光谱学与光谱分析 |
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Study of the Effect of Aliphatic Alcohol on the Inclusion Interaction of Qucertin-cyclodextrin Complexes |
LIU Xiu-ping, ZHANG Guo-mei, YANG Yu, DONG Chuan, SHUANG Shao-min |
Department of Chemistry, Shanxi University, Taiyuan 030006,China |
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Abstract The inclusion interaction of qucertin with β-cyclodextrin and its derivatives was studied by fluorimetry. The formation constants of their inclusion complexes were determined, and the stoichiometry ratio on the formation of the inclusion complexes was determined by equimolar continueous variation method. The effect of aliphatic alcohols with short chains on inclusion process was discussed. The results showed that the inclusion ability of β-CD and its derivatives was in the order: HP-β-CD>M-β-CD>β-CD. The effect of aliphatic alcohol on complexes was related to the carbon number and volume of alcohol molecules.
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Received: 2002-11-15
Accepted: 2003-06-20
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Corresponding Authors:
LIU Xiu-ping
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Cite this article: |
LIU Xiu-ping,ZHANG Guo-mei,YANG Yu, et al. Study of the Effect of Aliphatic Alcohol on the Inclusion Interaction of Qucertin-cyclodextrin Complexes [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(03): 323-326.
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URL: |
http://www.gpxygpfx.com/EN/Y2004/V24/I03/323 |
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