting point in 11 counties were collected and the second derivate spectra were calculated by Omnic 8.0 software. The infrared spectra and their second derivate spectra in the range 1 800~700 cm-1 were used to build model by stepwise discriminant analysis, which was in order to distinguish study on the genuineness of P. notoginseng. The model built based on the second derivate spectra showed the better recognition effect for the genuineness of P. notoginseng. The correct rate of returned classification reached to 100%, and the prediction accuracy was 93.4%. The stability of model was tested by cross validation and the method was performed extrapolation validation. The second derivate spectra combined with the same discriminant analysis method were used to distinguish the producing area of P. notoginseng. The recognition effect of models built based on different range of spectrum and different numbers of samples were compared and found that when the model was built by collecting 8 samples from each planting point as training sample and the spectrum in the range 1 500~1 200 cm-1, the recognition effect was better, with the correct rate of returned classification reached to 99.0%, and the prediction accuracy was 76.5%. The results indicated that infrared spectroscopy combined with discriminant analysis showed good recognition effect for the genuineness of P. notoginseng. The method might be a hopeful new method for identification of genuineness of P. notoginseng in practice. The method could recognize the producing area of P. notoginseng to some extent and could be a new thought for identification of the producing area of P. notoginseng.
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Received: 2014-02-08
Accepted: 2014-05-15
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Corresponding Authors:
JIN Hang
E-mail: jinhang2009@126.com
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[1] Chinese Pharmacopoeia Commission(中华人民共和国药典委员会). Pharmacopoeia of the People’s Republic of China(中华人民共和国药典), Part One(第一部). Beijing: China Medical Science Press(北京: 中国医学科学出版社), 2010. [2] LI Guan-lie(李冠烈). World Journal of Integrated Traditional and Western Medicine (世界中西医结合杂志), 2008, 3(10): 619. [3] XIA Peng-guo, CUI Xiu-ming, WEI Mei-tang, et al(夏鹏国,崔秀明,韦美膛, 等). Chinese Traditional and Herbal Drugs(中草药), 2012, 35(5): 831. [4] ZHU Yan, CUI Xiu-ming, SHI Li-ping(朱 艳,崔秀明,施莉屏). Research and Practice of Chinese Medicines(现代中药研究与实践),2006, 21(1): 58. [5] WANG Dan, ZHANG Qiu-yan, YANG Xing-xin, et al(王 丹, 张秋燕, 杨兴鑫, 等). China Journal of Chinese Materia Medica(中国中药管理), 2013, 38(12): 1951. [6] SUN Su-qin, ZHOU Qun, CHEN Jian-bo(孙素琴,周 群,陈建波). Analysis of Traditional Chinese Medicine by Infrared Spectroscopy(中药红外光谱分析与鉴定). Beijing: Chemical Industry Press(北京:化学工业出版社), 2010. [7] WANG Dong-hua(汪冬华). Multivariate Statistical Analysid and SPSS Application(多元统计分析与SPSS应用). Shanghai: East University of Science and Technology Press(上海: 华东理工大学出版社). 2010. [8] ZHANG Xin-xin, LI Yu, JI Yu-jia, et al(张新新,李 雨,纪玉佳,等). Journal of Shandong University(Health Sciences)(山东大学学报(医学版), 2012, 50(1): 143. [9] ZHU Li-jun, WANG Peng, SHI Feng-cheng, et al(朱立军,王 鹏,施丰成,等). Journal of Southwest University·Natural Science Edition(西南大学学报·自然科学版), 2012, 34(3): 9. [10] ZHAO Hai-yan, GUO Bo-li, WEI Yi-min, et al(赵海燕,郭波莉,魏益民, 等). Scientia Agricultura Sinica(中国农业科学), 2011, 44(7): 1451. [11] XIAO Bo, MAO Wen-hua, LIANG Xiao-hong, et al(肖 波,毛文华,梁小红,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2012, 32 (6): 1620. [12] XIE Jing-xi, CHANG Jun-biao, WANG Chu-ming(谢晶曦, 常俊标, 王诸明). Application of Infrared Spectroscopy in Organic Chemistry and Pharmaceutical Chemistry(红外光谱在有机化学和药物化学中的应用). Beijing: Science Press (北京: 科学出版社), 2001. [13] Ressom H W, Varghese R S, Zhang Z, et al. Frontiers in Bioscience, 2008, 13: 691. [14] JIN Hang, CUI Xiu-ming, ZHU Yan, et al(金 航, 崔秀明, 朱 艳, 等). Southwest china Journal of Agricultural Sciences(西南农业学报), 2005, 18(6): 825. [15] CUI Xiu-ming, XU Luo-shan, WANG Qiang, et al(崔秀明, 徐珞珊, 王 强, 等). China Journal of Chinese Materia Medica(中国中药管理), 2005, 30(5): 332. [16] CUI Xiu-ming, CHEN Zhong-jian(崔秀明, 陈中坚). Study on the Geoherbalism of Panax Notoginseng Medicinal Material(三七药材的道地性研究). Kunming: Yunnan Science and Technology Press(昆明: 云南科技出版社), 2007.
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