光谱学与光谱分析 |
|
|
|
|
|
The Interaction of Cucurbit[8]uril with Thionine and Carbendazim with Spectroscopic Method |
XI Yun-yun1, 2, TANG Qing1, HUANG Ying1, 2*, TAO Zhu2, XUE Sai-feng2, ZHU Qian-jiang2 |
1. The Engineering and Research Center for Southwest Bio-Pharmaceutical Resources Ministry of Education of Guizhou University, Guiyang 550025, China 2. Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou University, Guiyang 550025, China |
|
|
Abstract In this paper, the interaction of cucurbit [8]uril(Q[8]) with thionine (TH) and carbendazim (CBZ) were investigated with fluorescence and UV-Vis spectroscopy. The experimental results showed that the inclusion complex between Q[8] and TH informed was at molar ratios of 1∶2 in 0.01 mol·L-1 hydrochloric acid solution. The fluorescence intensity of the Q[8]/TH complexes quenched when Q[8] was added to TH solution, but fluorescence increasing of the Q[8]/TH complex with the addition of CBZ was observed. The fluorescence increasing values show a good linear relationship with the CBZ concentration within 0~3.5 μmol·L-1. The linear regression equation relating fluorescence intensity (If) to CBZ concentration (c) is If=0.45c+32.24 (r=0.999). The detection limit was 9.39×10-8 mol·L-1. Forthemore, the influence of foreign species on the analytical signal of the Q[8]/TH complex in the presence of carbendazim was established. No interference was observed from commonly used foreign species such as metal ions (Fe3+, Mg2+, Ca2+). In particular, benzimidazole compounds thiabendazole and fuberidazole do not interfere with CBZ determination at a specific concentration. The results revealed that complexation of Q[8] and TH with CBZ offers a fluorescent switching “on-off” effect which will supply a potential application in pesticide residues test.
|
Received: 2015-05-27
Accepted: 2015-09-01
|
|
Corresponding Authors:
HUANG Ying
E-mail: yinghung128@163.com
|
|
[1] Day A I, Arnold A P, Blanch R J, et al. J. Org. Chem., 2001, 66: 8094. [2] Joseph R, Nkrumah A, Clark R J, et al. J. Am. Chem. Soc., 2014, 136: 6602. [3] Zhang Q W, Tian H, Angew. Chem. Int. Ed., 2014, 53: 10582. [4] Fenley A T, Henriksen N M, Muddana H S, et al. J. Chem. Theory Comput., 2014, 10: 4069. [5] Manna A, Chakravorti S. Spectrochim Acta A, 2015, 140: 241. [6] Sun S G, Yuan Y, Li Z Y, et al. New J. Chem., 2014, 38: 3600. [7] TU Shi-chun, YANG Bo, XIAO Xin, et al(涂仕春,杨 波,肖 昕,等). Journal of Guizhou University·Natural Science(贵州大学学报·自然科学版), 2014, 31(2): 13. [8] Montes-Navajas P, Corma A, Garcia H. Chem. Phys. Chem., 2008, 9: 713. [9] Montes-Navajas P, Garcia H. J. Photoch. Photobio. A, 2009, 204: 97. [10] Paul P, Hossain M, Kumar G S. J. Chem. Thermodyn., 2011, 43: 1036. [11] Nicotra V E, Mora M F, Iglesias R A, et al. Dyes Pigments., 2008, 76(2): 315. [12] Koner A L, Ghosh I, Saleh N, et al. Can. J. Chem., 2011, 89: 139. [13] Kim M O, Blachly P G, Kaus J W, et al. J. Phys. Chem. B, 2015, 119(3): 861. [14] Kim J, Jung I S, Kim S Y, et al. J. Am. Chem. Soc., 2000, 122(3): 540. [15] Day A I, Blanch R J, Arnold A P, et al. Angew. Chem. Int. Ed., 2002, 41(2): 275. |
[1] |
HUANG Xiao-wei1, ZHANG Ning1, LI Zhi-hua1, SHI Ji-yong1, SUN Yue1, ZHANG Xin-ai1, ZOU Xiao-bo1, 2*. Detection of Carbendazim Residue in Apple Using Surface-Enhanced Raman Scattering Labeling Immunoassay[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2023, 43(05): 1478-1484. |
[2] |
HAO Jie, DONG Fu-jia, WANG Song-lei*, LI Ya-lei, CUI Jia-rui, LIU Si-jia, LÜ Yu. Rapid Detection of Pesticide Residues on Navel Oranges by Fluorescence Hyperspectral Imaging Technology Combined With Characteristic Wavelength Selection[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2022, 42(12): 3789-3796. |
[3] |
SONG Gui-xian1, TANG Qing2, HUANG Ying2*, ZHANG Jian-xin3, TAO Zhu1, XUE Sai-feng1, ZHU Qian-jiang1, WEI Gang4*. Interaction of Cucurbit[8]uril with β-Indoleacetic Acid and Methylviologen[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2015, 35(11): 3134-3139. |
[4] |
WANG Xiao-bin1, WU Rui-mei1, 2*, LIU Mu-hua1, ZHANG Lu-ling1, LIN Lei1, YAN Lin-yuan1 . Laser Raman Spectrum Analysis of Carbendazim Pesticide [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(06): 1566-1570. |
[5] |
JI Ren-dong1, 2, CHEN Meng-lan1, ZHAO Zhi-min1, 3*, ZHU Xing-yue1, WANG Le-xin1, LIU Quan-jin1,3 . Study on Experiment of Absorption Spectroscopy Detection of Pesticide Residues of Carbendazim in Orange Juice [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2014, 34(03): 721-724. |
[6] |
GAO Zhong-wei, MU Lan*, XUE Sai-feng, TAO Zhu, ZENG Xi . Cucurbit[8]urils-Induced Room Temperature Phosphorescence of Phenanthrene and Fluorene[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2010, 30(04): 1026-1029. |
[7] |
FENG Yan1, XUE Sai-feng1, 2*, MU Lan1, 2, ZHU Qian-jiang1, 2, TAO Zhu1, 2 . Recognition of Cucurbit[7 and 8]urils Toward Methylene Blue with Spectroscopy[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(11): 3042-3046. |
[8] |
TONG Ling,MU Lan*,XUE Sai-feng,ZHU Qian-jiang,TAO Zhu,ZENG Xi. Interaction of Cucurbit[8]urils with Ofloxacin, Fleroxacin, Gatifloxacin and Sparfloxacin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(02): 446-450. |
[9] |
TONG Ling,MU Lan*,XUE Sai-feng,ZHU Qian-jiang,TAO Zhu,ZENG Xi. Interaction of Cucurbit[8]urils with Ofloxacin, Fleroxacin, Gatifloxacin and Sparfloxacin[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2009, 29(02): 446-450. |
[10] |
TONG Xiao-qing1,2,Lü Jian-quan1*,SUN Juan1,GONG Zhong-hong1 . Fluorescence and Visible Spectroscopic Studies on Interaction of β-Cyclodextrin-Thionine Inclusion Complex with DNA[J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2007, 27(12): 2538-2541. |
[11] |
DU Jiang-yan1, HUANG Xiao-hua2, XU Fei2, FENG Yu-ying2, XING Wei1, LU Tian-hong1, 2* . Spectral Study on the Interaction Mechanism between Thionine and Calf Thymus DNA [J]. SPECTROSCOPY AND SPECTRAL ANALYSIS, 2005, 25(09): 1435-1438. |
|
|
|
|