| 光谱学与光谱分析 |
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| Synthesis of Naphthalimide Derivatives and Its Recognition of Fe3+ |
| DU Bin, DING Zhi-jun, GUO Lei, WANG Pu-hong, LI Zhi-jun, YU Jian-hua* |
| Research Institute of Chemical Defense, Beijing 102205, China |
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Abstract A novel naphthalimide derivatives N-hexyl-4-benzylamino-naphthalimide(HBN) was synthesized from 4-bromo-1,8-naphthalic anhydride, and the structure was characterized by NMR and MS. Spectral properties of HBN for recognition of Fe3+ were investigated by fluorescence spectrum. In a certain range of Fe3+ from 4×10-7 to 1×10-2 mol·L-1, the fluorescence intensity of HBN significantly reduced with increasing concentration of Fe3+ in ethanol/water(1∶1, volume ratio). The equation of linear regression was F0/F=623.253 2cFe3++0.964 2 (R2=0.996 3). Moreover, no obvious interference with the detection of the Fe3+ ion was observed in the presence of the common metal ions such as Ca2+, Na+, Cu2+, Zn2+, Pb2+, Co2+, Ni2+, Mn2+ and Fe2+, which indicated that HBN displayed excellent selectivity and high sensitivity for the detection of Fe3+.
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Received: 2014-02-20
Accepted: 2014-05-15
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Corresponding Authors:
YU Jian-hua
E-mail: chem_yu404@163.com
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