| 光谱学与光谱分析 |
|
|
|
|
|
| The Study of Three-Dimensional Synchronous Fluorescence Spectral Characteristics of Liuwei Dihuang Pills |
| ZHU Chun1,2,4, XIE Xin3, ZHAO Jin-chen1, DU Jia-meng1, CHEN Guo-qing1,4*, ZHU Tuo1,4 |
1. School of Science, Jiangnan University, Wuxi 214122, China
2. School of Internet of Things, Jiangnan University, Wuxi 214122, China
3. Shanghai TCM-Integrated Hospital, Shanghai 200082, China
4. Jiangsu Provincial Research Center of Light Industrial Optoelectronic Engineering and Technology, Wuxi 214122, China |
|
|
|
|
Abstract Three-dimensional synchronous fluorescence of each component of Liuwei dihuang pills (Prepared rehmannia root, cornel, yam, alisma, poria cocos, and cortex moutan) is measured by using FLS920P fluorescence spectrometer. Feature parameters were extracted. It can be found that each component is fluorescent material and the lines are all different. Furthermore, Three-dimensional synchronous fluorescence of Liuwei dihuang pills boiling with standard water and non-standard water are all measured and there are significant differences between them. It can be applied in distinguishing different formula of Chinese medicine decoction. Experimental and Theoretical conclusion show that: the three-dimensional fluorescence spectrometry method and the combination of synchronous fluorescence spectroscopy method can further improve the sensitivity and selectivity of fluorescence spectroscopy, have a distinct advantage in a complex multi-component mixture of fluorescence spectroscopic analysis.The study can provide a convenient and reliable method for establishing a complete fingerprint of Chinese traditional medicine. It also can help identifying the component and the quality of Chinese patent medicine.
|
|
Received: 2015-08-31
Accepted: 2015-12-25
|
|
|
|
Corresponding Authors:
CHEN Guo-qing
E-mail: cgq2098@163.com
|
|
[1] DUAN Fu-jin(段富津). Prescription(方剂学). Shanghai: Shanghai Science and Technology Press(上海：上海科学技术出版社)，1995. 130.
[2] Chinese Pharmacopoiea 2010 Edition A(中国药典2010年版，一部). Beijing: Pharmaceutical Technology(北京：中国医药科技出版社)，2010. 597.
[3] XU Ji-qun, WANG Mian-zhi(许济群，王绵之). Prescription(方剂学). Shanghai: Shanghai Science and Technology Press(上海：上海科学技术出版社)，1985. 104.
[4] SHI Yang, WANG Hui-juan, ZHAO Zhi, et al(石 洋，王慧娟，赵 致，等). Journal of Mountain Agriculture and Biology(山地农业生物学报)，2013，32(1)：75.
[5] ZHANG Xiao-mei, KE Xiu-mei, LI Na, et al(张小梅，柯秀梅，励 娜，等). Chinese Journal of Experimental Traditional Medical Formulas(中国实验方剂学杂志)，2014，20(23)：75.
[6] XIE Tian, WANG Shu-ling, LIU Nan, et al(谢 恬，王淑玲，刘 楠，等). World Journal of Integrated Traditional Chinese and Western Medicine(世界中西医结合杂志)，2014，9(1)：40.
[7] XU Jing, WANG Cheng-fang, DU Shu-shan, et al(许 靖，王成芳，杜树山，等). Chinese Traditional and Pharmaceutical(中成药)，2014，36(3)：563.
[8] CHEN Yan-yan, LI Xiao-nan, WANG Yue-fei, et al(陈燕燕，李晓男，王跃飞，等). Chinese Journal of Science and Technology(中国科技论文)，2014，9(12)：1410.
[9] FENG Yong-hui, YANG Shi-ying, WANG Shu-chun, et al(冯永辉，杨世颖，王树春，等). Journal of Anhui Agricultural Sciences(安徽农业科学)，2011，39(29)：17874.
[10] LI Wen-bo, HAN Jian-ping, GAO Jun, et al(李文博，韩建平，高 钧，等). Chinese Journal of Analytical Chemistry(分析化学)，2011，39(3)：387.
[11] HUA Yong-li, WEI Yan-ming, GUO Yan-sheng, et al(华永丽，魏彦明，郭延生，等). Chinese Journal of Analytical Chemistry(分析化学), 2012，40(4)：602.
[12] SHI Xun-li, ZHANG Lin, HU Jia-wen(史训立，张 琳，胡家文). Chinese Journal of Spectroscopy Laboratory(光谱实验室)，2013，30(3)：1152.
[13] WANG Lin, PANG Qi-chang, MA Ji, et al(王 琳，庞其昌，马 骥，等). Acta Photonica Sinica(光子学报)，2011，40(6)：860.
[14] XU Jin-gou, WANG Zun-ben(许金钩，王尊本). Fluorescence Analysis Method(荧光分析法). Beijing：Science Press(北京：科学出版社)，2006. 154.
[15] SHANG Li-ping, YANG Ren-jie(尚丽平，杨仁杰). In Situ Fluorescence Spectroscopy Technology and Its Application(现场荧光光谱技术及其应用). Beijing：Science Press(北京：科学出版社)，2009. 167. |
| [1] |
LEI Hong-jun1, YANG Guang1, PAN Hong-wei1*, WANG Yi-fei1, YI Jun2, WANG Ke-ke2, WANG Guo-hao2, TONG Wen-bin1, SHI Li-li1. Influence of Hydrochemical Ions on Three-Dimensional Fluorescence
Spectrum of Dissolved Organic Matter in the Water Environment
and the Proposed Classification Pretreatment Method[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 134-140. |
| [2] |
GU Yi-lu1, 2，PEI Jing-cheng1, 2*，ZHANG Yu-hui1, 2，YIN Xi-yan1, 2，YU Min-da1, 2, LAI Xiao-jing1, 2. Gemological and Spectral Characterization of Yellowish Green Apatite From Mexico[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 181-187. |
| [3] |
HAN Xue1, 2, LIU Hai1, 2, LIU Jia-wei3, WU Ming-kai1, 2*. Rapid Identification of Inorganic Elements in Understory Soils in
Different Regions of Guizhou Province by X-Ray
Fluorescence Spectrometry[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 225-229. |
| [4] |
WANG Hong-jian1, YU Hai-ye1, GAO Shan-yun1, LI Jin-quan1, LIU Guo-hong1, YU Yue1, LI Xiao-kai1, ZHANG Lei1, ZHANG Xin1, LU Ri-feng2, SUI Yuan-yuan1*. A Model for Predicting Early Spot Disease of Maize Based on Fluorescence Spectral Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3710-3718. |
| [5] |
CHENG Hui-zhu1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, MA Qian1, 2, ZHAO Yan-chun1, 2. Genetic Algorithm Optimized BP Neural Network for Quantitative
Analysis of Soil Heavy Metals in XRF[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3742-3746. |
| [6] |
SONG Yi-ming1, 2, SHEN Jian1, 2, LIU Chuan-yang1, 2, XIONG Qiu-ran1, 2, CHENG Cheng1, 2, CHAI Yi-di2, WANG Shi-feng2，WU Jing1, 2*. Fluorescence Quantum Yield and Fluorescence Lifetime of Indole, 3-Methylindole and L-Tryptophan[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3758-3762. |
| [7] |
YANG Ke-li1, 2, PENG Jiao-yu1, 2, DONG Ya-ping1, 2*, LIU Xin1, 2, LI Wu1, 3, LIU Hai-ning1, 3. Spectroscopic Characterization of Dissolved Organic Matter Isolated From Solar Pond[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3775-3780. |
| [8] |
LI Xiao-li1, WANG Yi-min2*, DENG Sai-wen2, WANG Yi-ya2, LI Song2, BAI Jin-feng1. Application of X-Ray Fluorescence Spectrometry in Geological and
Mineral Analysis for 60 Years[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 2989-2998. |
| [9] |
XUE Fang-jia, YU Jie*, YIN Hang, XIA Qi-yu, SHI Jie-gen, HOU Di-bo, HUANG Ping-jie, ZHANG Guang-xin. A Time Series Double Threshold Method for Pollution Events Detection in Drinking Water Using Three-Dimensional Fluorescence Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(10): 3081-3088. |
| [10] |
MA Qian1, 2, YANG Wan-qi1, 2, LI Fu-sheng1, 2*, CHENG Hui-zhu1, 2, ZHAO Yan-chun1, 2. Research on Classification of Heavy Metal Pb in Honeysuckle Based on XRF and Transfer Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2729-2733. |
| [11] |
JIA Yu-ge1, YANG Ming-xing1, 2*, YOU Bo-ya1, YU Ke-ye1. Gemological and Spectroscopic Identification Characteristics of Frozen Jelly-Filled Turquoise and Its Raw Material[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2974-2982. |
| [12] |
YANG Xin1, 2, XIA Min1, 2, YE Yin1, 2*, WANG Jing1, 2. Spatiotemporal Distribution Characteristics of Dissolved Organic Matter Spectrum in the Agricultural Watershed of Dianbu River[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(09): 2983-2988. |
| [13] |
CHEN Wen-jing, XU Nuo, JIAO Zhao-hang, YOU Jia-hua, WANG He, QI Dong-li, FENG Yu*. Study on the Diagnosis of Breast Cancer by Fluorescence Spectrometry Based on Machine Learning[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2407-2412. |
| [14] |
ZHU Yan-ping1, CUI Chuan-jin1*, CHENG Peng-fei1, 2, PAN Jin-yan1, SU Hao1, 2, ZHANG Yi1. Measurement of Oil Pollutants by Three-Dimensional Fluorescence
Spectroscopy Combined With BP Neural Network and SWATLD[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2467-2475. |
| [15] |
LIU Xian-yu1, YANG Jiu-chang1, 2, TU Cai1, XU Ya-fen1, XU Chang3, CHEN Quan-li2*. Study on Spectral Characteristics of Scheelite From Xuebaoding, Pingwu County, Sichuan Province, China[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(08): 2550-2556. |
|
|
|
|
