| 光谱学与光谱分析 |
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| Raman Spectroscopic Study of the Complex and Quantitative Analysis in the System CuCl2-H2O and FeCl3-H2O |
| YANG Dan, XU Wen-yi |
| The Institute of Mineral Resources, Chinese Academy of Geological Sciences, MLR Key Laboratory of Mefallogenesis and Resource Assessment, Beijing 100037, China |
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Abstract In the present paper, the Raman peaks of complex in the CuCl2-H2O system and FeCl3-H2O system were studied in detail. In the CuCl2-H2O system, the superimposed characteristic peaks of various complex formed by Cu2+and Cl-(such as [CuCl4]2- and [CuCl6]4-) may be formed the peak of 286 cm-1, and the superimposed characteristic peaks of various complex formed by Cu2+ hydrate([Cu(H2O)4]2+ and [Cu(H2O)6]2+ based ) may be formed the peak of 412 cm-1 ; Through the analysis of peak parameters, we has founded two quantitative relationships : ① The peak intensity ratio (I1/I3 400 or I2/I3 400) of 286 cm-1(or 412 cm-1)and OH stretching Raman spectrum of water (at 3 400 cm-1) and concentration ; ② The integral area of 286 cm-1 (or 412 cm-1 ) and concentration. In the FeCl3-H2O system, 173 and 331 cm-1 might be attributed to [FeCl4]- that is the most common form of FeCl3 complex in aqueous solution. The superimposed characteristic peaks of various complex formed by Fe3+and Cl-(such as [FeCl]2+，[FeCl2]+ etc) may be formed the broad peak of 173 cm-1, and the superimposed characteristic peaks of various complex formed by Fe3+ hydrate([Fe(H2O)4]3+ and [Fe(H2O)6]3+ based) may be formed the broad weak peak behind of 331 cm-1. Through the analysis of peak parameters, we has founded two quantitative relationships : ①The integral area of 331 cm-1(A2) and concentration ; ②The integral area ratio of 173 and 331 cm-1(A1/A2)and concentration.
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Received: 2011-01-10
Accepted: 2011-04-16
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Corresponding Authors:
YANG Dan
E-mail: yangd_2004@yahoo.com.cn
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[1] Cline J, Bodnar R J. Journal of Geophysical Research, 1991, 96: 8113.
[2] Cline J S. Arizona Geological Society Digest, 1995, 20: 69.
[3] Lowenstern J B, Mahood G A, Rivers M I, et al. Science, 1991, 252: 1405.
[4] Heinrich C A, Gunther D, Audetat A, et al. Geology, 1999, 27: 755.
[5] Audétat A, Gunther D, Heinrich C A. Science, 1998, 279: 2091.
[6] Heinrich C A. Mineralium Deposita, 2005, 39: 864.
[7] Nagaseki H, Hayashi K. Geology, 2008, 36: 27.
[8] Clark R J H, Williams C S. Inorg. Chem., 1965, 4: 350.
[9] Nakagawa I, Shimanouchi T. Spectrochim. Acta, 1964, 20: 429.
[10] ZHANG Xiang-lin(张祥麟). Chemical Complex(络合物化学). Beijing: Metallurgy Industry Press(北京：冶金工业出版社)，1979. 102.
[11] Sabatini A, Sacconi L. Am. Chem. Chem. Soc., 1964, 86: 17.
[12] Beattie I R, Gilson T R, Ozin G A. Chem. Soc., A, 1969, 534.
[13] Avery J S, Burbridge C D, Goodgame D M L. Spectrochim. Acta, 1968. 24A: 1721.
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