Abstract:In the present study, molecular imprinting was used to develop a method based on noncovalent interaction for the synthesis of a monocrotophos-specific polymer. The selective binding characteristics of the template polymer were evaluated by 1H NMR and ultraviolet spectrometry. The polymer obtained was found to interact specifically with monocrotophos by cooperative hydrogen bonding. The infrared spectrometry of the polymer further indicated that there were some functional groups in the moleculary imprinted polymer which could interact on the template.
朱晓兰,杨俊,苏庆德*,蔡继宝,高芸. 久效磷分子印迹聚合物分子识别特性的光谱研究[J]. 光谱学与光谱分析, 2006, 26(10): 1817-1820.
ZHU Xiao-lan, YANG Jun, SU Qing-de*, CAI Ji-bao, GAO Yun. Spectroscopy Study of Molecular Recognition of a Molecular Imprinted Monocrotophos-Specific Polymer. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(10): 1817-1820.
[1] Mullett W M, Lai E P C. Anal. Chem., 1998, 70: 3636. [2] He D, Tong A J, Li L D. Spectrochim. Acta Part A, 2003, 59: 279. [3] Fu Q, Zheng N, Li Y, et al. J. Mol. Recognit., 2001, 14: 151. [4] FU Ke-wen(傅可文). Chemical Pollution in Agricultural Environment(农业环境中的化学污染). Beijing: Agricultural Press(北京: 农业出版社), 1985. 207. [5] Matsui J, Miyoshi y, Doblhoff-Doer O, et al. Anal. Chem., 1995, 67: 4404. [6] WANG Xiao-yan, HUANG Xiang-hong(王小燕, 黄向红). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(5): 573. [7] Sellergren B, Lepisto M, Mosbach K. J. Am. Chem. Soc., 1988, 110: 5853. [8] XIE Meng-xia, LIU Yuan, ZHANG Xiao-tong, et al(谢孟峡, 刘 媛, 张晓彤, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2000, 20(5): 684. [9] ZHOU Jie, HE Xi-wen, ZHAO Jie, et al(周 杰, 何锡文, 赵 洁, 等). Chem. J. Chin. Univ.(高等学校化学学报), 1999, 20(2): 204. [10] LU Qun, YANG Xiao-zhen, ZHU Shan-nong(陆 群, 杨小震, 朱善农). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1994, 14(3): 35. [11] Sellergren B, Shea K J. J. Chromatogr. A, 1993, 635: 31.