| 光谱学与光谱分析 |
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| The Change in Optical Spectra from Solid and Liquid Solution of Copper Phthalocyanines Derivatives |
| ZHENG Xiao-pan, HE Zhi-qun*, ZHANG Chun-xiu, XU Zheng, WANG Yong-sheng |
| Key Laboratory of Luminescence and Optical Information, Institute of Optoelectronic Technology, Beijing Jiaotong University, Beijing 100044, China |
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Abstract In the present work, the change in electronic absorption spectra from three copper phthalocyanines (CuPc, tb-CuPc, oo-CuPc) in different environments was investigated. The mechanism of red shift Q-band absorption from the three species in an organic solvent before and after protonation was discussed. This was used to compare with those dispersed in solid films. The relation between the molecular interactions and the spectra change was studied. In a combination of POM，DSC and XRD techniques, the structure and morphology of the thin films were characterised. It was found that the molecules in the doped matrices of PC were associated or aggregated. This association and hence the corresponding change in absorption spectra cannot be altered by the modification of dopant concentration.
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Received: 2005-01-26
Accepted: 2005-06-28
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Corresponding Authors:
HE Zhi-qun
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| Cite this article: |
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ZHENG Xiao-pan,HE Zhi-qun,ZHANG Chun-xiu, et al. The Change in Optical Spectra from Solid and Liquid Solution of Copper Phthalocyanines Derivatives[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2006, 26(06): 1109-1112.
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https://www.gpxygpfx.com/EN/Y2006/V26/I06/1109 |
[1] Simon J J André. Molecular Semiconductors: Photoelectrical Properties and Solar Cells. New York: Springer-Verlag, 1985.
[2] Piechocki C, Simon J, Skoulios A, et al. J. Am. Chem. Soc., 1982, 104: 5245.
[3] Keller H, Hatz R. Handbook of Liquid Crystals, 1980, 33: 145.
[4] Lenzboff C C, Lever A B P. Phthalocyanines, Properties and Application. VCH, Weinheim, 1989.
[5] Selami S, Erbil A, Aysen A. Dyes and Pigments. 1999, 42: 1372.
[6] Cook M J. Spectroscopy of New Materials. John Wiley and Sons, 1993, Chapter 3.
[7] HUANG Jin-ling, PENG Yi-ru, CHEN Nai-sheng(黄金陵, 彭亦如, 陈耐生). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2001, 21(1): 1.
[8] HUANG Jian-dong, LIU Er-sheng, YANG Su-ling, et al(黄剑东, 刘尔生，杨素苓，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2000, 20(1): 95.
[9] Berezin B D. Izo Vyssh, Uchebn Zaced. Khim. Khim. Tekhnol., 1959, 2: 165.
[10] Gaspard S, Verdaguer M, Viovy R. J. Chim. Phys., 1972, 69: 1740.
[11] Abramczyk H, Szymczyk I, Waliszewska G, et al. J. Phys. Chem. A, 2004, 108: 264.
[12] WANG Wen-jun, ZHANG Shan-biao, LI Shu-hong, et al(王文军, 张山彪，李叔红，等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2003, 23(5): 873.
[13] Chang A T, Marchon J C. Inorg. Chim. Acta, 1981, L241: 53.
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