| 光谱学与光谱分析 |
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| Synthesis of Mixed Complexes of Lanthanum with 2,2-Bipyridyl and 1,10-Phenanthroline and Suudy of the Interaction of the Complexes with DNA |
| FANG Guang-rong，LI Ling, CAI Zhao-ｘia，LIU Li-ming，SONG Gong-wu |
| Faculty of Chemistry and Material Science, Hubei University, Wuhan 430062，China |
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Abstract A mixed complex of La with 2,2-bipyridyl (dpy) and 1,10-phenanthroline(phen) was synthesized. Elemental analysis, IR and TGA of the complex were investigated, thus it was proved that the conformation of it was La(dpy)(phen)Cl3. The interaction of the complex with DNA has been studied also. The spectra showed that the interaction between La(dpy)(phen)Cl3 and DNA experienced intercalation of long-range self-assembly. The study made it clear that the synthesized mixed complex La(dpy)(phen)Cl3 can interact with DNA, and La(dpy)(phen)Cl3 can be used for probing a nucleic acid.
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Received: 2002-06-21
Accepted: 2002-11-08
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Corresponding Authors:
FANG Guang-rong
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| Cite this article: |
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FANG Guang-rong,LI Ling,CAI Zhao-ｘia, et al. Synthesis of Mixed Complexes of Lanthanum with 2,2-Bipyridyl and 1,10-Phenanthroline and Suudy of the Interaction of the Complexes with DNA[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(03): 327-329.
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http://www.gpxygpfx.com/EN/Y2004/V24/I03/327 |
[1] YANG Pin，YANG Bin-sheng，CI Yun-xiang et al(杨 频，杨斌盛，慈云祥等). Foundational Medicine and Clinic(基础医学与临床)，1995，15(4): 15.
[2] YANG Pin，REN Rui，YANG Bin-sheng(杨 频，任 蕤，杨斌盛).Chemical Research and Application(化学研究与应用)，1994，6(1): 22.
[3] ZHAO Yong-liang，ZHAO Feng-ying(赵永亮，赵凤英). Chinese J． of Rare Earth(稀土)，2000，21(5): 5.
[4] QIAN Guo-dong，WANG Min-ｑuan，Lü Shao-zhe et al(钱国栋，王民权，吕少哲等). Chinese Journal of Luminescence(发光学报)，1998，19(1): 60.
[5] CHEN Jing，KANG Jing-wan，SONG Yu-min et al(陈 婧，康敬万，宋玉民等). Journal of Northwest Normal University(Natural Science)(西北师范大学学报(自然科学版)), 2000，36(3): 33.
[6] YANG Pin, YANG Bin-sheng(杨 频，杨斌盛). Conduction to A Method of Ion Probe(离子探针方法导论). Beijing(北京): Science Press(科学出版社)，1994: 138.
[7] NI Jia-zan, YANG Ping(倪嘉瓒，杨 频). Rare Earth Biochemistry(稀土生物无机化学). Beijing(北京): Science Press(科学出版社), 1995.
[8] WANG Xue-zhi(王学智). Chinese J． of Rare Earth(稀土)，1997，18(3): 14.
[9] WANG Xue-zhi，LUO Hong-jun，WU Ji-gui(王学智，罗洪君，吴集贵). Journal of Anhui Institute of Machinery and Electrical Engineering(安徽机电学院学报)，1994，9(1): 39.
[10] WANG Xue-zhi(王学智). Journal of Anhui Institute of Machinery and Electrical Engineering(安徽机电学院学报)，1996，11(1): 25.
[11] WANG Xue-zhi，ZHEN Li-min，SU Xiao-yun(王学智，郑利民，苏小云). Journal of East China University of Science and Technology(华东理工大学学报)，1996，22(1): 103.
[12] WANG Xue-zhi，QING Hong-gui(王学智，秦红桂). Journal of Anhui Institute of Machinery and Electrical Engineering(安徽机电学院学报)，1997，12(1): 26.
[13] HUANG Cheng-zhi，LI Yuan-fang，LI Nian-bing et al(黄承志，李原芳，李念兵等). Chinese Journal of Analytical Chemistry(分析化学)，1999，27(11): 1241.
[14] Carvlin M J，Fiel R J. Nucleic Acids Res.，1983，11：6121.
[15] Huang C Z，Li K A，Tong S Y. Anal. Chim. Acta，1997，345: 235.
[16] Sigel H. Coord. Chem., 1980, 20: 27. |
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