| 光谱学与光谱分析 |
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| Study on Speciation and Fractionation of Rare Earth Elements in Surface Sediments in Gansu, Ningxia and Inner Mongolia Sections of Yellow River |
| LIU Jing-jun, LAI Zi-juan, LIU Ying* |
| College of Life and Environmental Science, Minzu University of China, Beijing 100081, China |
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Abstract In the present paper, BCR sequential extraction and high resolution inductively coupled plasma-mass spectrometry (HR-ICP-MS) were performed to analyze the speciation contents of 14 kinds of rare earth elements (REE) in the surface sediments from 12 sampling sites (S1-S12) in Gansu, Ningxia and Inner Mongolia Sections of Yellow River, and REE fractionation were also studied. The results indicated that the contents of REE in 12 sediment samples were the same order. The average contents of 14 rare earth elements were in this order: Ce(66.4)>La(35.8)>Nd(28.6)>Pr(7.88)>Sm(5.87) >Gd(5.01)>Dy(4.53)>Yb(2.86)>Er(2.51)>Eu(1.31)>Ho(0.856)>Tb(0.760)>Tm(0.428)>Lu(0.404), which were similar to the Chinese soil background. The residual fractions of all elements were present at the highest percentages(71.9%～93.9%), which indicated that the bioavailability or environmental impact was low. The percentage of reducible fraction was the lowest, ranged from 0.20% to 3.87% with the mean value of 0.83%, while the oxidizable fraction percentage(7.61%) was close to acid-soluble fraction(7.69%). But in Maqu (S12), oxidizable percentage (16.1%) was significantly higher than the acid-soluble fraction(1.73%). Correlation analysis showed that there was a significant positive correlation between total organic carbon (TOC) content and oxidizable percentage, and the correlation coefficients were between 0.763 and 0.914. REE fractionation results showed that: the contents of REE in surface sediments of Gansu, Ningxia and Inner Mongolia Sections of Yellow River were mainly from soil weathering, with light-REE enrichment and Eu depletion. The chondrite-normalized curve implied that La and Ce in Jinshawan (S8) and Baotou-Dengkou (S1) and heavy REE at all the sampling points might have external REE sources.
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Received: 2012-08-10
Accepted: 2012-11-26
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Corresponding Authors:
LIU Ying
E-mail: liuying430@yahoo.com.cn
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[1] Yang S Y, Jung H S, Choi M S, et al. Earth Planet Sci. Lett., 2002, 201: 407.
[2] Hannigan R, Dorval E, Jones C, et al. Chem. Geol., 2010, 272: 20.
[3] YAO Fan-zhao, HU Xin, LIU Xin, et al(姚藩照, 胡 忻, 柳 欣, 等). Journal of the Chinese Rare Earth Society(中国稀土学报), 2010, 28(4): 495.
[4] CHEN Zu-yi, ZHU Xu-dong(陈祖义, 朱旭东). Journal of Ecology and Rural Environment(生态与农村环境学报), 2008, 24(1): 88.
[5] LI Yu-mei, REN Zhi-yong, YU Ling-hong, et al(李玉梅, 任智勇, 于玲红, 等). Yellow River(人民黄河), 2010, 32(12): 138.
[6] Wang Z L, Liu C Q. J. Oceanogr., 2008, 64(3): 407.
[7] PANG Shou-ji, YE Si-yuan, SU Xin, et al(庞守吉, 叶思源, 苏 新, 等). Acta Geoscientia Sinica(地球学报), 2008, 29(5): 607.
[8] HE Jiang, MI Na, KUANG Yun-chen, et al(何 江, 米 娜, 匡运臣, 等). Environmental Science(环境科学), 2004, 25(2): 61.
[9] YANG Shou-ye, LI Cong-xian, Jung H S, et al(杨守业, 李从先, Jung Hoi-Soo, 等). Progress in Natural Science(自然科学进展), 2003, 13(4): 365.
[10] PENG An, ZHU Jian-guo(彭 安, 朱建国). Environmental Chemistry and Ecological Effects of Rare Earth Elements(稀土元素的环境化学及生态效应). Beijing: China Environmental Science Press(北京: 中国环境科学出版社), 2003.
[11] The China Environmental Monitoring Station(中国环境监测总站). Background Value of China Soil Elements(中国土壤元素背景值). Beijing: China Environmental Science Press(北京: 中国环境科学出版社), 1990.
[12] ZHUANG Ke-lin, BI Shi-pu, SU Da-peng, et al(庄克琳, 毕世普, 苏大鹏, 等). Marine Geology & Quaternary Geology(海洋地质与第四纪地质), 2005, 25(4): 15.
[13] Tessier A, Campbell P G C, Bisson M. Anal. Chim. Acta, 1979, 51(07): 844.
[14] Quevauviller P H, Rauret G, Griepink B. Int. J. Environ. Anal. Chem., 1993, 51: 231. |
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