| 光谱学与光谱分析 |
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| The UV Spectra of Heterocyclic Selenium Compounds and Metallic Ions in Ethanol Solutions |
| ZHENG Wen-jie1，2，ZENG Xin-hua1，YANG Fang1，HE Hong-zhi1，BAI Yan1，LI Yi-qun1，GUO Bao-jiang2 |
1.Department of Chemistry, Ji′nan University, Guangzhou 510632, China
2.Biotech Research Institute, South China Normal University, Guangzhou 510631, China |
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Abstract The UV spectra of heterocyclic selenium compounds and metallic ions in ethanol solutions were investigated in this paper. Heterocyclic selenium compounds included 4,5-benzopiazselenole (BP), anthra [1, 2-c][1, 2, 5] selenadiazol-6, 11-dione(AS), piazselenole (PS), 5-methyl- piazselenole (MP), 4,6-diBr- piazselenole(DBP) and 4,4＇-dipiazselenole (DP). Several important results were obtained: (1)The absorption wavelengths λ of piazselenoles were bathochromic and their ε increased with the increased conjugative effect; (2) Sn(Ⅳ)enhanced the UV absorption of piazselenoles at higher frequencies with the ratio of nSn(Ⅳ)/nPS at 1; (3) The UV absorption of BP was obviously enhanced by Sn(Ⅳ)，Cd(Ⅱ)，Cr(Ⅲ)，Sb(Ⅲ)，Fe(Ⅲ)，Fe(Ⅱ)and Cu(Ⅱ), while Zn(Ⅱ)had little effect on the UV of BP;(4) The UV absorption of piazselenoles at higher frequencies was enhanced by Sn(Ⅳ)，Cr(Ⅲ) and Sb(Ⅲ), and the peak of MP at 233 nm was blunt in MP-M solutions.
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Received: 2002-06-18
Accepted: 2002-12-18
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Corresponding Authors:
ZHENG Wen-jie
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| Cite this article: |
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ZHENG Wen-jie,ZENG Xin-hua,YANG Fang, et al. The UV Spectra of Heterocyclic Selenium Compounds and Metallic Ions in Ethanol Solutions [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(04): 470-473.
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| URL: |
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http://www.gpxygpfx.com/EN/Y2004/V24/I04/470 |
[1] ZHENG Wen-jie, OUYANG Zheng(郑文杰，欧阳政). The Application of Plant Organic Selenium to Chemistry and Medicine(植物有机硒的化学及其医学应用). Guangzhou: Ji′nan University Prass(广州：暨南大学出版社). 2001. 97.
[2] Klyman D L, Gunther W H H. Organic Selenium Compounds: Their Chemistry and biology, John Wiley ＆ Sons, INC, 1973.
[3] XU Hui-bi, HUANG Kai-xun(徐辉碧，黄开勋). Selenium Chemistry, Biochemistry and Their Application to Life Science(硒的化学、生物化学及其在生命科学中的应用). Wuhan: Huazhong Science and Technology University Press(武汉：华中理工大学出版社), 1994. 86.
[4] CAI Qian-tao，SHI Wen-zhao(蔡乾涛，施文赵). Analytical Laboratory(分析试验室)，1988，7(9)：26.
[5] ZHENG Wen-jie，ZENG Xin-hua，GUO Bao-jiang et al(郑文杰，曾鑫华，郭宝江等). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2004，24(1): 102.
[6] XIE Wen-lei，XU Wei-he，FENG Guang-zhu(谢文磊，徐卫河，冯光炷). Spectroscopy and Spectral Analysis(光谱学与光谱分析)，2001，21(5)：707.
[7] Wrinnt M C, Whitehead M A. J. Chem. Soc. Faraday Trans.，1992, 88(18): 2641.
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