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| Raman and IR Study on Silicon Films at Transition Regime |
| FAN Shan-shan1，2, GUO Qiang3, YANG Yan-bin3, CONG Ri-dong3, YU Wei3, FU Guang-sheng1，3 |
1. School of Electronic and Information Engineering, Hebei University of Technology, Tianjin 300400, China
2. School of Science, Hebei University of Technology, Tianjin 300400, China
3. College of Physics Science and Technology, Hebei University, Key Laboratory of Photo-Electricity Information Materials of Hebei Province, Baoding 071002, China |
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Abstract A series of silicon films at transition regime from amorphous to microcrystalline phase with different hydrogen dilution ratios were fabricated by the plasma-enhanced chemical vapor deposition (PECVD) technique, and the microstructural properties of the films at transition regime from amorphous to microcrystalline phase were studied using Raman scattering and Fourier transform infrared spectroscopy. The paracrystalline structure was used to elucidate the microstructure of silicon films at transition regime from amorphous to microcrystalline phase. The paracrystalline fraction (fp) as a signature of intermediate range order for the silicon films was proposed. The results indicated that the transition from amorphous to microcrystalline phase took place with the increase of hydrogen dilution. Silicon film grown just below transition edge was characterized by high hydrogen content, compact structure and enhanced medium range order, and hydrogen mainly passivated the surface of the film. Silicon film grown just above transition edge was characterized by low hydrogen content, high crystalline fraction and low interface phase, and hydrogen etching played an important role during film growth. The microstructure topography detected by scanning electron microscope verified the results from Raman scattering and Fourier transform infrared spectra. Silicon films had good microstructural properties at transition regime from amorphous to microcrystalline phase, especially around transition edge and were available as intrinsic layer for the thin film solar cells.
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Received: 2017-09-10
Accepted: 2017-11-30
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[1] Zhao L, Diao H W, Zeng X B, et al. Physica B, 2010, 405(1): 61.
[2] Barro R, Gandia J J. Solar Energy Materials and Solar Cells, 2010, 94(2): 282.
[3] Li Z, Zhang X W. Physica Status Solidi A, 2010, 207(1): 144.
[4] Amor S B, Atyaoui M, Bousbih R. Solar Energy, 2014, 108: 126.
[5] Amor S B, Bousbih R, Ouertani R. Solar Energy, 2014, 103: 12.
[6] ZHANG Shi-bin, LIAO Xian-bo, AN Long(张世斌，廖显伯，安 龙). Acta Physica Sinica(物理学报), 2002, 51(8): 1811.
[7] Tsu D V, Chao B S, Ovshinsky S R. Applied Physics Letters, 1997, 71: 1317.
[8] Voyles P M, Abelson J R. Solar Energy Materials & Solar Cells, 2003, 78: 85.
[9] Danesh P, Pantchev B, Antonova K. Journal of Physics D: Applied Physics, 2003, 37(2): 249.
[10] Smets A H M, Matsui T, Kondo M. Applied Physics Letters, 2008, 92: 033506.
[11] PENG Wen-bo, LIU Shi-yong, XIAO Hai-bo(彭文博，刘石勇，肖海波). Acta Physica Sinica(物理学报), 2009, 58(8): 5716.
[12] Schropp R E I, Li H. Thin Solid Films, 2008, 516: 6818.
[13] Schropp R E I, Rath J K. Journal of Crystal Growth, 2009, 311: 760.
[14] Kiriluk K G, Fields J D, Simonds B J. Applied Physics Letters , 2013, 102: 133101.
[15] YUAN Jun-bao, YANG Wen, CHEN Xiao-bo(袁俊宝，杨 雯，陈小波). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2016, 36(2): 326. |
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