|
|
|
|
|
|
The Study of Non-Destructive Analysis of Tang Sancai Firing Technology |
SHAO Jin-fa1, LI Rong-wu2, PAN Qiu-li1, CHENG Lin1* |
1. Key Laboratory of Beam Technology of Ministry of Education, College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875, China
2. Department of Physics, Beijing Normal University, Beijing 100875, China
|
|
|
Abstract Tang Sancai is an important cultural heritage of China. The analysis of the chemical compositions and phase structures of the Tang Sancai body and glaze is helpful to studying the Tang Sancai raw materials and firing technologies. This paper reports the analysis results of chemical compositions and phase structures of the Tang Sancai from the Liquanfang Kiln, the Huangye Kiln, and modern products from the Shaanxi Provincial Museum by the micro X-Ray fluorescence spectrometer and the X-ray diffractometer. The results show that the raw materials of Tang Sancai bodies in the Liquanfang kiln and Huangye kiln come from different clays. The cristobalite (PDF 76-0932) and α-quartz (PDF 46-1045) are the main phase structures in the Tang Sancai bodies of Liquanfang kiln and Huangye kiln. However, a small number of α-Fe2O3 (PDF 16-0653) phase andtraces of mullite (PDF 83-1881) phase existed in the Tang Sancai bodies of Liquanfang kiln and Huangye kiln, respectively.It shows that the difference in the firing technology and raw materials of the two kilns results in the different mineral structures of the bodies. In the glaze of Tang Sancai, the coloring elements Fe, Cu, and Co in the glazes melted in the lead flux, and Fe and Cu blended in the mixed area of the yellow glaze and the green glaze. The XRD patterns of the glazes show that there are mainly amorphous glass phases and traces of α-quartz (PDF 46-1045) in the glass. In addition, a small amount of Pb8Cu(Si2O7)3 (PDF 31-0464) phase existed in the Tang Sancai green glaze of Liquanfang kiln; a large amount of CaAl2Si2O8(PDF 89-1462) phase existed in the Tang Sancai yellow glaze of Huangye kiln; a small number of α-Fe2O3 (PDF 47-1409) phase existed in the Tang Sancai yellow glaze of Liquanfang kiln. It indicates that the differences in the chemical compositions of the glaze raw materials and the firing technologies lead to the different mineral crystals in the Tang Sancai glazes. The concentrations of the main elements of the modern products’bodies and glazes are close to the Huangye kiln samples. However, there are significant differences between the fake and true Tang Sancai in the phase compositions of the bodies and glazes. In general, the combination of micro X-ray fluorescence and X-ray diffraction analysis technology could have broad application prospects in raw material origin, authenticity identification, and firing technology of ancient ceramics.
|
Received: 2022-01-18
Accepted: 2022-07-07
|
|
Corresponding Authors:
CHENG Lin
E-mail: chenglin@bnu.edu.cn
|
|
[1] LI Jia-zhi(李家治). History of Science and Technology in China (Ceramics Vol.) (中国科学技术史: 陶瓷卷). Beijing: Science Press(北京: 科学出版社), 1998. 467.
[2] Shen J Y, Henderson J, Evans J, et al. Archaeometry 2019, 61(2): 358.
[3] Chang D X, Ma R J, Zhang L R, et al. Ceramics International, 2020, 46(4): 4778.
[4] Cui J F, Lei Y, Jin Z B, et al. Archaeometry,2010, 52(4): 597.
[5] Li B P, Zhao J X, Greig A, et al. Journal of Archaeological Science, 2006, 33: 56.
[6] CHENG Lin, LI Mei-tian, KIM You-shi, et al(程 琳,李梅田,金优石,等). Atomic Energy Science and Technology(原子能科学技术), 2011, 45(11): 1399.
[7] Duan Z M, Liu J, Jiang Q L, et al. Nuclear Inst. and Methods in Physics Research B, 2019, 442: 13.
[8] Liu J, Shao J F, Shuai Q L, et al. Proc. SPIE 11780, Global Intelligent Industry Conference, 2020, 117800H.
[9] SHUAI Qi-lin, LIU Jun, SHAO Jin-fa, et al(帅麒麟,刘 俊,邵金发,等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2021, 41(3): 714.
[10] Wolff T, Malzer W, Mantouvalou I, et al. Spectrochimica Acta Part B, 2011, 66: 170.
[11] Rousseau R. Journal of Geosciences and Geomatics, 2013, 1(1): 1.
[12] Hartati H, Purwaningsih A, Tjahjandarie T S, et al. Open Chemistry, 2020, 18: 295.
|
[1] |
SUN Wei-ji1, LIU Lang1, 2*, HOU Dong-zhuang3, QIU Hua-fu1, 2, TU Bing-bing4, XIN Jie1. Experimental Study on Physicochemical Properties and Hydration Activity of Modified Magnesium Slag[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3877-3884. |
[2] |
ZHU Yu-qi1, 2, ZHANG Xin2, DU Pan-pan2, LIU Shu1, ZHANG Gui-xin1, 2, GUAN Song-lei2*, ZHENG Zhong1*. Infrared Spectroscopy and X-Ray Spectroscopy Combined With
Inductively Coupled Plasma Mass Spectrometry for Quality
Control of Mongolian Medicine Yu Grain Soil[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3163-3169. |
[3] |
LI Yu-tang1, WANG Lin-zhu1, 2*, LI Xiang3, WANG Jun1. Characterization and Comparative Analysis of Non-Metallic Inclusions in Zirconium Deoxidized Steel[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2916-2921. |
[4] |
GAO Ya1, LIAO Cui-ping1, ALATAN Chaolumen2, CHEN Jian-bo3, TU Ya4*. X-Ray Diffraction and Infrared Spectral Analysis of the Differential Chemical Indicators Between the Raw and Milk-Processed Corals[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2494-2499. |
[5] |
ZHOU Qing-qing1, LI Dong-ling1, 2, JIANG Li-wu1, 3*, WAN Wei-hao1, ZENG Qiang4, XUE Xin4, WANG Hai-zhou1, 2*. Quantitative Statistical Study on Dendritic Component Distribution of Single Crystal Blade Based on Microbeam X-Ray Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(07): 2112-2118. |
[6] |
XU Ming-kun, LIN Jia-xiang, ZHANG Xiao-lin, LI Zhen-yin, WANG Ya-ming, LIU Chun-tai, SHEN Chang-yu, SHAO Chun-guang*. In Situ Detection of Structural Evolution of Isotropic Polypropylene Crystals During Uniaxial Stretching by Two-Dimensional X-Ray Diffraction Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1426-1433. |
[7] |
SHI Zhi-feng1, 2, LIU Jia2, XIAO Juan2, ZHENG Zhi-wen1*. Investigation of Novel Method for Detecting Vanillin Based on X-Ray Diffraction Technology[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1563-1568. |
[8] |
WANG Mei-li1, 2, SHI Guang-hai2*, ZHANG Xiao-hui1, YANG Ze-yu2, 3, XING Ying-mei1. Experimental Study on High-Temperature Phase Transformation of Calcite[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(04): 1205-1211. |
[9] |
ZHANG Dian1, WANG Hui1, CHEN Yin-wei2, 3, WANG Ju-lin2, 3*. Identification and Influence of Color Components in Red Lime From the Roof of Yangxin Hall in the Palace Museum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 877-882. |
[10] |
ZHANG Yan1, 2, WANG Hui-le1, LIU Zhong2, ZHAO Hui-fang1, YU Ying-ying1, LI Jing1, TONG Xin1. Spectral Analysis of Liquefaction Residue From Corn Stalk Polyhydric
Alcohols Liquefaction at Ambient Pressure[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(03): 911-916. |
[11] |
FAN Qing-jie, SONG Yan, LAI Shi-quan*, YUE Li, ZHU Ya-ming, ZHAO Xue-fei. XRD Structural Analysis of Raw Material Used as Coal-Based Needle Coke in the Coking Process[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(06): 1979-1984. |
[12] |
PAN Qiu-li1, SHAO Jin-fa1, LI Rong-wu2, CHENG Lin1*, WANG Rong1. Non-Destructive Analysis of Red and Green Porcelain in Qing Dynasty[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(03): 732-736. |
[13] |
SUN Xue-peng1, 2, ZHANG Xiao-yun1, 2, SHAO Shang-kun1, 2, WANG Ya-bing1, 2, LI Hui-quan1, 2, SUN Tian-xi1, 2*. A Method Quickly to Measure the Size of the Confocal Volume of Confocal X-Ray Instrument[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3493-3497. |
[14] |
PENG Ya1,2, LI Dong-ling2,3*, WAN Wei-hao1,2, ZHOU Qing-qing3,4, CAI Wen-yi1,2, LI Fu-lin1, LIU Qing-bin2,3, WANG Hai-zhou2,3. Analysis of Composition Distribution of New Cast-Forging FGH4096 Alloy Turbine Disk Based on Microbeam X-Ray Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(11): 3498-3505. |
[15] |
WANG Yi1, 2, LI Chang-rong1, 2*, ZENG Ze-yun1, 2,XI Zuo-bing1, 2, ZHUANG Chang-ling1, 2. Study on Alumina/Cerium Oxide X-Ray Diffraction and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2021, 41(06): 1841-1845. |
|
|
|
|