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| Review on the Literature of X-Ray Fluorescence Analysis of Rare Earth Elements in Geological Materials |
| WANG Yi-ya1, GAO Xin-hua2, WANG Yi-min1*, DENG Sai-wen1, LI Song1 |
1. National Research Center of Geoanalysis, Beijing 100037, China
2. Central Iron & Steel Research Institute, Beijing 100081, China |
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Abstract The analysis of rare earth elements had been a hot topic in inorganic analytical chemistry, and it was also a big problem for a long time. In the 1960s and 1970s, the research upsurge in the composition of complex polymetallic rare earth minerals in Bayan Obo and the research upsurge in the geochemistry of trace rare earth elements in the 1970s and 1980s greatly promoted the development of rare earth element analysis technology of geological materials in China. In this paper, the literature of rare earth elements in China and the basic conditions of rare earth element analysis were reviewed from the aspects of Monographs on rare earth element analysis, national standard reference materials for rare earth ores, national standard analysis methods and review papers on rare earth element analysis. In this paper, 63 papers on XRF analysis of rare earth elements in geological materials from 1964 to 2018 in China were collected. The papers were mainly reviewed from three aspects: analysis of rare earth elements in ore minerals, trace rare earth elements in various geological materials and micro area in situ analysis of rare earth elements in ore minerals. In this paper, the historical contribution of XRF to the determination of REE in early rare earth ores and minerals was briefly introduced. Finally, the existing problems of XRF in the analysis of rare earth elements in geological materials are discussed and suggestions for future development were put forward. There were 126 citations in this paper.
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Received: 2019-10-31
Accepted: 2020-03-02
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Corresponding Authors:
WANG Yi-min
E-mail: wym7852@126.com
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[1] CHENG Jian-zhong, CHE Li-ping( 程建忠, 车丽萍). Chinese Rare Earths(稀土), 2010, 31(2): 65.
[2] ZHANG Xiao-mo(张小陌). Natural Resource Economics of China(中国国土资源经济), 2018, 31(12): 22.
[3] SUN Jian-cheng(孙健程). China Nonferrous Metals(中国有色金属), 2017, (11): 60.
[4] ZOU Jun-yu, WANG Jian-ping, LIU Zhen-jiang, et al(邹君宇, 王建平, 柳振江, 等). Mining Research and Development(矿业研究与开发), 2014, 34(2): 119.
[5] Laboratory of Rare Element Mineral Chemistry, Guiyang Institute of Geochemistry, Chinese Academy of Sciences(中国科学院贵阳地球化学研究所稀有元素矿物化学实验室). Chinese Journal of Analytical Chemistry(分析化学), 1972, (1): 37.
[6] Guiyang Institute of Geochemistry, Chinese Academy of Sciences(中国科学院贵阳地球化学研究所). Chinese Journal of Analytical Chemistry(分析化学), 1973, (4): 86.
[7] Department of Analytical Chemistry, Wuhan University(武汉大学化学系分析化学教研室). Journal of Wuhan University·Natural Science(武汉大学学报·自然科学版), 1974, (1): 51.
[8] Analysis room of Metallurgical Research Institute of Baotou Steel(包钢冶金研究所分析室). Chinese Rare Earths Niobium(稀土与铌), 1976, (2): 27.
[9] NI Jia-zan, SU Qiang, YAO Ke-min, et al(倪加缵, 苏 锵, 姚克敏, 等). Chemistry(化学通报), 1979, (6): 1.
[10] YAO Xiu-ren, ZHOU Ji-xing, YIN Ming(姚修仁, 周继兴, 尹 明). Analytical Chemistry(分析化学), 1981, (1): 22.
[11] GAO Xiao-xia(高小霞). Chinese Rare Earths(稀土), 1981, (2): 44.
[12] YANG Rui-ying, HUANG Zhong-xiang, JIANG Yong, et al（杨瑞英, 黄忠祥, 江 泳, 等）. Nuclear Techniques (核技术), 1982, (4): 36.
[13] Professional Group of Rare Element Ore and Mineral Analysis and Testing Base of National Science and Technology Commission(国家科委稀有元素矿石、矿物分析测试基地专业组), Report Collection of 1964 National Test Base Annual Meeting(1964全国测试基地年会报告集（上、下集）, 1964, 1：1.
[14] Department of Chemistry, Wuhan University(武汉大学化学系). Analytical Chemistry of Rare Earth Elements (Volume Ⅰ and Volume Ⅱ)(稀土元素分析化学（上、下 ）). Beijing: Science Press(北京: 科学出版社)，1981, 1983. 499, 350.
[15] JIANG Zu-cheng, CAI Ru-xiu, ZHANG Hua-shan(江祖成, 蔡汝秀, 张华山). Analytical Chemistry of Rare Earth Elements, Second Edition(稀土元素分析化学, 第2版). Beijing: Science Press(北京: 科学出版社), 2000. 495.
[16] LI Mei, LIU Zhao-gang, WU Jin-xiu (李 梅, 柳召刚, 吴锦绣). Rare Earth Elements and their Analytical Chemistry(稀土元素及其分析化学). Beijing: Chemical Industry Press(北京: 化学工业出版社), 2009. 240.
[17] WANG Zhong-gang, YU Xue-yuan, ZHAO Zhen-hua(王中刚, 于学元, 赵振华). REE Geochemistry(稀土元素地球化学). Beijing: Science Press(北京: 科学出版社), 1989. 595.
[18] CHEN De-qian, CHEN Gang(陈德潜, 陈 刚). Practical REE Geochemistry(实用稀土元素地球化学). Beijing: Metallurgical Industry Press(北京: 冶金工业出版社), 1990. 268.
[19] FENG Jing(冯 静). Chemical Analysis and Metrology(化学分析计量), 2005, 14(4): 1.
[20] China National Standardization Management Committee(中国国家标准化管理委员会). Certified Standard Sample Certificate(有证标准样品证书) GSB 04-3309-2016, 2016, 1.
[21] China National Standardization Management Committee(中国国家标准化管理委员会). Certified Standard Sample Certificate(有证标准样品证书) GSB 04-3310-2016, 2016, 1.
[22] China National Standardization Management Committee(中国国家标准化管理委员会). Certified Standard Sample Certificate(有证标准样品证书) GSB 04-3311-2016, 2016, 1.
[23] National Standard Material Management Committee(全国标准物质管理委员会). List of Reference Materials(标准物质目录). Beijing: China Measurement Press(北京: 中国计量出版社), 2003. 174.
[24] WANG Yi-min, GU Tie-xin, WANG Xiao-hong, et al(王毅民, 顾铁新, 王晓红, 等), Practical Handbook of Reference Materials for Geoanalysis (Chinese-English, Second Edition)（实用地质分析标准物质手册（汉-英对照, 第2版））. Beijing: Geological Publishing House（北京: 地质出版社）, 2013. 589.
[25] GB/T 17417.1—1998 Method for Chemical Analysis of Rare Earth Ores-Determination of Separated Rare Earth Content-Preconcentration and Separation by Cation Exchange Resin, ICP-AES Method(《稀土矿石化学分析方法 阳离子交换树脂分离富集 电感耦合等离子体发射光谱法测定稀土分量》).
[26] GB/T 18882.1—2008 Chemical Analysis Methods of Mixed Rare Earth Oxide of Ion-Absorpted Type RE Ore-Determination of Fifteen REO Relative Content(离子型稀土矿混合稀土氧化物 化学分析方法 十五个稀土元素氧化物配分量的测定).
[27] GB/T 18114.1—2010 Chemical Analysis Methods of Rare Earth Concentrates(稀土精矿化学分析方法).
[28] CHENG Jie-ke, LIU Jin-chun, JIANG Zu-cheng(程介克, 刘锦春, 江祖成). Chinese Journal of Analysis Laboratory(分析试验室), 1988, (Z1): 54.
[29] CHENG Jie-ke, LIU Jin-chun, JIANG Zu-cheng(程介克, 刘锦春, 江祖成). Chinese Journal of Analysis Laboratory(分析试验室), 1990, (4): 54.
[30] CHENG Jie-ke(程介克). University Chemistry(大学化学), 1991, (6): 1.
[31] LIU Wen-hua, WANG Chang-qing, CAO Xiang-jiu(刘文华, 王长庆, 曹相九). Chinese Journal of Analysis Laboratory(分析试验室), 1992, (6): 51.
[32] LIU Wen-hua, WANG Chang-qing, CAO Xiang-jiu(刘文华, 王长庆, 曹相九). Chinese Journal of Analysis Laboratory(分析试验室), 1994, (5): 77.
[33] BAI Guang-bi, YUAN Li, YANG Wu(白光弼, 袁 莉, 杨 武). Chinese Journal of Analysis Laboratory(分析试验室), 1996, (5): 89.
[34] BAI Guang-bi, YUAN Li, YANG Wu(白光弼, 袁 莉, 杨 武). Chinese Journal of Analysis Laboratory(分析试验室), 1998, (6): 55.
[35] LIU Wen-hua, LIU Peng-yu(刘文华, 刘鹏宇). Chinese Journal of Analysis Laboratory(分析试验室), 2002, (3): 89.
[36] LIU Wen-hua(刘文华). Chinese Journal of Analysis Laboratory(分析试验室), 2011, 30（6）: 106.
[37] LIU Wen-hua(刘文华). Chinese Journal of Analysis Laboratory(分析试验室), 2012, 31（7）: 111.
[38] TIAN Chun-xia, LIU Wen-hua, LIU Jing(田春霞, 刘文华, 刘 璟). Chinese Journal of Analysis Laboratory(分析试验室), 2018, 37（2）: 222.
[39] LEI Jian-quan, WANG Zheng-zhen(雷剑泉, 王正珍). Geology-Geochemistry(地质地球化学), 1985, (S1): 89.
[40] LEI Jian-quan(雷剑泉). Geology-Geochemistry(地质地球化学), 1991, (1): 59.
[41] JIANG Zu-cheng, HU Cheng(江祖成, 胡 诚). Journal of Analytical Science(分析科学学报), 1995, 11(2): 62.
[42] ZHOU Shi-lin, LIU Fang, GAO Ming-hui, et al(周仕林, 刘 芳, 高明慧, 等). Physical Testing and Chemical Analysis（Part B: Chemical Analysis）(理化检验-化学分册), 2014, 50(3): 392.
[43] ZHUO Xiu-ying(卓秀英). Guangzhou Chemical Industry(广州化工), 2015, 43（16）: 63.
[44] WU Xing(伍 星). Journal of Rare Earths(中国稀土学报), 2006, (24): 137.
[45] GAO Lan, KANG Jin-wen(高 兰, 亢锦文). China Nonferrous Metals(中国有色金属), 2009, 19: 72.
[46] CHENG Ming-yan, LIU He-lian, WU Wei-ming, et al(程明焱, 刘和连, 吴伟明, 等). Nonferrous Metals Science and Engineering(有色金属科学与工程), 2012, 3(4): 108.
[47] YI Li-ying(伊丽莹). Rock and Mineral Analysis(岩矿测试), 1992, Z1: 173.
[48] SUN Chao-yang, HE Ying-ting, GONG Zu-xing, et al(孙朝阳, 贺颖婷, 龚祖星, 等). Shangdong Land and Resources(山东国土资源), 2015, 31（11）: 63.
[49] HUA Hai-long (花海隆). Technology Innovation and Application(科技创新与应用), 2013, (22): 293.
[50] WANG Xue-yan(王雪艳). Scientific and Technological Innovation(科学技术创新), 2017, 31: 74.
[51] XU Chun-cai(许春才). Jiang Xi Nonferrous Metals Information Network(江西有色金属), 1988, 4: 54.
[52] ZHANG Qi-chao, HE Chun-fu, REN Hong-xing(张启超, 贺春福, 任红星). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1992, 12(1): 89.
[53] LU Shao-lan, LI Shi-zhen, HAO Gong-zhang, et al(陆少兰, 李世珍, 郝贡章, 等). Chinese Journal of Analysis Laboratory(分析试验室), 1995, 14(1): 66.
[54] WU Wen-qi, XU Tao, HAO Qian, et al. Journal of Rare Earths, 2010, 28(S): 30.
[55] WU Wen-qi, XU Tao, HAO Qian, et al(吴文琪, 许 涛, 郝 茜, 等). Metallurgical Analysis(冶金分析), 2011, 31（3）: 33.
[56] XIE Zhong-xin, LI Jun-ling, TIAN Shu-gui, et al(谢忠信, 李君龄, 田淑贵, 等). Report Collection of Annual Meeting of National Test Base (Part Ⅰ), Beijing: State Scientific and Technological Commission (全国测试基地年会报告集（上集）, 北京: 国家科委), 1964, 257.
[57] XIE Zhong-xin, LIU Yi-kuan(谢忠信, 刘益宽). Report Collection of Annual Meeting of National Test Base (Part Ⅰ), Beijing: State Scientific and Technological Commission(全国测试基地年会报告集（上集）, 北京: 国家科委), 1964, 265.
[58] ZHAO Zong-ling, MA Guang-zu, LIANG Guo-li(赵宗玲, 马光祖, 梁国立). Report Collection of Annual Meeting of National Test Base (Part Ⅰ), Beijing: State Scientific and Technological Commission(全国测试基地年会报告集（上集）, 北京: 国家科委), 1964, 272.
[59] ZHU Fu-sheng, LUO Jin-xin(祝甫生, 罗津新). Physical Testing and Chemical Analysis Part B: Chemical Analysis( 理化检验（化学分册）), 1979, 6（6）: 25.
[60] CHEN Yuan-pan(陈远盘). Chinese Journal of Analytical Chemistry(分析化学), 1981, 9（1）: 61.
[61] JIANG Jing-kan, WANG Tao-zhen, WANG Hou-guang, et al(蒋敬侃, 王桃珍, 王厚光, 等). Chinese Journal of Analysis Laboratory(分析试验室), 1982, (1): 23.
[62] LU Shao-lan, HAO Gong-zhang, BU Sai-bin, et al(陆少兰, 郝贡章, 卜赛斌, 等). Chinese Journal of Rare Metals(稀有金属), 1982, (6): 45.
[63] LU Shao-lan, XU Pei-zhen, LI Shi-zhen, et al(陆少兰, 许佩珍, 李世珍, 等). Journal of the Chinese Society of Rare Earths(中国稀土学报), 1984, (1): 88.
[64] DING Shan-bao, LI Xian-zhong(丁善宝, 李献忠). Chinese Journal of Analysis Laboratory(分析试验室), 1983, (3): 54.
[65] WANG Zi-yao, HE Chun-fu, LIN Jing-xiang, et al(王子尧, 贺春福, 林景祥, 等). Chinese Journal of Analytical Chemistry(分析化学), 1985, (2): 105.
[66] WANG Zi-zhen(王子箴). Jiang Xi Nonferrous Metals Information Network(江西有色金属), 1987, (3): 55.
[67] HE Chun-fu, LIU Xue-dong, REN Hong-xing(贺春福, 刘学东, 任红星). Chinese Journal of Analytical Chemistry(分析化学), 1987, (10): 931.
[68] MAO Zhen-wei(毛振伟). Chinese Rare Earths(稀土), 1987，(1): 55.
[69] ZHAO Gui-wen, TANG Yu-qi, MAO Zhen-wei(赵贵文, 唐予奇, 毛振伟). Journal of University of Science and Technology of China(中国科学技术大学学报), 1987, 17（3）: 419.
[70] LE Qun(乐 群). Physical Testing and Chemical Analysis（Part B: Chemical Analysis）(理化检验-化学分册), 1991, 27(4): 207.
[71] XIAO De-ming(肖德明). Uranium Geology(铀矿地质), 1992, 16(4): 242.
[72] CHEN Yong-jun(陈永君). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1993, 13(1): 151.
[73] MAO Zhen-wei, et al(毛振伟, 等). Physical Testing and Chemical Analysis（Part B: Chemical Analysis）(理化检验-化学分册), 1993, 29(4): 239.
[74] ZHU Bi-ru, XIONG Chao-dong, YANG Ge, et al(朱碧如, 熊朝东, 杨 戈, 等). Environment and Exploition(环境与开发), 1997, 4: 45.
[75] ZHANG Shu-ying, BU Sai-bin, CUI Feng-hui, et al(张淑英, 卜赛斌, 崔凤辉, 等). Metallurgical Analysis(冶金分析), 2000, 5: 22.
[76] GB/T 18882.2—2002 Chemical Analysis Methods for Mixed Rare Earth Oxide of Ion-Absorpted Type RE Ore Determination of Fifteen REO Relative Content X-ray Fluorescence Spectrometric Method(离子型稀土矿混合稀土氧化物化学分析方法 X-射线荧光光谱法测定—十五个稀土元素氧化物的配分量).
[77] LI Ping(李 萍). Journal of the Chinese Rare Earths Society(中国稀土学报), 2002, 20(S1): 199.
[78] ZHANG Shu-ying, BU Sai-bin(张淑英, 卜赛斌). Rock and Mineral Analysis(岩矿测试), 2003, (1): 37.
[79] LU Yi(逯 义). Rock and Mineral Analysis(岩矿测试), 2012, 31(2): 277.
[80] Institute of Geology and Mineral Resources(地质矿产研究所), Chinese Journal of Geology(地质科技), 1973（Supplement增刊）, 68.
[81] JING Zhao-zheng, ZHANG Bo-yi(荆照政, 张博仪). Physical Testing and Chemical Analysis（Part B: Chemical Analysis）(理化检验-化学分册), 1989, 25（6）: 355.
[82] GUO Cheng-cai, CHEN Yan(郭成才, 陈 艳). Chinese Rare Earths(稀土), 1996, (3): 70.
[83] DE Xi, WANG Shi-wu(德 喜, 王世武). Metallurgical Analysis(冶金分析), 1999, (01): 26.
[84] CHENG Ze, LIU Xiao-guang, TAN Yu-juan, et al(程 泽, 刘晓光, 谭玉娟, 等), Rock and Mineral Analysis(岩矿测试), 2005, 24(1): 79.
[85] JIANG Tian-yi, WU Wen-qi, ZHANG Shu-jie, et al(蒋天怡, 吴文琪, 张术杰, 等). Metallurgical Analysis(冶金分析), 2017, 37(12): 27.
[86] ZHOU Wei, ZENG Meng, WANG Jian, et al(周 伟, 曾 梦, 王 健, 等). Rock and Mineral Analysis(岩矿测试), 2018, 37(3): 298.
[87] FENG Liang-yuan, LI Ruo-ling, ZHANG Ya-wen,(丰梁垣, 李若龄, 张亚文, 等). Geochimica(地球化学), 1982, 1: 35.
[88] YI Wei-xi, ZHANG Zai-quan, YU Song-hua, et al(易惟熙, 张在权, 余松华, 等). Nuclear Technique(核技术), 1982, 4: 111.
[89] DIAO Gui-nian, CHEN Pi-tong, LI Jin-xun, et al(刁桂年, 陈丕通, 李锦勋, 等). Metallurgical Analysis and Test·Metallurgical Analysis Volume)(冶金分析与测试·冶金分析分册), 1983, 4: 224.
[90] AN Qing-xiang(安庆骧). Rock and Mineral Analysis(岩矿测试), 1984, 3(2): 162.
[91] XIAO De-ming, ZHANG Hong-wen, GAN Xuan-xian, et al(肖德明, 张鸿文, 甘漩现, 等). Chinese Journal of Analysis Laboratory(分析试验室), 1985, 4（2）: 1.
[92] HE Chun-fu, LIU Xue-dong, REN Hong-xing(贺春福, 刘学东, 任红星). Chinese Journal of Analytical Chemistry(分析化学), 1987, 15（10）: 933.
[93] ZHENG Hou-lin, LIU He-wu, JIN Xin-di(郑厚琳, 刘鹤武, 靳新娣). Rock and Mineral Analysis(岩矿测试), 1987, (4): 245.
[94] GAN Xuan-ji, ZHU Ning(甘璇玑, 朱 宁). Chinese Journal of Spectroscopy Laboratory(光谱实验室), 1989, (4): 178.
[95] LI Hua, HE Chun-fu, YUAN Xiu-shun(李 华, 贺春福, 袁秀顺). Chinese Rare Earths(稀土), 1989, 10(1): 14.
[96] SUN Ping-hui, WU Xiao-ling(孙平蕙, 武小玲). Mineral Resources and Geology(矿产与地质), 1989, (1): 76.
[97] FENG Liang-yuan, BAO Hui-lan, LI Ruo-ling, et al(丰梁垣, 鲍蕙兰, 李若龄, 等). Geochimica(地球化学), 1990, 9(1): 77.
[98] JIANG Gui-lan, CAO Shu-qin, WANG Duo-xi, et al(姜桂兰, 曹淑琴, 王多禧, 等). Chinese Journal of Analytical Chemistry(分析化学), 1994, (1): 47.
[99] WANG Yi-min, LIANG Guo-li(王毅民, 梁国立). Rock and Mineral Analysis(岩矿测试), 1984, 3(1): 58.
[100] WANG Yi-min, LIANG Guo-li(王毅民, 梁国立). Atomic Spectroscopy(原子光谱分析), 1981, (5): 10.
[101] WANG Yi-min, LIANG Guo-li(王毅民, 梁国立). Rock and Mineral Analysis(岩矿测试), 1984, 3(4): 354.
[102] LIANG Guo-li, WANG Yi-min(梁国立, 王毅民). Rock and Mineral Analysis(岩矿测试), 1984, 3(3): 262.
[103] ZHANG Shi-ding, LIANG Shu-ting, NIE Quan-xin, et al(张仕定, 梁述廷, 聂全新, 等). Geological Laboratory(地质实验室), 1992, 8(6): 335.
[104] LIANG Shu-ting(梁述廷). Trace Analysis(痕量分析), 1993, 9(1-2): 48.
[105] LIANG Shu-ting(梁述廷). Journal of Mineralogy and Petrology(矿物岩石), 1997, (1): 117.
[106] ZHANG Shu-hua, ZHANG Jian(张淑华, 张 建). Petroleum Geology & Oilfield Development in Daqing(大庆石油地质与开发), 2003, (3): 22.
[107] LI Xiao-li, ZHANG Qin(李小莉, 张 勤). Metallurgical Analysis(冶金分析), 2013, 33(7): 35.
[108] SHI Hui, LAI Wan-chang, LIN Hong-jian, et al(石 慧, 赖万昌, 林宏健, 等). Technology Innovation and Application(科技创新与应用), 2015, (3): 43.
[109] LIU Ju-qin, LI Xiao-li(刘菊琴, 李小莉). Metallurgical Analysis(冶金分析), 2018, (5): 7.
[110] YUAN Jing, SHEN Jia-lin, LIU Jian-kun, et al(袁 静, 沈加林, 刘建坤, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2018, 38(2): 582.
[111] ZHANG Ying, WANG Hong-min, ZHANG Hui, et al(张 颖, 汪虹敏, 张 辉, 等). Advances in Marine Science(海洋科学进展), 2019, 37(1): 32.
[112] MA Xin-pei，Palmer G R, MacArthur J D(马鑫培，Palmer G R, MacArthur J D). Journal of Nuclear and Radiochemistry(核化学与放射化学), 1991, (3): 183.
[113] AN Qing-xiang, WANG Rui-bing, DENG Sai-wen, et al(安庆骧, 王锐兵, 邓赛文, 等). Journal of the Chinese Rare Earths Society(中国稀土学报), 1996, 14(3): 280.
[114] LI Bing, ZHOU Jian-xiong, ZHAN Xiu-chun(李 冰, 周剑雄, 詹秀春). Acta Geologica Sinica(地质学报), 2011, 85(11): 1878.
[115] WANG Yi-min, GAO Yu-shu(王毅民，高玉淑). Practical X-Ray Spectral Line Charts and Tables(X射线谱线图和表). Beijing: Geological Publishing House(北京：地质出版社), 1994, 155. |
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Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
| [3] |
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| [4] |
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| [5] |
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| [8] |
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| [9] |
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