|
|
|
|
|
|
| The Preparation of the New Membrane-Like Gold Nanoparticles Substrate and the Study of Its Raman Spectroscopy |
| ZHANG Lu-tao, ZHOU Guang-ming*, ZHANG Cai-hong, LUO Dan |
| Key Laboratory of Luminescence and Real-time Analysis of the Ministry of Education, School of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, China |
|
|
|
|
Abstract As enhanced substrates, precious metal nanoparticles have been widely used in the study of the SERS.The traditional precious metal nanoparticles were still to be improved in the preparation methods, enhancement ability and accuracy. In this paper, simple and efficient method was developed to prepare a new membrane-like nanoparticles substrate. PVP was used as protectant and binder, gold nanoparticles were perpared by chemical reduction method. The effects of the reaction conditions on the reaction were investigated, including species of reducing agent, the temperature of the reaction, pH of the reaction system and the concentration of reducing agent. In addition, a new membrane-like nanoparticles substrate which had the best enhanced effect was prepared. The SERS characteristic of the substrate was inspected by rhodamine B. Its enhancement factor could reach to 6.5×105.The shape of gold nanoparticles was characterized by SEM. The results showed that it has a membrane structure and a large specific surface area which is conducive to molecular absorption. Compared with the traditional precious metal nanoparticles substrate, the new membrane-like gold nanoparticles substrate had a better enhanced effect and higher detection sensitivity and accuracy. All in all, it has a wide application prospect.
|
|
Received: 2017-06-19
Accepted: 2017-11-23
|
|
|
|
Corresponding Authors:
ZHOU Guang-ming
E-mail: gmzhou@swu.edu.cn
|
|
[1] Li B W, Chen L X. J. Instrum. Anal., 2015, 34(3): 302.
[2] Jani T, Valinger D, Kljusuri J G, et al. Food Chemistry, 2017, 224: 48.
[3] Fan M, Andrade G F S, Brolo A G. Analytica Chimica Acta, 2011, 693(1): 7.
[4] Le Ru E C, Blackie E, Meyer M, et al. Journal of Physical Chemistry, 2007, 111(37): 13794.
[5] Haes A J, Haynes C L, McFarland A D, et al. MRS Bulletin, 2005, 30(5): 368.
[6] Cao P G, Yao J L, Ren B, et al. Chemical Physics Letters, 2000, 316(1): 1.
[7] Jin R, Cao Y W, Mirkin C A, et al. Science, 2001, 294(5548): 1901.
[8] Ko H, Tsukruk V V. Small, 2008, 4(11): 1980.
[9] Bishnoi S W, Lin Y, Tibudan M, et al. Analytical Chemistry, 2011, 83(11): 4053.
[10] Guerrini L, Garcia-Ramos J V, Domingo C, et al. Analytical Chemistry, 2009, 81(3): 953.
[11] Kang T, Yoo S M, Yoon I, et al. Nano Letters, 2010, 10(4): 1189.
[12] Li J F, Huang Y F, Ding Y, et al. Nature, 2010, 464(7287): 392.
[13] Ling X, Xie L, Fang Y, et al. Nano Letters, 2009, 10(2): 553.
[14] Li X, Cao M, Zhang H, et al. Journal of Colloid and Interface Science, 2012, 382(1): 28.
[15] Lee C H, Hankus M E, Tian L, et al. Analytical Chemistry, 2011, 83(23): 8953.
[16] JIANG Si-wen, LI Xia, ZHANG Yue-jiao，et al(蒋思文，李 霞，张月皎，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2016, 36(1): 99.
[17] FANG Yan, MA Lin-lin, SHAN Duo-liang，et al(方 艳，马琳琳，陕多亮，等). Chem. J. Chinese Universities(高等学校化学学报), 2015, 36(8)：1491.
[18] Joo S W. Vibrational Spectroscopy, 2004, 34(2): 269.
[19] Frens G. Nature, 1973, 241(105): 20.
[20] Dasgupta A, Singh D, Tandon S, et al. Journal of Nanophotonics, 2014, 8(1): 083899. |
| [1] |
FU Qiu-yue1, FANG Xiang-lin1, ZHAO Yi2, QIU Xun1, WANG Peng1, LI Shao-xin1*. Research Progress of Pathogenic Bacteria and Their Drug Resistance
Detection Based on Surface Enhanced Raman Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(05): 1339-1345. |
| [2] |
FU Ying-ying, ZHANG Ping, ZHENG Da-wei , LIN Tai-feng*, WANG Hui-qin, WU Xi-hao, SONG Jia-chen. Preparation and SERS Performance of Au-Nylon Flexible Membrane Substrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 692-698. |
| [3] |
SONG Hong-yan, ZHAO Hang, YAN Xia, SHI Xiao-feng, MA Jun*. Adsorption Characteristics of Marine Contaminant Polychlorinated Biphenyls Based on Surface-Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 704-712. |
| [4] |
ZHANG Lin1, WEN Bao-ying2, LIU Wei-wei1, FU Wen-xiang1, KONG Jing-lin1*, LI Jian-feng2*. Rapidly Detection of Chemical Warfare Agent Simulants by Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 110-114. |
| [5] |
XU Yang1, LEI Lei2, YAN Jun1*, CHEN Yu-yun1, TAN Xue-cai1, LIU Yu-qian1, WANG Qi3. Determination of Glutaraldehyde in Water by Surface Enhanced Raman Spectroscopy Based on Metal Organic Framework Composite Substrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(01): 115-123. |
| [6] |
SHI Si-qian, YANG Fang-wei, YAO Wei-rong, YU Hang, XIE Yun-fei*. Rapid Detection of Levamisole Residue in Pork by Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(12): 3759-3764. |
| [7] |
QIU Meng-qing1, 2, XU Qing-shan1*, ZHENG Shou-guo1*, WENG Shi-zhuang3. Research Progress of Surface-Enhanced Raman Spectroscopy in Pesticide Residue Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3339-3346. |
| [8] |
TAN Ai-ling1, ZHAO Rong1, SUN Jia-lin1, WANG Xin-rui1, ZHAO Yong2*. Detection of Chlorpyrifos Based on Surface-Enhanced Raman Spectroscopy and Density Functional Theory[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3462-3467. |
| [9] |
ZHANG Yan-jun, KANG Cheng-long, LIU Ya-qian, FU Xing-hu*, ZHANG Jin-xiao, WANG Ming-xue, YANG Liu-zhen. Rapidly Detection of Total Nitrogen and Phosphorus Content in Water by Surface Enhanced Raman Spectroscopy and GWO-SVR Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3147-3152. |
| [10] |
JIN Xiang-peng, LI Xing-jia, ZHANG Chen-jie, YUAN Ya-xian, YAO Jian-lin*. Surface Enhanced Raman Spectroscopic Investigation on SPR Catalyzed Decarboxylation of Ortho-Mercaptobenzoic Acid at Au Nanoparticles Monolayer Film[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3153-3158. |
| [11] |
ZOU Jing-xin1, LIU Yan-qin1, YUAN Ming-zhe1, WANG Qi-hang1, FAN Zhou2, WAN Fu3. Study on the Raman Spectral Characteristics in Ageing Condition Discrimination of Oil-Paper Insulation[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(10): 3159-3165. |
| [12] |
LIU Yan-mei1, PEI Yuan1, LI Bo2, LI Hui-yan3, WANG Xue-pei4, XIAN Hao-han1, WEI Ying-na4, CHEN Ying5, DI Zhi-gang6, WU Zhen-gang1*, WEI Heng-yong4*. Preparation of Gold/Silver/Titanium Nitride Suface-Enhanced Raman Substrate and Its Effect on Nicotinic Acid Quantitative Detection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(07): 2092-2098. |
| [13] |
XU Ning1, 2, LIU Mu-hua1, 2, YUAN Hai-chao1, 2, HUANG Shuang-gen1, 2, WANG Xiao1, 2, ZHAO Jin-hui1, 2*, CHEN Jian1, 2, WANG Ting1, 2, HU Wei1, 2, SONG Yi-xin1, 2. Rapid Identification of Sulfamethazine and Sulfadiazine Residues in Chicken Based on SERS[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(03): 924-931. |
| [14] |
SHEN Zheng-dong, KONG Xian-ming*, YU Qian, YANG Zhan-xu. Research Progress of Thin Layer Chromatography and Surface Enhanced Raman Scattering Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 388-394. |
| [15] |
YAN Shuai1, LI Yong-yu1*, PENG Yan-kun1, LIU Ya-chao1, HAN Dong-hai2. A Method for Correcting Nitrofurantoin Raman Signal in Honey Based on Internal Standard of Substrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(02): 546-551. |
|
|
|
|
