光谱学与光谱分析 |
|
|
|
|
|
Detection and Analysis of Polycyclic Aromatic Hydrocarbons Using Surface-Enhanced Raman Spectroscopy |
MA Jun1, LIU Shu1, SHI Xiao-feng1,2, HAN Xiao-hong1, KONG De-di1, ZHENG Rong-er1 |
1. Optics & Optoelectronics Laboratory, Ocean University of China, Qingdao 266100, China2. College of Science, Qingdao Agricultural University, Qingdao 266109, China |
|
|
Abstract In the present paper, the gold colloid with parameters optimized was used as surface-enhanced Raman scattering(SERS) active substrate to realize the trace detection of polycyclic aromatic hydrocarbons(PAHs) in water for the first time. Gold colloids with different size were prepared using chemical reduction method, and the optimum size selected at 632.8 nm excitation wavelength by experiment is (32±3) nm. The influence of pH value on the enhancement of PAHs was researched, and the optimal pH value is 13. Spectral intensity increased by approximately 20-fold compared with pH 6. The SERS spectra of naphthalene, phenanthrene and pyrene aqueous solutions were detected by the optimum gold colloid, and the minimum concentrations obtained were 20, 4 and 4nmol·L-1, respectively. There was a linear relationship between peak intensity and concentration, and the linear regression correlation coefficients were all above 0.985. For the mixture, the authors could distinguish each PAH easily for their own characteristic peaks. The experimental results show that such active substrate has a very high sensitivity as well as good application prospect.
|
Received: 2012-03-13
Accepted: 2012-06-20
|
|
Corresponding Authors:
MA Jun
E-mail: majun@ouc.edu.cn
|
|
[1] ZHAO Wen-chang, CHENG Jin-ping, XIE Hai-zhui, et al(赵文昌, 程金平, 谢海赘, 等). Periodical of Ocean University of China(环境科学与技术), 2006, 29(3): 105. [2] LI Xian-guo, GUO Xin-yun, ZHOU Xiao(李先国, 虢新运, 周 晓). Periodical of Ocean University of China(中国海洋大学学报), 2008, 38(3): 473. [3] Fleischmann M, Hendra P, McQuilla A J. Chemical Physics Letters, 1974, 26(2): 163. [4] Kneipp K, Wang Y, Kneipp H, et al. Physical Review Letters, 1997, 78(9): 1667. [5] Nie S M, Emory S R. Science, 1997, 275(5303): 1102. [6] Moskovits M. Rev. Mod. Phys., 1985, 57(3): 783. [7] Otto A. Journal of Raman Spectroscopy, 2005, 36(12): 497. [8] Olson L G, Uibe R H, Harris J M, et al. Applied Spectroscopy,2004, 58(12): 1394. [9] Peron O, Rinnert E, Lehaitre M, et al. Talanta, 2009, 79(2): 199. [10] Jones C L, Bantz K C, Haynes C L, Analytical and Bioanalytical Chemistry, 2009, 394(1): 303. [11] Xie Y, Wang X, Han X, et a1. Journal of Raman Spectroscopy, 2011, 42(5): 945. [12] WANG Jian, ZHU Tao, ZHANG Xu(王 健, 朱 涛, 张 续). Chinese Journal of Chemical Physics(物理化学学报), 1999, 15(5): 476. [13] Sanchez-Cortes S, Garcia-Ramos J V. Surface Science, 2001, 473(1-2): 133. [14] Frens G. Nature Physical Science, 1973, 241(1): 20. [15] LIU Kun, WU Shi-fa(刘 琨, 吴世法). Chinese Journal of Light Scattering(光散射学报), 2006, 17(4): 332. [16] WU Jie, ZHOU Guang-ming, LIU Lan, et al(吴 捷, 周光明, 刘 兰, 等). Chinese Journal of Spectroscopy Laboratory(光谱实验室), 2008, 25(6): 1171. [17] Costa J C S, Sant’Ana A C, Corio P, et al. Talanta, 2006, 70(5): 1011. |
[1] |
ZHANG Lu-tao, ZHOU Guang-ming*, ZHANG Cai-hong, LUO Dan. The Preparation of the New Membrane-Like Gold Nanoparticles Substrate and the Study of Its Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1741-1746. |
[2] |
CHEN Si-yuan1, YANG Miao1, LIU Xiao-yun2*, ZHA Liu-sheng1*. Study on Au@Ag Core-Shell Composite Bimetallic Nanorods Laoding Filter Paper as SERS Substrate[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(06): 1747-1752. |
[3] |
LU Shu-hua1, 2*, WANG Yin-shu3. Developments in Detection of Explosives Based on Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(05): 1412-1419. |
[4] |
LI Jing-hui1, CHENG Nao-nao1, LIU Ji-cheng1, LI Li1*, JIA Shou-shi2. Rapid on-site TLC-SERS Detection of Four Sleep Problems Drugs Used as Adulterants in Health-Care Food[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1122-1128. |
[5] |
WANG Yu-tian, LIU Ting-ting*, LIU Ling-fei, YANG Zhe, CUI Yao-yao. Determination of Polycyclic Aromatic Hydrocarbons in Water Based on Three Dimensional Fluorescence Spectroscopy Combined with Wavelet Compression and APTLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(04): 1171-1177. |
[6] |
YANG Yu, PENG Yan-kun, LI Yong-yu*, FANG Xiao-qian, ZHAI Chen, WANG Wen-xiu, ZHENG Xiao-chun. Calibration Transfer of Surface-Enhanced Raman Spectroscopy Quantitative Prediction Model of Potassium Sorbate in Osmanthus Wine to Other Wine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 824-829. |
[7] |
WANG Xiang1, 2, 3, ZHAO Nan-jing1, 3*, YU Zhi-min2, MENG De-shuo1, 3, XIAO Xue1, 3, ZUO Zhao-lu1, 3,. Detection Method Progress and Development Trend of Organic Pollutants in Soil Using Laser-Induced Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(03): 857-863. |
[8] |
WENG Shi-zhuang1, YUAN Bao-hong2, ZHENG Shou-guo3, ZHANG Dong-yan1, ZHAO Jin-ling1, HUANG Lin-sheng1*. Dynamic Surface-Enhanced Raman Spectroscopy for Rapid and Quantitative Analysis of Edifenphos[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(02): 454-458. |
[9] |
YANG Huan-di, LIN Xiang*, LIU Yuan-lan, ZHAO Hai-yan, WANG Li*. Preparation of Three-Dimensional Hotpot SERS Substrate with Sliver Nanocubes and Its Application in Detection of Pesticide[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 99-103. |
[10] |
ZHANG Cai-hong, ZHOU Guan-ming*, ZHANG Lu-tao, LUO Dan, YU Lu, GAO Yi. An Application to Quantitative Analysis of Hg(Ⅱ) with L-Cysteine Molecular Probe by Surface-Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2018, 38(01): 117-122. |
[11] |
PENG Yi-jie, LIU Mu-hua, ZHAO Jin-hui*, YUAN Hai-chao, LI Yao, TAO Jin-jiang, GUO Hong-qing. Study on Detection of Nafcillin Residues in Duck Meat Using Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(12): 3736-3742. |
[12] |
LIU Jiang-mei1, LIU Wen-han1*, TENG Yuan-jie1, LAN Min-bo2, MA Su-zhen1, YUAN Rong-hui1, 3, NIE Jing1, HE Chang-jing1. Adsorption of Oxamyl on Fe3O4/Ag Magnetic Nanoparticles Surface with Surface-Enhanced Raman Scattering[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2061-2066. |
[13] |
CHEN Yu-feng1,2, YANG Jin1, ZHUANG Zhi-ping2, RUAN Wei-dong1*, ZHAO Bing1. Study of Detection of 2-Mercaptobenzimidazole Based on Surface Enhanced Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2057-2060. |
[14] |
ZHAO Xiao-hui1, 2, ZENG Ya-ling1, 2, QIU You-li1, 2, LI Yu1, 2*. Vibration Identification of PAHs Molecular Raman Signatures Based on Group Theory[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2067-2072. |
[15] |
ZHANG Cai-hong, ZHOU Guang-ming*, CHENG Hong-mei, ZHANG Lu-tao, YU Lu, GAO Yi. Surface Enhanced Raman Spectroscopy Study of Complexes of Metal Ions with L-Cysteine[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2017, 37(07): 2079-2086. |
|
|
|
|