| 光谱学与光谱分析 |
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| Electron Spectra of Chemical Assembly Mesoporous MCM-41 with Transition Metal Complexes |
| HUO Yong-qian, LI Jun, WANG Wei, GONG Ya-qiong, ZHANG Feng-xing* |
| Chemistry Department, Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Northwest University, Xi'an710069, China |
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Abstract In the paper the complexes of metal cobalt(Ⅲ), manganese(Ⅲ), iron(Ⅲ) and copper(Ⅱ) with Schiff-base N,N-ethylenebis(salicylideneaminnato) have been synthesized and characterized. The nanosized porous material MCM-41 has been functionalized by the modification of the internal pore surface with γ-aminopropyl and was assembled by the modification groups with metal complex of Schiff-base. These metal complexes and functionalized nanosized porous materials were charcterized by XRD, IR and UV-Vis. It is indicated by spectral analysis that the synthesized nanosized porous materials have been confirmed to be MCM-41 with hexagon bores, and the γ-aminopropyls have been bonded on their internal pore surface. And the complexes of metal cobalt(Ⅲ), manganese(Ⅲ), iron(Ⅲ) and copper(Ⅱ) with Schiff-base N,N-ethylenebis(salicylideneaminnato) were assembled into MCM-41. The IR spectra of these samples show that there were characteristic absorptions of the amino and the Schiff base groups, and the absorption of amino shifted to longer wavelength.
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Received: 2003-01-06
Accepted: 2003-05-16
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Corresponding Authors:
ZHANG Feng-xing
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| Cite this article: |
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HUO Yong-qian,LI Jun,WANG Wei, et al. Electron Spectra of Chemical Assembly Mesoporous MCM-41 with Transition Metal Complexes [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(03): 281-284.
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| URL: |
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http://www.gpxygpfx.com/EN/Y2004/V24/I03/281 |
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