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| A Fluorescent Probe Based Host-Guest Complexation Between Cucurbit[7]uril and Neutral Red for the Detection of Paraquat Herbicide in Water Sample |
| TANG Qing1, ZHANG Jing2, SONG Gui-xian2, XI Yun-yun2, HUANG Ying2*, TAO Zhu2, ZHOU Qing-di3, WEI Gang4* |
1. College of Tobacco Science, Guizhou University, Guiyang 550025, China
2. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China
3. School of Chemistry, the University of Sydney, NSW 2006, Australia
4. Commonwealth Scientific and Industrial Research Organization (CSIRO), Manufacturing, P. O. Box 218, Lindfield, NSW 2070, Australia |
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Abstract We have now shown that a host-guest complex between cucurbit[7]uril (Q[7]) and neutral red (NR) can be used as a fluorescent probe for detecting the herbicide paraquat. The Q[7]/NR complex can be used to detect paraquat with high selectivity using fluorescence spectrometry. A linear correlation (ΔF=4.98+0.32c, ｒ=0.999 1) was observed between the fluorescence intensity and the concentration of PQ over the concentration range (1~8)×10-6 mol·L-1. The detection limit for PQ was 1.40×10-8 mol·L-1. Recoveries obtained with the proposed method in river water examples were 104%~108%. Such method provides a rapid, selective and sensitive strategy for herbicide detection in real samples.
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Received: 2016-09-20
Accepted: 2017-01-30
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Corresponding Authors:
HUANG Ying, WEI Gang
E-mail: yinghung128@163.com；Gang.wei@csiro.au
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[1] US Environmental Protection Agency, Drinking Water Health Advisory: Pesticides, Lewis Publishors, Chelsea, MI, 1989.
[2] Code of Federal Regulations, US Government Printing Office, Rev., 2001.
[3] Chen Y, Luo J, Yuan B, et al. Environ. Chem., 2012, 31: 748.
[4] Qiu K, Wu H, Zhang Z, et al. Chin. Pharm. J., 2009, 44: 1259.
[5] Zhang T, Tan J Y, Qi B K, et al. Chin. J. Nat. Med., 2009, 24: 161.
[6] Mallat E, Barzen C, Abuknesha R, et al. Anal. Chim. Acta, 2001, 427: 165.
[7] Raul G F, Pablo S J, Francisco S B, et al. Food Control, 2014, 41: 193.
[8] LIU Qi, JI Wen-bo, WANG Ai-jun(刘 奇，姬文博，王爱军). PTCA (Part B: Chem. Anal.)(理化检验:化学分册), 2014, 50: 594.
[9] Zhang N, Chen Y, Yu M, et al. Chem. Asian J., 2009, 4: 1697.
[10] GAO Jian-hua, ZHAI Hai-yun, CHEN Bin(高建华，翟海云，陈 彬). Chinese J. Anal. Chem.(分析化学), 2002, 30(3): 295.
[11] Freeman W A, Mock W L, Shih N Y, J. Am. Chem. Soc., 1981, 103：7367.
[12] Kim J, Jung I S, Kim S Y, et al. J. Am. Chem. Soc., 2000, 122：540.
[13] Kim K, Selvapalam N, Ko Y H, et al. Chem. Soc. Rev., 2007, 36, 267.
[14] Koner A L, Nau W M. Supramol. Chem., 2007, 19(1-2), 55.
[15] YANG Ji-yuan, SHEN Ai-zhuo, DU Li-ming, et al(杨吉元，申爱卓，杜黎明，等). Chinese J. Anal. Chem.(分析化学), 2010, 38(12): 1813.
[16] Wu W Y, Yang J Y, Du L M, et al. Spectrochimica Acta Part A, 2011, 79: 418.
[17] Li C F, Du L M, Wu H, et al. Chin. Chem. Lett., 2011, 22: 851.
[18] Zhang H M, Yang J Y, Du L M, et al. Anal. Methods., 2011, 3: 1156.
[19] Xing X Q, Zhou Y Y, Sun J Y, et al. Anal. Lett., 2013, 46: 694.
[20] Yao F, Liu H L, Wang G Q, et al. J. Environ. Sci., 2013, 25(6): 1245.
[21] Mohanty J, Bhasikuttan A C, Nau W M, et al. J. Phys. Chem. B., 2006, 110：5132.
[22] Kim J, Jung I S, Kim S Y, et al. J. Am. Chem. Soc., 2000, 122：540.
[23] Day A I, Blanch R J, Arnold A P, et al. Angew. Chem. 2002, 114：285. |
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