| 光谱学与光谱分析 |
|
|
|
|
|
| Spectrum Characterization and Fine Structure of Copper Phthalocyanine-Doped TiO2 Microcavities |
| LIU Cheng-lin1,2, ZHANG Xin-yi2, ZHONG Ju-hua3, ZHU Yi-hua3, HE Bo4, WEI Shi-qiang4 |
1. Physics Department of Yancheng Teachers’ College, Yancheng 224002, China
2.Synchrotron Radiation Research Center, Fudan University, Shanghai 200433, China
3. Science School of East China University of Science and Technology, Shanghai 200237, China
4. National Synchrotron Radiation Lab, University of Science and Technology of China, Hefei 230029, China |
|
|
|
|
Abstract Copper phthalocyanine-doped TiO2 microcavities were fabricated by chemistry method. Their spectrum characterization was studied by Fourier transform infrared (FTIR) and Raman spectroscopy, and their fine structure was analyzed by X-ray absorption fine structure (XAFS). The results show that there is interaction of copper phthalocyanine (CuPc) and TiO2 microcavities after TiO2 microcavities was doped with CuPc. For example, there is absorption at 900.76 cm-1 in FTIR spectra, and the “red shift” of both OH vibration at 3392.75 cm-1 and CH vibration at 2848.83 cm-1. There exist definite peak shifts and intensity changes in infrared absorption in the C—C or C—N vibration in the planar phthalocyanine ring, the winding vibration of C—H inside and C—N outside plane of benzene ring. In Raman spectrum, there are 403.4, 592.1 and 679.1 cm-1 characterized peaks of TiO2 in CuPc-doped TiO2 microcavities, but their wave-numbers show shifts to anatase TiO2. The vibration peaks at 1586.8 and 1525.6 cm-1 show that there exists the composite material of CuPc and TiO2. These changes are related to the plane tropism of the molecule structure of copper phthalocyanine. XAFS showed tetrahedron TiO4 structure of Ti in TiO2 microcavities doped with copper phthalocyanine, and the changes of inner “medial distances” and the surface structure of TiO2 microcavities.
|
|
Received: 2006-06-28
Accepted: 2006-09-26
|
|
|
|
Corresponding Authors:
LIU Cheng-lin
E-mail: liuch@fudan.edu.cn
|
|
| Cite this article: |
|
LIU Cheng-lin,ZHANG Xin-yi,ZHONG Ju-hua, et al. Spectrum Characterization and Fine Structure of Copper Phthalocyanine-Doped TiO2 Microcavities[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(10): 1966-1969.
|
|
|
|
| URL: |
|
https://www.gpxygpfx.com/EN/Y2007/V27/I10/1966 |
[1] Chen L L, Li W L, Wei H Z, et al. Solar Energy Materials & Solar Cells, 2006, 90: 1788.
[2] Michal Wojdyla, Beate Derkowska, Waclaw Bata, et al. Optical Materials, 2006, 28: 1000.
[3] GAO Zhao-yang, ZHANG Xu, ZHENG Dai-shun, et al(郜朝阳, 张 旭, 郑代顺, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2004, 24(4): 502.
[4] Nguyen The Vinh, Lee Hynn Cheol, Yang O Bong, et al. Solar Energy Materials & Solar Cells, 2006, 90: 967.
[5] LIU Cheng-lin, ZHONG Ju-hua, LI Yuan-guang, et al(刘成林, 钟菊花, 李远光, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2005, 25(12): 1947.
[6] LIU Cheng-lin, LI Yuan-guang, ZHONG Ju-hua, et al(刘成林, 李远光, 钟菊花, 等). Function Material(功能材料), 1999, 30(2): 223.
[7] Lin Li, Minoru Mizuhata, Akihiko Kajinami, et al. Synthetic Metals, 2004, 146: 17.
[8] Wayne M Campbell, Anthony K Burrell, David L Officer, et al. Coordination Chemistry Reviews, 2004, 248: 1363.
[9] Di K, Zhu Y H, Yang X L, et al. Journal of Colloid and Interface Science, 2006, 294: 499.
[10] Haiyan Li, Carl P Tripp. Langmuir, 2005, 21: 2585.
[11] DING Han-ming, ZHANG Yin, CHEN Wen-qi, et al(丁旱明, 张 引, 陈文启, 等). Spectroscopy and Spectral Analysis(光谱学与光谱分析), 1997, 17(2): 73.
[12] Lei Miao, Sakae Tanemura, Shoichi Toh, et al. J. Crystal Growth, 2004, 264: 246.
[13] Wagemaker M, Lutzenkirchen Hechi D, Keil P, et al. Physica B, 2003, 336: 118. |
| [1] |
CHENG Jia-wei1, 2，LIU Xin-xing1, 2*，ZHANG Juan1, 2. Application of Infrared Spectroscopy in Exploration of Mineral Deposits: A Review[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 15-21. |
| [2] |
LI Jie, ZHOU Qu*, JIA Lu-fen, CUI Xiao-sen. Comparative Study on Detection Methods of Furfural in Transformer Oil Based on IR and Raman Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 125-133. |
| [3] |
YANG Cheng-en1, 2, LI Meng3, LU Qiu-yu2, WANG Jin-ling4, LI Yu-ting2*, SU Ling1*. Fast Prediction of Flavone and Polysaccharide Contents in
Aronia Melanocarpa by FTIR and ELM[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 62-68. |
| [4] |
GAO Feng1, 2, XING Ya-ge3, 4, LUO Hua-ping1, 2, ZHANG Yuan-hua3, 4, GUO Ling3, 4*. Nondestructive Identification of Apricot Varieties Based on Visible/Near Infrared Spectroscopy and Chemometrics Methods[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 44-51. |
| [5] |
LIU Jia, ZHENG Ya-long, WANG Cheng-bo, YIN Zuo-wei*, PAN Shao-kui. Spectra Characterization of Diaspore-Sapphire From Hotan, Xinjiang[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 176-180. |
| [6] |
BAO Hao1, 2，ZHANG Yan1, 2*. Research on Spectral Feature Band Selection Model Based on Improved Harris Hawk Optimization Algorithm[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 148-157. |
| [7] |
GUO Ya-fei1, CAO Qiang1, YE Lei-lei1, ZHANG Cheng-yuan1, KOU Ren-bo1, WANG Jun-mei1, GUO Mei1, 2*. Double Index Sequence Analysis of FTIR and Anti-Inflammatory Spectrum Effect Relationship of Rheum Tanguticum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2024, 44(01): 188-196. |
| [8] |
BAI Xue-bing1, 2, SONG Chang-ze1, ZHANG Qian-wei1, DAI Bin-xiu1, JIN Guo-jie1, 2, LIU Wen-zheng1, TAO Yong-sheng1, 2*. Rapid and Nndestructive Dagnosis Mthod for Posphate Dficiency in “Cabernet Sauvignon” Gape Laves by Vis/NIR Sectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3719-3725. |
| [9] |
WANG Qi-biao1, HE Yu-kai1, LUO Yu-shi1, WANG Shu-jun1, XIE Bo2, DENG Chao2*, LIU Yong3, TUO Xian-guo3. Study on Analysis Method of Distiller's Grains Acidity Based on
Convolutional Neural Network and Near Infrared Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3726-3731. |
| [10] |
DANG Rui, GAO Zi-ang, ZHANG Tong, WANG Jia-xing. Lighting Damage Model of Silk Cultural Relics in Museum Collections Based on Infrared Spectrum[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3930-3936. |
| [11] |
SUN Wei-ji1, LIU Lang1, 2*, HOU Dong-zhuang3, QIU Hua-fu1, 2, TU Bing-bing4, XIN Jie1. Experimental Study on Physicochemical Properties and Hydration Activity of Modified Magnesium Slag[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3877-3884. |
| [12] |
LI Xiao-dian1, TANG Nian1, ZHANG Man-jun1, SUN Dong-wei1, HE Shu-kai2, WANG Xian-zhong2, 3, ZENG Xiao-zhe2*, WANG Xing-hui2, LIU Xi-ya2. Infrared Spectral Characteristics and Mixing Ratio Detection Method of a New Environmentally Friendly Insulating Gas C5-PFK[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3794-3801. |
| [13] |
HU Cai-ping1, HE Cheng-yu2, KONG Li-wei3, ZHU You-you3*, WU Bin4, ZHOU Hao-xiang3, SUN Jun2. Identification of Tea Based on Near-Infrared Spectra and Fuzzy Linear Discriminant QR Analysis[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3802-3805. |
| [14] |
LIU Xin-peng1, SUN Xiang-hong2, QIN Yu-hua1*, ZHANG Min1, GONG Hui-li3. Research on t-SNE Similarity Measurement Method Based on Wasserstein Divergence[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(12): 3806-3812. |
| [15] |
LUO Li, WANG Jing-yi, XU Zhao-jun, NA Bin*. Geographic Origin Discrimination of Wood Using NIR Spectroscopy
Combined With Machine Learning Techniques[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(11): 3372-3379. |
|
|
|
|
