光谱学与光谱分析 |
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FTIR Study on the Synthesis of Poly(Propylene Fumarate) and Its Copolymer |
ZHANG Na1, CAI Zhong-yu2, CHANG Jun-biao1 |
1.College of Pharmaceutical Science and Technology,Tianjin University, Tianjin 300072, China 2.College of Material Science and Engineering, Tianjin University, Tianjin 300072, China |
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Abstract Poly(propylene fumarate) (PPF) is one kind of linear biodegradable polyester and the unsaturated double bonds along its main chain can be crosslinked with other olefinic monomers to form three-dimensional networks, and the networks can support tissues.In the present paper, firstly, the intermediate oligomer-bis(2-hydroxypropyl) fumarate (PFP) was synthesized, and then the unsaturated linear polyester PPF was synthesized with the oligomer PFP through melting condensation process.Additionally, on the base of the process, the oligomer bis(2-hydroxypropyl) sebacate (PSP) was synthesized by similar method and then a kind of new copolymer named poly(propylene fumarate-co-propylene sebacate) [P(PF-co-PS)] that comprised bis(2-hydroxypropyl) sebacate segments was synthesized with PFP and PSP by melting condensation.During the synthesis process, the structures of bis(2-hdroxypropyl) fumarate, bis(2-hydroxypropyl) sebacate, PPF and P(PF-co-PS) were characterized by FTIR.The results shows that with the polymerization going along, oligomer bis(2-hydroxypropyl) fumarate and bis(2-hydroxypropyl) sebacate converted to PPF or P(PF-co-PS) gradually.
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Received: 2008-12-22
Accepted: 2009-03-25
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Corresponding Authors:
ZHANG Na
E-mail: zhangna@sipo.gov.cn; zhangna_tju@yahoo.com.cn
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