|
|
|
|
|
|
Study on the Determination of Basic Orange Ⅱ and Acid Orange Ⅱ in Food by TLC-SERS |
FU Yun-peng, QI Ying, HU Xiao-peng, TONG Rui, FANG Guo-zhen*, WANG Shuo |
Key Laboratory of Food Nutrition and Safety, College of Food Engineering and Biotechnology, Tianjin University of Science and Technology, Tianjin 300457, China |
|
|
Abstract A method for the rapid detection of illegally added basic orange Ⅱ and acid orange Ⅱ in food was established by the combination of thin layer chromatography (TLC) and surface enhanced Raman spectroscopy (SERS). TLC was used for the separation of sample extracts tentatively and the conditions were optimized. Two kinds of silver sols, aqueous phase and organic phase, were synthesized and used as the substrate to enhance Raman signal for basic orange Ⅱ and acid orange Ⅱ. SERS was used to detect isolated micro-substances and the time was investigated. The detection limits of basic orange Ⅱ and acid orange Ⅱ were 1 and 2.5 mg·L-1. Then, the method has been successfully used for rapid detection of basic orange and orange Ⅱ in the complex food matrix. The method has the advantages of simplicity, rapidity, economic and specificity, and will provide a new scheme for the simultaneous detection of basic orange Ⅱ and acid orange Ⅱ in food.
|
Received: 2017-06-16
Accepted: 2017-10-30
|
|
Corresponding Authors:
FANG Guo-zhen
E-mail: fangguozhen@tust.edu.cn
|
|
[1] Golka K,Kopps S,Myslak Z W. Toxicology Letters,2004,151(1):203.
[2] Fang Guozhen, Wu Yu,Dong Xiaomeng,et al. Journal of Agricultural and Food Chemistry,2013,61(16):3834.
[3] Huang Rongfu,Han Sungyub,Li Xiang. Analytical Bioanalytical Chemistry,2013,405(21):6815.
[4] Andrea Lucotti,Matteo Tommasini,Michele Casella,et al. Vibrational Spectroscopy,2012,62(5):286.
[5] Li Dawei,Qu Lulu,Zhai Wenlei,et al. Environmental Science Technology,2011,45(9):4046.
[6] CHEN Yan-qiong, HAO Yong, QI Xue-yong(陈艳琼,郝 勇,戚雪勇). Research and Practice on Chinese Medicines(现代中药研究与实践),2016,(2):10.
[7] LIU Kun(刘 琨). The Journal of Light Scattering(光散射学报),2005,17(4):332.
[8] QIN Jian-hong(秦剑红). Journal of Pharmaceutical Practice(药学实践杂志),2014, (3):206.
[9] XIA Li-ya, HAN Yuan-yuan, KUANG Lin-he(夏立娅,韩媛媛,匡林鹤). Chinese Journal of Analysis Laboratory(分析试验室),2010,29(6):15. |
[1] |
LIN Xue-liang1, LIN Duo1, 2, QIU Su-fang3, GE Xiao-song1, PAN Jian-ji3, WU Qiong1, LIN Hui-jing1, HUANG Hao2*. Detection of Nasopharyngeal Carcinoma Based on Human Saliva Surface-Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2430-2434. |
[2] |
ZHONG Hang, XU Jin-song, TAO Ran, DU Xiao-qing, CHEN Jun*, LIAO Jun-sheng*. Corrosion Resistance of Gold Surface Investigated by Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(08): 2435-2440. |
[3] |
ZHANG Lu-tao, ZHOU Guang-ming*, ZHANG Cai-hong, LUO Dan. The Preparation of the New Membrane-Like Gold Nanoparticles Substrate and the Study of Its Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1741-1746. |
[4] |
CHEN Si-yuan1, YANG Miao1, LIU Xiao-yun2*, ZHA Liu-sheng1*. Study on Au@Ag Core-Shell Composite Bimetallic Nanorods Laoding Filter Paper as SERS Substrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1747-1752. |
[5] |
LU Shu-hua1, 2*, WANG Yin-shu3. Developments in Detection of Explosives Based on Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1412-1419. |
[6] |
LI Jing-hui1, CHENG Nao-nao1, LIU Ji-cheng1, LI Li1*, JIA Shou-shi2. Rapid on-site TLC-SERS Detection of Four Sleep Problems Drugs Used as Adulterants in Health-Care Food[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1122-1128. |
[7] |
YANG Yu, PENG Yan-kun, LI Yong-yu*, FANG Xiao-qian, ZHAI Chen, WANG Wen-xiu, ZHENG Xiao-chun. Calibration Transfer of Surface-Enhanced Raman Spectroscopy Quantitative Prediction Model of Potassium Sorbate in Osmanthus Wine to Other Wine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 824-829. |
[8] |
LI Xiang1, TAN Li-li1, LIU Ji-cheng1, LI Li1*, JIA Shou-shi2. Rapid Detection of Four Chemical Components Added Illegally in Slimming Health Food with TLC Situ Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 830-836. |
[9] |
WENG Shi-zhuang1, YUAN Bao-hong2, ZHENG Shou-guo3, ZHANG Dong-yan1, ZHAO Jin-ling1, HUANG Lin-sheng1*. Dynamic Surface-Enhanced Raman Spectroscopy for Rapid and Quantitative Analysis of Edifenphos[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 454-458. |
[10] |
YANG Huan-di, LIN Xiang*, LIU Yuan-lan, ZHAO Hai-yan, WANG Li*. Preparation of Three-Dimensional Hotpot SERS Substrate with Sliver Nanocubes and Its Application in Detection of Pesticide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 99-103. |
[11] |
ZHANG Cai-hong, ZHOU Guan-ming*, ZHANG Lu-tao, LUO Dan, YU Lu, GAO Yi. An Application to Quantitative Analysis of Hg(Ⅱ) with L-Cysteine Molecular Probe by Surface-Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 117-122. |
[12] |
PENG Yi-jie, LIU Mu-hua, ZHAO Jin-hui*, YUAN Hai-chao, LI Yao, TAO Jin-jiang, GUO Hong-qing. Study on Detection of Nafcillin Residues in Duck Meat Using Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3736-3742. |
[13] |
LIU Jiang-mei1, LIU Wen-han1*, TENG Yuan-jie1, LAN Min-bo2, MA Su-zhen1, YUAN Rong-hui1, 3, NIE Jing1, HE Chang-jing1. Adsorption of Oxamyl on Fe3O4/Ag Magnetic Nanoparticles Surface with Surface-Enhanced Raman Scattering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2061-2066. |
[14] |
CHEN Yu-feng1,2, YANG Jin1, ZHUANG Zhi-ping2, RUAN Wei-dong1*, ZHAO Bing1. Study of Detection of 2-Mercaptobenzimidazole Based on Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2057-2060. |
[15] |
ZHANG Cai-hong, ZHOU Guang-ming*, CHENG Hong-mei, ZHANG Lu-tao, YU Lu, GAO Yi. Surface Enhanced Raman Spectroscopy Study of Complexes of Metal Ions with L-Cysteine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2079-2086. |
|
|
|
|