| 光谱学与光谱分析 |
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| The IR Spectra of Complexes of Fiber Containing Amidoxime Groups with Fe(Ⅲ)，Co(Ⅱ)，Ni(Ⅱ)，Cd(Ⅱ) and Hg(Ⅱ) |
| WU Zhi-chuan，TAO Ting-xian，WANG Xue-qian |
| Department of Biochem. Engn.，Anhui University of Technology and Science, Wuhu 241000, China |
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Abstract By the reaction Fe3+，Co2+，Ni2+，Cd2+ and Hg2+ with fiber containing amidoxime groups modified polyacrylonitrile fiber(AOCF), a series of coordinate complexes-AOCF-Fe(Ⅲ)，AOCF-Co(Ⅱ)，AOCF-Ni(Ⅱ)，AOCF-Cd(Ⅱ) and AOCF-Hg(Ⅱ) were prepared in acid medium. The fibers containing amidoxime groups with and without metal ions were taken for FTIR in the range of 4 000-400 cm-1. Their major bonds were assigned and compared. The results showed that in all complexes some bands (νC—N，νCN and νN—O) were strengthened and a certain shift to higher wave number took place in the FTIR spectra with 4-21 cm-1 shifts observed. The amidoxime groups and metal ions were bonding with coordinated bond.
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Received: 2003-06-06
Accepted: 2004-01-16
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Corresponding Authors:
WU Zhi-chuan
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| Cite this article: |
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WU Zhi-chuan,TAO Ting-xian,WANG Xue-qian. The IR Spectra of Complexes of Fiber Containing Amidoxime Groups with Fe(Ⅲ)，Co(Ⅱ)，Ni(Ⅱ)，Cd(Ⅱ) and Hg(Ⅱ) [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2004, 24(04): 440-443.
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http://www.gpxygpfx.com/EN/Y2004/V24/I04/440 |
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